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261.
Two types of biomolecules were tested in the comparison of usefulness of two ways of formation of the intermediate layers at electrodes: a 20‐nucleotide DNA sequence and glucose oxidase. Chronocoulometric, amperometric, electrochemical impedance and PM‐IRRAS experiments proved that the layers obtained by electroreduction of diazonium salts are much more stable and more efficient in the accumulation of biomolecules compared to layers obtained by self‐assembling of appropriate thiols. 相似文献
262.
研究了脉冲HF激光与水柱表面相互作用下电信号的产生过程。电信号显示了与激光能量线性相关的峰值间有时间间隔的两峰结构,且第二个尖峰在水柱底部的蒸汽腔塌缩后出现。实验还显示电信号的幅值和激光脉冲照射过程中是否存在膨胀和挤压的薄水层密切相关。如果在电池上边缘和石英平板(石英板紧邻电池,并与水柱上表面相接)之间存在一薄水层,电信号强度会增加10倍。 相似文献
263.
In this paper, the problem of unsteady flow induced by a shrinking sheet with mass transfer in a rotating fluid is studied. The transformed boundary layer equations are solved numerically by an implicit finite‐difference scheme known as the Keller‐box method. The influence of rotation, unsteadiness and mass suction parameters on the reduced skin friction coefficients f″(0) and g′(0), as well as the lateral velocity and velocity profiles are presented and discussed in detail. Copyright © 2010 John Wiley & Sons, Ltd. 相似文献
264.
Electron transfer behavior at polyoxometalate-adsorbed alkanethiol self-assembled monolayers 总被引:1,自引:0,他引:1
Yeonyi ChuJandee Kim Suhee ChoiChoong Kyun Rhee Jongwon Kim 《Applied Surface Science》2011,257(22):9490-9497
The interaction between polyoxometalate (POM) anions, SiMo12O404−, and a self-assembled monolayer (SAM) of dodecanethiol (DT) on Au surfaces was investigated using electrochemical methods, X-ray photoelectron spectroscopy, and scanning probe microscopy. The SiMo12O404− ions adsorb on the SAM of DT on Au to form a composite organic-inorganic hybrid layer. The adsorbed SiMo12O404− ion on the SAM layer shows its characteristic redox waves with an electron transfer rate slower than that on a bare Au electrode. The electron transfer behavior at DT−SAM could be regulated by the adsorption of SiMo12O404− depending on the charge of the investigated electroactive species: a significant increase toward a positively charged Ru(NH3)63+ ion, a moderate increase toward a neutral 1,1′-ferrocenedimethanol molecule and a slight decrease toward a negatively charged Fe(CN)63− ion. The effect of the chain length of alkanethiols on the adsorption of SiMo12O404− ion was also investigated: as the chain length decreases, the amount of the adsorbed POM increases and the electron transfer rate through the composite layers increases. The nature of SiMo12O404− ions adsorbed on the SAMs of alkanethiols on Au is discussed in detail. 相似文献
265.
Denys Dutykh 《Physics letters. A》2009,373(36):3212-3216
Water wave propagation can be attenuated by various physical mechanisms. One of the main sources of wave energy dissipation lies in boundary layers. The present work is entirely devoted to thorough analysis of the dispersion relation of the novel visco-potential formulation. Namely, in this study we relax all assumptions of the weak dependence of the wave frequency on time. As a result, we have to deal with complex integro-differential equations that describe transient behaviour of the phase and group velocities. Using numerical computations, we show several snapshots of these important quantities at different times as functions of the wave number. Good qualitative agreement with previous study [D. Dutykh, Eur. J. Mech. B/Fluids 28 (2009) 430] is obtained. Thus, we validate in some sense approximations made anteriorly. There is an unexpected conclusion of this study. According to our computations, the bottom boundary layer creates disintegrating modes in the group velocity. In the same time, the imaginary part of the phase velocity remains negative for all times. This result can be interpreted as a new kind of instability which is induced by the bottom boundary layer effect. 相似文献
266.
