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91.
92.
Bimetallic SCN ligand based single crystals of manganese mercury thiocyanate (MMTC), cadmium mercury thiocyanate (CMTC) and zinc cadmium thiocyanate (ZCTC) are grown by slow solvent evaporation technique. The growth mechanism and surface features are investigated by optical microscopic techniques such as scanning electron microscopy (SEM) and atomic force microscopy (AFM). The laser induced surface damage measurements were carried out using a Q-switched Nd:YAG laser at 1064 nm with laser beam of 1.0 Hz and pulse duration 25 ps. The laser damage threshold values of MMTC, CMTC and ZCTC are found to be 15.9, 22.9 and 19.7 GW/cm2, respectively. The SEM analysis of MMTC reveals the formation of elongated dendrite growth pattern caused by the fluctuations of Mn and Hg metal ligands when thiocyanate (SCN) bridges them. The etching study indicates the occurrence of different types of etch pit patterns like terraced triangles, pillars, pyramids and rods. The AFM images confirm the formation of three major hillocks with cavities in MMTC. The measured roughness values for CMTC crystal are very much lower than that of MMTC. 相似文献
93.
利用电子束蒸发方法,在不同沉积温度(50~350℃)下制备了Sc2O3薄膜。分别用分光光度计,小角掠入射X射线衍射仪和轮廓仪测试了薄膜样品的光谱、微结构和表面粗糙度信息,并用薄膜分析软件Essential Macleod计算了Sc2O3薄膜的折射率和消光系数。结果表明:随着沉积温度升高,Sc2O3薄膜结晶程度增强,晶粒尺寸增大,且较高的沉积温度有利于获得较高的折射率。最后用355 nm,8 ns的三倍频Nd:YAG激光器测试了其激光损伤阈值(LIDT),最大值为2.6 J/cm2,且阈值与薄膜的消光系数、表面粗糙度、光学损耗均呈现相反的变化趋势。用光学显微镜和扫描电子显微镜表征了该薄膜的破坏形貌,详细分析了薄膜在不同激光能量作用下破坏的发展过程,以及Sc2O3薄膜在355 nm紫外激光作用下LIDT与制备工艺的关系,重点分析了355 nm激光作用下薄膜的破坏机理。 相似文献
94.
Laser conditioning of high-reflective and anti-reflective coatings in vacuum environments 总被引:1,自引:0,他引:1
Laser conditioning effects of the dielectric mirror coatings in vacuum environments were investigated. The laser-induced damage thresholds (LIDT) in vacuum environments before and after laser conditioning were compared. It is found that laser conditioning in vacuum environments decrease the LIDT of the component. Laser conditioning effects in vacuum and atmosphere environments were also compared and investigated. The negative effects of laser conditioning in vacuum environments were discussed and analyzed with defect statistical model, energy dispersive X-ray analysis and absorption measurements. 相似文献
95.
连续CO2激光对红外窗口材料损伤研究 总被引:4,自引:0,他引:4
研究了连续CO2激光对几种红外窗口材料的表面损伤特性,研究表明,损伤机制在于杂质缺陷吸收造成的热冲击应力破坏。深入研究了杂质缺陷密度、焦斑与材料损伤阈值的关系,并建立了一个损伤模型。同时分析了热冲击应力破坏方式。 相似文献
96.
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98.
为揭示不同围压下硬岩在破坏过程中的力学性质和能量演化规律,基于RMT-150B岩石力学试验系统对花岗岩试样进行不同围压条件下常规三轴压缩试验。研究结果表明:岩样的峰值应力和围压具有较强的线性关系,利用Mohr-Coulomb强度准则求出花岗岩的黏聚力为23.548 MPa,内摩擦角为57.629°。围压对花岗岩加载破坏过程中能量演化的影响显著,岩石的峰值能量、弹性应变能以及耗散能都随着围压的增大而增大,且两者呈线性增加关系。根据岩石的线性储能规律,提出了确定岩石应力阈值的方法。围压越大,起裂应力和扩容应力越大,且岩样起裂点处与扩容点处的能量也越大;当围压较低时,岩石破坏前储存的能量较少,破坏时能量释放速率低,岩样表现为典型低劈裂破坏;在高围压情况下,能量快速释放,岩样表现为剪切破坏。基于能量演化规律,提出了岩石损伤演化模型,得到了花岗岩的损伤变量D在不同围压下加载破坏过程中的演化规律。 相似文献
99.
The effects of Co-60 gamma-rays and about 25-MeV pulsed electrons have been investigated on CR-39 plastic nuclear track detector. The bulk etch rate was measured as a function of the absorbed dose under three different irradiation conditions; gamma-ray exposure in air at the dose rate of 6 kGy/h, that in vacuum and electron shower in air at 126 kGy/h on average. It was found that the bulk etch rate (V) increased nearly exponentially with the dose (D); V=V0exp(kD), and the characteristic parameter (k) was 35, 9 and 12 MGy−1, respectively. It is considered that a lack of oxygen in damage formation processes could occur momentarily during a short electron pulse, just similarly to the vacuum effect of reduction in track etch rates in outgassed CR-39 plastic. 相似文献
100.
Zuning Zhang Zhen Liu Yong Jiang Huachun Zhu Te Ji Jie Wang Min Chen Weiwei Peng Lihua Wang Xiangjun Wei 《X射线光谱测定》2022,51(4):394-402
Advanced synchrotron radiation light is a powerful tool for archaeometry research. However, its applications to precious cultural relics, especially for color painting, have been hindered to some degree due to potential X-ray radiation damage. Compared to inorganic mineral pigments, organic binders in the painting are easier to be damaged by synchrotron radiation X-ray beam. The radiation damage effect of two typical painting samples, pure rabbit skin glue and the mixed sample of rabbit skin glue and zinc white, has been investigated by in situ time-resolved ED-XAS and IR combined techniques. The results show that the radiation damage effect of pure rabbit skin glue is more serious at low X-ray energy (7775 eV). The radiation damage effect of the mixed sample increases significantly due to more X-ray absorption by inorganic pigments. Furthermore, the radiation damage is more serious at the energy near Zn K-edge and is somewhat slight at higher energy (13,054 eV). These damages are more obvious from the point of view of protein secondary structures. The irradiation damage effects increase more rapidly at the beginning and are not linear with the irradiating time. The results indicate that synchrotron radiation damage can be reduced effectively by using X-ray energy far away from the X-ray absorption edge of the major element in the pigments during XRF, XRD and CT experiments, or by using time-resolved techniques such as QXAFS and ED-XAS during XAFS experiments. 相似文献