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61.
By focusing on cold-crystallized poly(ether diphenyl ether metaketone) (PEKm), a more in-depth understanding of the nature
of the crystalline morphology has been gained, which may lead to thorough mechanisms for interpreting the observed thermal
behavior in PEKm. Apparently, cold-crystallized PEKm containing initially only a single P1 crystal can exhibit dual melting
peaks (300 and 320 °C), with the second high-melting peak corresponding to the P2 crystal that was subsequently formed via
P1 melting/repacking during the scan. However, dual morphism (preexisting P1 and P2 crystals) could be intentionally introduced
into PEKm if it was cold-crystallized at temperature schemes of decreasing order. The P1 and P2 crystals possess the same
unit cells (orthorhombic) and thus they differ only in the lamellae populations. The dual lamellar morphism in this PEKm sample
also exhibited similar dual melting peaks during scanning, which correspond to melting of the individual P1 and P2 in a sequential
order. This study has thus provided important clues in and shed new light on the interpretation of multiple melting with respect
to polymorphism in polymers. Relationships between the low-melting and high-melting lamellae in cold-crystallized polyketone
polymer have been thoroughly explored.
Received: 9 January 2001/Accepted: 3 February 2001 相似文献
62.
《Analytica chimica acta》2002,460(1):111-122
Direct cold vapour generation from aqueous slurries of environmental (marine sediment, soil, coal) and biological (human hair, seafood) samples have been developed using a batch mode generation system coupled with electrothermal atomic absorption spectroscopy. The effects of several variables affecting the cold vapour generation efficiency from solid particles (hydrochloric acid and sodium tetrahydroborate concentrations, argon flow rate, acid solution volume and mean particle size) have been evaluated using a Plackett-Burman experimental design. In addition, variables affecting cold vapour trapping and atomisation efficiency on Ir-treated graphite tubes (trapping and atomisation temperatures and trapping time) have been also investigated. Atomisation and trapping temperatures, trapping time and hydrochloric acid concentration were the significant variables. The 22+star and 23+star central composite designs have been used to obtain optimum values of the variables selected. The accuracy of methods have been verified by using several certified reference materials (PACS-1, GBW-07410, NIST-1632c, CRM-397 and DORM-2). A characteristic mass of 390 pg were achieved. The detection limits of methods were in the range of 40-600 ng g−1. A particle size less than 50 μm is adequate to obtain total cold vapour generation of Hg content in the aqueous slurry particles. 相似文献
63.
64.
动态冷原子吸收法快速测定地球化学样品中微量汞 总被引:3,自引:0,他引:3
本文介绍了动态冷原子吸收法快速测定地球化学样品中微量汞的方法。本文研究采用了新型的汞蒸气发生器,并对气泡的干扰进行了研究。线性范围为0.2-12ng/mL,标准回收率为97%-106%,相对标准偏差为3.6%,相关系数为0.9997,试验结果表明此方法简便、快速、准确。 相似文献
65.
66.
U. Kulshreshtha D. S. Kulshreshtha 《International Journal of Theoretical Physics》2002,41(10):1941-1956
The nonlinear sigma model in one-space one-time dimension is considered on the light-front. The front-form theory is seen to possess a set of three first-class constraints and consequently it possesses a local vector gauge symmetry. This is in contrast to the usual instant-form theory, which is well known to be a gauge noninvariant theory possessing a set of four second-class constraints. The front-form Hamiltonian, path integral, and BRST formulations of this theory are investigated under some specific gauge choices. 相似文献
67.
描述了在BBOⅠ类相位匹配的飞秒光参量放大(OPA)中,利用非共线结构和倾斜抽运光的脉 冲波面来完全补偿三波群速失配的方法.理论计算了三波群速匹配时,非共线角、相位匹配 角、抽运光的脉冲波面倾斜角随信号光波长的变化,并分析了对抽运光光斑尺寸的要求和对 空间走离长度的影响.结果表明,利用该方法不仅能够实现最大的参量带宽,而且能够完全 补偿飞秒OPA中三波的群速失配.此外,选取合适的抽运光光斑尺寸和非线性晶体的长度对提 高参量增益也至关重要.
关键词:
群速匹配
非共线相位匹配
脉冲波面倾斜
飞秒光参量放大 相似文献
68.
提出分块波前法求解非对称大型有限元方程组,该方法综合分块解法和波前法的优点,根据计算机容量和方程的阶数优化计算过程,以在经济效率和存储效率之间达到平衡。本文利用该方法求解了轮胎稳态滚动有限元方程组,表明该方法是有效、可靠的。 相似文献
69.
A one-dimensional approximate analytical model, which preserves the main features of soil-crop-atmospheric hydrodynamics,
has been suggested for plant roots of low soil-root conductivity ratio (SRCR). The proposed approach involves physically based
concepts, such as mass balance equation, Darcy’s law, and related water uptake and plant transpiration functions. Two main
assumptions have been made to derive the analytical solution: (1) gravitational flow is adopted and (2) the uniform soil moisture
distribution within the root water activity zone is supposed. The mass balance equation in its integral form is solved by
the method of characteristics. This leads to the two functional equations for soil pressure head and root potential, which
can be solved simultaneously by using common software. The model has been further verified against the numerical one. The
model represents a reasonable compromise between the complicated mechanism of unsaturated water flow with root water uptake
(RWU) and still insufficient knowledge of the soil-plant-atmospheric continuum. It is able to account for temporal fluctuations
in root activity zone and provides a relatively simple algorithm for investigation of RWU-mechanism. Besides the theoretical
and applicative importance, this flow model yields water and velocity distributions within soil profile, and, thereby, constitutes
a preliminary step toward solution of contaminant transport problems in vadose zone.
Deceased 相似文献
70.
The behavior of the interface in a two-phase immiscible fluid flow in a randomly heterogeneous porous medium is investigated. The medium is described by the permeability distribution which represents a random field with given statistical characteristics. When the approach proposed is used, it turns out to be possible to relate the statistical characteristics of the interface with the statistical characteristics of the permeability field and the properties of the phases. On the basis of this relation an important characteristic of the two-phase flow, namely, the average saturation distribution in the neighborhood of the interface, can be calculated. 相似文献