Fen Yu Dr. Xuan Fang Huimin Jia Miaoxing Liu Xiaotong Shi Chaowen Xue Dr. Tingtao Chen Prof. Zhipeng Wei Prof. Fang Fang Prof. Hui Zhu Prof. Hongbo Xin Prof. Jing Feng Prof. Xiaolei Wang 《Chemistry (Weinheim an der Bergstrasse, Germany)》2016,22(24):8053-8058
For the first time, the influence of different types of atoms (Zn and O) on the antibacterial activities of nanosized ZnO was quantitatively evaluated with the aid of a 3D‐printing‐manufactured evaluation system. Two different outermost atomic layers were manufactured separately by using an ALD (atomic layer deposition) method. Interestingly, we found that each outermost atomic layer exhibited certain differences against gram‐positive or gram‐negative bacterial species. Zinc atoms as outermost layer (ZnO?Zn) showed a more pronounced antibacterial effect towards gram‐negative E. coli (Escherichia coli), whereas oxygen atoms (ZnO?O) showed a stronger antibacterial activity against gram‐positive S. aureus (Staphylococcus aureus). A possible antibacterial mechanism has been comprehensively discussed from different perspectives, including Zn2+ concentrations, oxygen vacancies, photocatalytic activities and the DNA structural characteristics of different bacterial species. 相似文献
267.
《Journal of separation science》2018,41(18):3553-3560
The combination of sofosbuvir and daclatasvir or sofosbuvir and ledipasvir is now widely used as an ideal treatment for hepatitis C virus infection. For this purpose, a simple, sensitive, accurate, economic, and precise high‐performance thin‐layer chromatography was developed and validated for the determination of sofosbuvir, daclatasvir, and ledipasvir in their pure form as well as their different pharmaceutical products. The method used Merck high‐performance thin‐layer chromatography aluminum plates precoated with silica gel 60 F254 as a stationary phase and mobile phase consisting of methylene chloride/methanol/ethyl acetate/ammonia (25%) (6:1:4:1, v/v/v/v). This system was found to give compact symmetric peaks of sofosbuvir, daclatasvir, and ledipasvir with retardation factors of 0.27 ± 0.01, 0.50 ± 0.007, and 0.68 ± 0.008, respectively. The densitometric scanner was set at 275 nm using a deuterium lamp. The calibration curves were linear over the range of 100–3000 ng/spot for sofosbuvir, and daclatasvir, and range of 50–3000 ng/spot for ledipasvir. The detection limits were 22.5, 31.90, and 15.80 for sofosbuvir, daclatasvir, and ledipasvir. The quantitation limits were 67.50, 95.60, and 47.50 for sofosbuvir, daclatasvir, and ledipasvir. The proposed method was validated according to International Conference on Harmonization (ICH) guidelines and the results were acceptable. 相似文献
268.
Sadhan Ghosh 《Journal of magnetism and magnetic materials》2011,323(5):552-556
This work reports isothermal reversible variation of magnetization in nanoporous Pd-Ni alloys subjected to continuous charging and discharging of the sample in aprotic electrolyte medium. Polarizing metal surface with excess charge also finds strain in the nanoporous structure using the sample as working electrode. Therefore, it is proposed that pressure induced by strain is the key parameter for the observed reversible magnetization in the transition metal alloys. 相似文献
269.
270.
Seokgeun Jin Byung Jun Jung Chung Kun Song Jeonghun Kwak 《Current Applied Physics》2014,14(12):1809-1812
We introduce a room temperature and solution-processible vanadium oxide (VOx) buffer layer beneath Au source/drain electrodes for bottom-contact (BC) organic field-effect transistors (OFETs). The OFETs with the VOx buffer layer exhibited higher mobility and lower threshold voltages than the devices without a buffer layer. The hole mobility with VOx was over 0.11 cm2/V with the BC geometry with a short channel length (10 μm), even without a surface treatment on SiO2. The channel width normalized contact resistance was decreased from 98 kΩ cm to 23 kΩ cm with VOx. The improved mobility and the reduced contact resistance were attributed to the enhanced continuity of pentacene grains, and the increased work function and adhesion of the Au electrodes using the VOx buffer layer. 相似文献