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41.
A correction method is proposed for the quantitative determination of stoichiometric ratios in porous materials by electron microprobe analysis. Analysis of this kind of material is complicated by an imperfect surface that can only be improved to some extent. The correction is based on a linear dependence (different for each element) of the analyses on a sum of weight concentrations of oxides. With this correction it is possible to use analyses affected by the imperfection of the surface with much better confidence compared to common normalisation. An example is presented for a series of ceramic superconductors Bi2.1(SrCa)2.9Cu2O8+. 相似文献
42.
The inner-shell structure of some heavy atoms is examined using a self-consistent relativistic local density method. Ar(K), Kr(K) and Xe (K,L
1,L
2 andL
3) binding energies and {ie863-1} (hyper-satellite) energies of Tl, Hg and Tm are calculated. The results are compared with
available experimental data.
A part of this work was presented byMPD at the Trieste International Symposium on “Core level excitations in atoms, molecules and solids,” 22–26 June 1981, Extended
Abstracts (ed.) E Tosatti, ICTP Report No. 89/81 p. 11. 相似文献
43.
Summary This paper proposes an optimization model for gas-solid chromatographic separations in a non-linear programming form and an approximate equation of the plate height for the model. A computer-modified mapping procedure is also described for searching the optimum separation conditions. Just five experiments and about 20 minutes of the computer time are needed to establish the optima of column temperature and of the carrier gas linear velocity. The relative deviation between the predicted and the experimental values was found to be within 20% for the plate heights, and within 1.5% for the retention times. 相似文献
44.
The coloration of glass via melting techniques presents some unique problems with respect to the reproducibility, toxicology and economics of certain colors, especially if the market demands are highly variable. This is also the case for consumer products such as crystal glass and tableware. Traditionally, the decoration of crystal glasses is performed by laborious manual techniques, which are costly and do not meet modern market requirements. Alternatively, spraying of colored lacquers is a highly flexible and valuable tool for the development of new products. Sol-gel type hybrid coatings provide several advantages compared to conventional organic systems like high abrasion resistance, almost perfect adhesion, refractive index matching and sufficient stability in dishwashing procedures. The solubility of organic dyes in the hybrid matrix is sufficient for intense colors even at rather low layer thicknesses, which on the other hand convey the high brilliance of the base material. The development of transparent, translucent and opaque hybrid coatings for crystal glass has been completed in the last few years and the production of partially coated articles has started recently. The synthesis and properties of the coating material are reviewed and the industrial process and first market results are also outlined. 相似文献
45.
Guevara-Riba A Sahuquillo A Rubio R Rauret G 《Analytical and bioanalytical chemistry》2005,382(2):353-359
To evaluate the environmental impact of polluted sediments, several operationally defined sequential extraction procedures (SEPs) have been described. Salinity has long been recognised as an important variable determining the physicochemical behaviour of heavy metals in marine sediments. Thus, in the present paper, the modified BCR-SEP has been applied to harbour sediments in order to assess to what extent trace metal mobility (Cd, Cr, Cu, Ni, Pb and Zn) could be influenced by chloride content in sediments. For this, washed (W) and non-washed (NW) sediments were compared. The relative mobility order observed for the six trace metals studied was not seen to be influenced by the presence of chloride in the sediments, but an increase of mobility was observed for Cd and Zn (the most mobile metals) when chloride was present in the sediments. Characterisation of the sediments and of the pseudo-total metal contents by means of an aqua regia extraction was also assessed. 相似文献
46.
47.
An attempt has been made to apply Green’s function and partitioning technique to the case of XY2Z (ClO2F) pyramidal type molecule belonging toC, point group. The isotopic rules have been formulated. The force constants, rotation distortion constants and mean amplitude
of vibration have been computed and compared with other observed and calculated values whichever is available. 相似文献
48.
Mechanisms for the initial stage of glyceraldehyde and glycine Maillard reaction under different pH conditions have been proposed, following usually the Hodge-scheme. Computations have been performed on the mechanisms at the standard state to test the possibility of the formation of different compounds, through evaluating the changes in Gibb's free energy during the reaction. Electronic energy changes during the reaction have also been evaluated. Glyceraldehyde+deprotonated glycine reaction has been found to be the most favorable for the formation of the Amadori rearrangement products in both gaseous and aqueous states. Due to the possibility of the production of both enol and keto forms of the Amadori rearrangement product, the rate of browning in glyceraldehyde+deprotonated glycine reaction is assumed to be faster than the others. Glyceraldehyde+unionized glycine reaction has been found to be more plausible for the formation of the keto form of the Amadori rearrangement products, particularly, in the gaseous phase. Glyceraldehyde+protonated glycine and glyceraldehyde+glycine zwitterion reactions are not favorable for the formation of the Amadori rearrangement products. Formation of hydroxyacetaldehyde from glyceralaldehyde, as one of the possible C2-fragmentation product, has been found to be favorable in the aqueous state. 相似文献
49.
Jong-Shi Pang 《Mathematical Programming》1979,16(1):111-126
The present paper studies the linear complementarity problem of finding vectorsx andy inR
+
n
such thatc + Dx + y 0,b – x 0 andx
T
(c + Dx + y) = y
T
(b – x) = 0 whereD is aZ-matrix andb > 0. Complementarity problems of this nature arise, for example, from the minimization of certain quadratic functions subject to upper and lower bounds on the variables. Two least-element characterizations of solutions to the above linear complementarity problem are established first. Next, a new and direct method to solve this class of problems, which depends on the idea of least-element solution is presented. Finally, applications and computational experience with its implementation are discussed.Research partially supported by the National Science Foundation Grant MCS 71-03341 A04 and the Air Force Office of Scientific Research Contract F 44620 14 C 0079. 相似文献
50.
Yahya Fathi 《Mathematical Programming》1979,17(1):335-344
Murty in a recent paper has shown that the computational effort required to solve a linear complementarity problem (LCP), by either of the two well known complementary pivot methods is not bounded above by a polynomial in the size of the problem. In that paper, by constructing a class of LCPs—one of ordern forn 2—he has shown that to solve the problem of ordern, either of the two methods goes through 2
n
pivot steps before termination.However that paper leaves it as an open question to show whether or not the same property holds if the matrix,M, in the LCP is positive definite and symmetric. The class of LCPs in whichM is positive definite and symmetric is of particular interest because of the special structure of the problems, and also because they appear in many practical applications.In this paper, we study the computational growth of each of the two methods to solve the LCP, (q, M), whenM is positive definite and symmetric and obtain similar results.This research is partially supported by Air Force Office of Scientific Research, Air Force Number AFOSR-78-3646. The United States Government is authorized to reproduce and distribute reprints for governmental purposes notwithstanding any copyright notation thereon. 相似文献