首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   728篇
  免费   23篇
  国内免费   27篇
化学   163篇
晶体学   1篇
力学   333篇
综合类   5篇
数学   147篇
物理学   129篇
  2024年   2篇
  2023年   3篇
  2022年   10篇
  2021年   18篇
  2020年   13篇
  2019年   8篇
  2018年   15篇
  2017年   15篇
  2016年   18篇
  2015年   21篇
  2014年   40篇
  2013年   24篇
  2012年   19篇
  2011年   38篇
  2010年   21篇
  2009年   30篇
  2008年   49篇
  2007年   53篇
  2006年   38篇
  2005年   31篇
  2004年   27篇
  2003年   36篇
  2002年   19篇
  2001年   22篇
  2000年   20篇
  1999年   21篇
  1998年   11篇
  1997年   26篇
  1996年   15篇
  1995年   9篇
  1994年   18篇
  1993年   9篇
  1992年   17篇
  1991年   15篇
  1990年   14篇
  1989年   14篇
  1988年   5篇
  1987年   5篇
  1986年   2篇
  1985年   1篇
  1984年   2篇
  1982年   1篇
  1979年   1篇
  1978年   1篇
  1957年   1篇
排序方式: 共有778条查询结果,搜索用时 15 毫秒
11.
In our previous two works, we studied the blow-up and lifespan estimates for damped wave equations with a power nonlinearity of the solution or its derivative, with scattering damping independently. In this work, we are devoted to establishing a similar result for a combined nonlinearity. Comparing to the result of wave equation without damping, one can say that the scattering damping has no influence.  相似文献   
12.
13.
To solve the problem of high pressure of water injection in low permeability reservoirs, a high concentration of surfactant system was developed in this article. With the solubilization of oil in aqueous surfactant solution as a criterion, a formula was screened from anionic and nonionic-anionic surfactants, and the optimal depressurized system was obtained as follows, 13.3% surfactant HEX +2.23% n-propanol +4.47% n-butanol, the solubilization capability being up to 0.66 g/g. This system had good salt tolerance, and it exhibited water external microemulsion in the range of of 1 to 200 g/L NaCl. Core flooding results show that this high concentration of surfactant system formed water external microemulsion with the residual oil in the core, reducing the displacement pressure over 35%. Meanwhile, the effects of concentration and injection volume on depressurization were also investigated. It is indicated that a good depressurization effect was achieved after injecting 1 pore volume of the system with the salt concentration of 100 g/L.  相似文献   
14.
The present work investigates the degradation of 4-chloro 2-aminophenol (4C2AP), a highly toxic organic compound, using ultrasonic reactors and combination of ultrasound with photolysis and ozonation for the first time. Two types of ultrasonic reactors viz. ultrasonic horn and ultrasonic bath operating at frequency of 20 kHz and 36 kHz respectively have been used in the work. The effect of initial pH, temperature and power dissipation of the ultrasonic horn on the degradation rate has been investigated. The established optimum parameters of initial pH as 6 (natural pH of the aqueous solution) and temperature as 30 ± 2 °C were then used in the degradation studies using the combined approaches. Kinetic study revealed that degradation of 4C2AP followed first order kinetics for all the treatment approaches investigated in the present work. It has been established that US + UV + O3 combined process was the most promising method giving maximum degradation of 4C2AP in both ultrasonic horn (complete removal) and bath (89.9%) with synergistic index as 1.98 and 1.29 respectively. The cavitational yield of ultrasonic bath was found to be eighteen times higher as compared to ultrasonic horn implying that configurations with higher overall areas of transducers would be better selection for large scale treatment. Overall, the work has clearly demonstrated that combined approaches could synergistically remove the toxic pollutant (4C2AP).  相似文献   
15.
实验研究了Nd∶YVO4/Nd∶GdVO4双波长激光器在不同抽运功率条件下,通过调节热沉温度达到功率均衡时的输出特性.实验结果表明:对于Nd∶YVO4/Nd∶GdVO4双波长激光器,当提高抽运功率,需要重新降低热沉温度达到功率均衡输出,降温幅度与抽运功率增加之比为11.23℃/W.与此同时,随着抽运功率和热沉温度的变化,双波长激光器的中心波长会出现小幅度的漂移,左峰波长随抽运功率增加的蓝移速率为0.056 nm/W,右峰波长随抽运功率增加的蓝移速率为0.054 nm/W.实验还发现功率均衡条件下激光器的输出总功率随抽运功率的增加而增加,拟合斜效率为8.7%,当抽运功率为5.58 W时,输出最大总功率达到115.7 mW.  相似文献   
16.
