全文获取类型
收费全文 | 3043篇 |
免费 | 190篇 |
国内免费 | 94篇 |
专业分类
化学 | 431篇 |
晶体学 | 14篇 |
力学 | 1241篇 |
综合类 | 18篇 |
数学 | 880篇 |
物理学 | 743篇 |
出版年
2024年 | 1篇 |
2023年 | 32篇 |
2022年 | 36篇 |
2021年 | 54篇 |
2020年 | 73篇 |
2019年 | 75篇 |
2018年 | 79篇 |
2017年 | 78篇 |
2016年 | 85篇 |
2015年 | 87篇 |
2014年 | 111篇 |
2013年 | 265篇 |
2012年 | 121篇 |
2011年 | 167篇 |
2010年 | 135篇 |
2009年 | 177篇 |
2008年 | 162篇 |
2007年 | 168篇 |
2006年 | 147篇 |
2005年 | 152篇 |
2004年 | 128篇 |
2003年 | 121篇 |
2002年 | 100篇 |
2001年 | 78篇 |
2000年 | 78篇 |
1999年 | 84篇 |
1998年 | 72篇 |
1997年 | 63篇 |
1996年 | 59篇 |
1995年 | 42篇 |
1994年 | 38篇 |
1993年 | 52篇 |
1992年 | 36篇 |
1991年 | 40篇 |
1990年 | 21篇 |
1989年 | 25篇 |
1988年 | 19篇 |
1987年 | 9篇 |
1986年 | 14篇 |
1985年 | 8篇 |
1984年 | 10篇 |
1983年 | 3篇 |
1982年 | 8篇 |
1981年 | 7篇 |
1980年 | 2篇 |
1977年 | 2篇 |
1975年 | 1篇 |
1970年 | 1篇 |
1969年 | 1篇 |
排序方式: 共有3327条查询结果,搜索用时 15 毫秒
91.
A. Sarimeseli 《Journal of Dispersion Science and Technology》2013,34(5):694-697
Measurement of drop sizes play vital role in applications dealing with gas/liquid flow mixtures. In the present work, drop sizes in vertical and horizontal pipe flows were determined using Malvern 2600HSD system that applies laser diffraction method. From the analysis of the experimental data obtained at two different pipe orientations, two separate expressions were developed to determine Sauter mean diameter, d 32. Except for the 20 m/s superficial gas velocity in vertical flow case, a good agreement was found between the developed expressions and the experimental data. 相似文献
92.
Sven T. Lagerwall 《Liquid crystals》2013,40(12):1698-1729
Before 1910, the study of liquid crystals was dominated by Lehmann and the German school of chemists. The point of gravity then moved to France with Friedel as a leading figure. While there are many studies about Lehmann, there are fewer about Friedel. He has written about himself, so to speak, and more people have cited him than read his original papers. In the first part of this historical review, I will, after a close reading of the original papers, trace the development on French soil between 1910 and 1922.After 1922, the progress stopped in France, but a renewal of interest in liquid crystals came from Germany in the late 1920s and the first international symposium was organised there in 1931, closely followed by one in England 1933. After the Second World War, a new symposium in 1958 revived the field and then came a new outburst of turbulent productivity in the late 1960s. My aim is to focus on some of the most prominent persons and some turning points also in this modern era. But my foremost aim is to illustrate that nothing happened in the straightforward way in which most texts tend to outline the history. 相似文献
93.
94.
Andreas Braeuer Robert Fabian Hankel Markus Konstantin Mehnert Julian Jonathan Schuster Stefan Will 《Journal of Raman spectroscopy : JRS》2015,46(11):1145-1149
We report a Raman technique applicable for the in situ analysis of the development of hydrogen bonds in the liquid water‐rich phase just before the onset of gas hydrate formation. Herewith, the phase transition as well as the working principle of hydrate formation inhibitors and promoters can be analyzed. © 2015 The Authors. Journal of Raman Spectroscopy published by John Wiley & Sons Ltd. 相似文献
95.
96.
