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71.
Jo?o?Pedro?Ferreira Jo?o?Alexandre?Rodrigues Inês?Teodora?Elias?da?FonsecaEmail author 《Journal of Solid State Electrochemistry》2004,8(4):260-271
The electrochemical behaviour of copper in neutral buffered and non-buffered synthetic seawater and in pure chloride solutions has been studied by cyclic voltammetry, weight loss measurements, open circuit potential and scanning electron microscopy (SEM). Values of the repassivation potentials of Cu in non-buffered and buffered synthetic seawater, at 50 mV s–1, were 0.12 and 0.46 V vs. SCE, respectively. The sharpness, heights and location of the different peaks as well as their charges were shown to be influenced by the composition of the solution, buffering conditions, deoxygenation, polarization potential and time. High chloride concentrations lead to higher oxidation charges. The anodic and the cathodic charges were shown to increase as the chloride concentration increases. The open circuit potential transients of copper in non-deoxygenated, non-buffered synthetic seawater indicate pitting from the beginning of the exposure, while in buffered solutions the pitting appeared only after a quite long exposure period, i.e. after 40 days. Corrosion rates of Cu samples after 3 months of immersion were higher in solutions of pure chloride (0.5 M) than in synthetic seawater. After six months the differences were even more noticeable. SEM images have showed a somewhat higher density of pits on copper samples immersed in the chloride solution (0.5 M), in comparison with those in synthetic seawater. 相似文献
72.
《Arabian Journal of Chemistry》2020,13(12):8848-8887
Phthalocyanine (Pc) complexes are an important class of dyes with numerous (e.g., biological, photophysical, and analytical) applications. Among the methods used to improve the properties of these complexes, one should mention the introduction of different substituents, variation of the central metal ion, ligand exchange, and conjugation to nanomaterials (e.g., carbon-based nanomaterials and metal nanoparticles (NPs)). This work briefly reviews Pc complex conjugation to Ag and Au NPs, highlights the different NP shapes, and discusses the diversity of conjugation approaches. Moreover, the use of UV–Vis spectroscopy, powder X-ray diffraction, X-ray photoelectron spectroscopy, transmission electron microscopy, atomic force microscopy, dynamic light scattering and Fourier transform infrared spectroscopy to characterize Pc-NP hybrids is summarized. The effect of conjugation on Pc photo-physicochemical properties (fluorescence, singlet oxygen generation, triplet state formation, and optical limiting behavior) is discussed, and future perspectives for the synthesis and applications of new hybrids are provided. 相似文献
73.
文中直接取硫酸样品3ml于装有约10ml水的25ml比色管中,加入碘化钾溶液2ml,用水稀至刻度。加入甲基异丁酮5ml,萃取lmin,分层后,在有机相中测定铅、镉、铜含量;在水相中测定锌含量。方法的加标回收率为98.9%~103%,精密度1.8%~4.3%,标准曲线法和标准加入法结果相近,倍比试验结果亦相吻合,方法快速简便、准确,适合于工业中的快速分析。 相似文献
74.
J. Borrs R. Carballo A. Castieiras M. C. Gmez‐Conde M. C. Fernndez‐Vidal J. Nicls 《无机化学与普通化学杂志》2005,631(11):2221-2226
Four new dinuclear copper(II) complexes have been synthesized and have the general formula [Cu2(L)(H2O)2], where L = GLYDTO [N,N′‐bis(carboxymethyl)dithiooxamide], ALADTO [N,N′‐bis(carboxyethyl)dithiooxamide], VALDTO [N,N′‐bis(1‐carboxy‐2‐methylpropyl)dithiooxamide] and LEUDTO [N,N′‐bis(1‐carboxy‐3‐methylbutyl)dithiooxamide]. The complexes were characterized by elemental analysis as well as by IR, electronic and EPR spectroscopy. These techniques provided evidence for the presence of the CuNO2S chromophore. Magnetic susceptibility measurements on all the complexes in the range 4–300 K show the existence of a dominant antiferromagnetic interaction with ?J values greater than 300 cm?1. Thermal decomposition behaviour of the complexes was studied by thermogravimetry. 相似文献
75.