马诗瑶  杜慧  耿闯  王扬  庞琳瀚  赵娜  刘筱  郭永泰  曲江英 《应用化学》2016,33(11):1316-1321
采用废弃蟹壳为碳源,KOH为活化剂原位制备了氮/氧共掺杂多孔炭,并研究其作为电极材料在超级电容器中的应用。 固定蟹壳与KOH的质量比为5:3,考察了煅烧温度对所得炭材料产率、孔结构和氮氧含量的影响。 结果表明,蟹壳基炭材料的孔结构和氮/氧含量可通过改变煅烧温度调变。 随着煅烧温度从500 ℃上升至700 ℃,多孔炭的比表面积和孔体积逐渐增大,而氮/氧含量随温度升高则降低。 采用循环伏安和恒流充放电对所得材料的电化学性能进行测试。 结果表明,所得多孔炭的电化学性能取决于其孔结构与氮/氧表面性质的协同作用,其中煅烧温度为600 ℃所得的多孔炭比表面积为612 m2/g,氮和氧含量分别为3.53%和32.8%,在50 mA/g的电流密度下比电容达到310 F/g,循环1000次比电容仍然保持95%以上,展现出良好的电化学性能。  相似文献   
17.
以花生壳粉(PS)为生物基质,甲苯-2,4-二异氰酸酯(TDI)为交联剂,均苯四甲酸酐(PMDA)为改性剂,制备了均苯四甲酸酐改性花生壳粉(PMPS)吸附剂,并研究了PMPS对阳离子红染料吸附效果的影响因素。结果表明,在25℃,吸附时间3 h,pH值为2.0时,PMPS处理浓度为400.0 mg/mL的阳离子红溶液25 mL,最大吸附容量Q为177.2 mg/g,是未改性花生壳粉的2.2倍。改性花生壳粉吸附模式为Langmuir单分子层化学吸附。  相似文献   
18.
硼氢化钠是一种温和、高选择性的亲核还原剂。一般它只能还原醛、酮和酰氯,而对其它功能团不起作用。因而其应用范围有一定的限制。据文献报道,某些金属卤化物能有效地提高硼氢化钠的还原性能[1]。复合还原剂硼氢化钠/三氯化铁已应用于将β-二烷基氨基共轭烯酮还原为相应的饱和γ-氨基醇[2]。本文研究了硼氢化钠/三氯化铁对亚砜的还原反应。  相似文献   
19.
A new approach was developed for modeling the effect of the third body on fretting. This was accomplished using the combined finite-discrete element method (FDEM) in which the third body is analyzed as discrete elements while the first bodies are modeled using finite elements. This approach provides a link between large scale models which treat the mass of wear debris as a single or small number of bodies and small scale models which only study a control volume. The FDEM was used to analyze the behavior of third body particles between flat sliding surfaces. When the third body mass is composed of unconnected particles, it behaves as a Newtonian fluid, but this behavior ceases when the particles are connected into platelets. The FDEM was also used to study the behavior of third body particles inside a Hertzian line contact. As the number of particles and platelet size increase the load carried by the worn slip zone grows larger in relationship to the unworn stick zone.  相似文献   
20.
The rod-shaped Co-Ni-P shells were prepared by metalling Bacillus. The microstructures and composition of the shells were characterized by scanning electron microscopy (SEM), transmission electron microscopy (TEM) and energy dispersive analysis (EDS). The electromagnetic parameters were measured by the coaxial line method in the frequency of 2-18 GHz. It was found that the Bacillus were successfully coated with Co-Ni-P, and the inner structure of the shells are hollow in structure. The shells exhibit excellent microwave absorption properties in 5-17 GHz frequency. The microwave reflection loss is above −10 dB in 5.38-16.6 GHz frequency. The maximum microwave reflection loss reaches −35.83 dB at 9.12 GHz for samples thickness 2.4 mm, and the widest bandwidth for microwave reflection loss above −10 dB is about ∼5.32 GHz for samples thickness 2.0 mm. These results confirm the feasibility of applying Bacillus as biotemplates for fabrication of the metallic shells as lightweight microwave absorption materials are very promising for applications.  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号