Eve Kozari Dr. Mark Sigalov Dr. Dina Pines Dr. Benjamin P. Fingerhut Prof. Dr. Ehud Pines 《Chemphyschem》2021,22(8):716-725
Infrared (IR) absorption in the 1000–3700 cm−1 range and 1H NMR spectroscopy reveal the existence of an asymmetric protonated water trimer, H7+O3, in acetonitrile. The core H7+O3 motif persists in larger protonated water clusters in acetonitrile up to at least 8 water molecules. Quantum mechanics/molecular mechanics (QM/MM) molecular dynamics (MD) simulations reveal irreversible proton transport promoted by propagating the asymmetric H7+O3 structure in solution. The QM/MM calculations allow for the successful simulation of the measured IR absorption spectra of H7+O3 in the OH stretch region, which reaffirms the assignment of the H7+O3 spectra to a hybrid-complex structure: a protonated water dimer strongly hydrogen-bonded to a third water molecule with the proton exchanging between the two possible shared-proton Zundel-like centers. The H7+O3 structure lends itself to promoting irreversible proton transport in presence of even one additional water molecule. We demonstrate how continuously evolving H7+O3 structures may support proton transport within larger water solvates. 相似文献
97.
“活化分子”作为国内化学教育领域广为人知的科学概念,在各类相关化学教材中都有介绍。然而在国外多种经典化学教材中却完全没有“活化分子”的概念,反映出国内外化学教育领域对化学反应速率理论相关知识点的处理上存在明显的差异与分歧。通过溯源关键历史文献,回顾了“活化分子”概念的形成及其在化学反应速率理论发展过程中的角色演变,指出“活化分子”概念已经退出反应速率理论的舞台,在教材中应更多地呈现其在科学史方面的价值,而不是科学价值。 相似文献
98.
傅克反应(Friedel-Crafts Reaction)是迄今为止最古老、应用最长久的碳-碳键形成反应之一,广泛应用于医药、染料、石油等化学工业的各个分支。自1877年被发现以来,傅克反应已经发展成为最经典的有机反应之一,被写进现代有机化学教科书。跟其他重大化学发现类似,傅克反应的发现过程也充满着惊喜和意外,折射出化学家敏锐的洞察力和非同寻常的逻辑推理能力。本文通过整理一些早期的国内外文献和相关化学史料,简述了傅克反应发现的历史背景、发现过程,回顾了两位化学家查理斯·傅列德尔(Charles Friedel)和杰姆斯·克拉夫茨(James Crafts)的一些重要成长经历以及他们接近40年的伟大合作历程。 相似文献
99.
The airborne transport of particles on a granular surface by the
saltation mechanism is studied through numerical simulation of
particles dragged by turbulent air flow. We calculate the
saturated flux qs and show that its dependence on the wind
strength u* is consistent with several empirical relations
obtained from experimental measurements. We propose and explain
a new relation for fluxes close to the threshold velocity ut,
namely, qs=a(u*-ut)α with α≈2. We
also obtain the distortion of the velocity profile of the wind due to the
drag of the particles and find a novel dynamical
scaling relation. We also obtain a new expression for the dependence of
the height of the saltation layer as function of the strength of the wind. 相似文献
100.
When a ferrofluid drop is trapped in a horizontal Hele-Shaw cell and subjected to a vertical magnetic field, a fingering instability
results in the droplet evolving into a complex branched structure. This fingering instability depends on the magnetic field
ramp rate but also depends critically on the initial state of the droplet. Small perturbations in the initial droplet can
have a large influence on the resulting final pattern. By simultaneously applying a stabilizing (horizontal) azimuthal magnetic
field, we gain more control over the mode selection mechanism. We perform a linear stability analysis that shows that any
single mode can be selected by appropriately adjusting the strengths of the applied fields. This offers a unique and accurate
mode selection mechanism for this confined magnetic fluid system. We present the results of numerical simulations that demonstrate
that this mode selection mechanism is quite robust and “overpowers” any initial perturbations on the droplet. This provides
a predictable way to obtain patterns with any desired number of fingers. 相似文献