Bright orange (CuBr)3P4Se4 is obtained from the reaction of CuBr, P, and Se in stoichiometric amounts (CuBr : P : Se = 3 : 4 : 4). The composition and the crystal structure of the compound were determined from single crystal X‐ray diffraction data. Lattice constants are a = 33.627(2) Å, b = 6.402(1) Å, c = 19.059(1) Å, β = 90.19(3) °, V = 4103.2(3) Å3, and Z = 12. The compound crystallizes in a structure that is related to (CuI)3P4Se4. Cages of β‐P4Se4 are stacked along the b‐axis and are separated by columns of copper(I) bromide. However, the coordination of the β‐P4Se4 cage molecules to the copper atoms in the CuBr columns in (CuBr)3P4Se4 is quite different from (CuI)3P4Se4. The monoclinic compound (space group: P21, no. 4) has an almost orthorhombic metric in combination with a threefold superstructure in [100]. Structural aspects of (CuBr)3P4Se4 are discussed with respect to the heavier homologue (CuI)3P4Se4. 相似文献
76.
本文研究了Cu(Ⅱ)-PEG(聚乙二醇-2000)-Zincon(锌试剂)-(NH4)2SO4体系的析相光度法并应用于测定Cu(Ⅱ)。最宜酸度为pH5.5~8.5(KH2PO4-K2HPO4)缓冲溶液)其络合物的最大吸收位于610nm,表观摩尔吸光系数为4.0×10^4L.mol^-1.cm^-1,Cu(Ⅱ)浓度在0~1.5mg/L范围内服从比尔定律,铜与Zincon形式组成为1:2的稳定的蓝色络 相似文献
77.
Helmut Ehrenberg Hermann Pauly Joachim Gröbner 《Journal of solid state chemistry》2004,177(1):227-230
The cubic face-centered structure of LiAl (, at ) transforms into a tetragonal body-centered structure (I41/amd, , at ). This first-order phase transition at about during heating is probably the reason for the so-called “ anomalies” in some physical properties like specific heat, electrical resistivity and nuclear-spin lattice relaxation. This transition seems to be correlated with the composition Li:Al of the alloy and the amount of Li vacancies. 相似文献
78.
络合物晶体的电子吸收光谱作为研究晶体的电子结构的基础内容,很早以前就得到人们注意,虽然对Cu~(2+)、Ni~(2+)等络合物电子光谱的能级的经验指认已是一项较为成熟的工作,但对吸收光谱的系统的理论计算和定量解释在以前的文献中尚不多见.近年来,我们对多种晶体的电子吸收光谱进行了定量的解释,结果表明理论计算值总是能很好地符合于实验测定值。一般说来,吸收峰位的波数误差在8%以内. 早在本世纪四十年代就奠定了乙二胺四乙酸(EDTA)在分析化学中的应用基础。 相似文献
79.
Coexistence Relations, Preparation and Properties of Ternary Compounds in the System Cu/Mo/O The phase diagram of the ternary system Cu/Mo/O is presented at 773 K. The compounds CuMoO4, Cu3Mo2O9, Cu4Mo5O17, Cu6Mo5O18, Cu4–xMo3O12, and CuxMoO3 are found to be thermodynamical stable. The homogeneity range of Cu4–xMo3O12 runs to x = 0.1–0.2. Single crystals of CuMoO4 and Cu3Mo2O9 were grown by chemical transport reactions with TeCl4, Cl2, HCl, and Br2 as transport agent. The results were compared with thermochemical calculations. The decomposition of CuMoO4 and Cu3Mo2O9 was investigated with thermal analysis and decompositon pressure measurements. 相似文献
80.
Roman E. Sioda 《Monatshefte für Chemie / Chemical Monthly》1985,116(1):49-52
The specific dissolution rate, expressed in mol cm–2s–1, and time-variation of the rest potential of copper foil in an aerated aqueous solution ofpH = 2.0 were measured.
Die Auflösbarkeit von Kupfer-Folie in wäriger Lösung von pH 2 (Kurze Mitteilung)
Zusammenfassung Es wurde die spezifische Auflösungsgeschwindigkeit (in mol cm–2s–1) und die zeitliche Veränderung des Restpotentials von Kupfer-Folie in einer belüfteten wäßrigen Lösung von pH 2,0 gemessen.相似文献