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101.
The corrosion inhibition of 1-(2-pyridylazo)-2-naphthol (PAR) on the corrosion of cold rolled steel in 0.5 M sulfuric acid (H2SO4) was studied using weight loss method and potentiodynamic polarization method. Results obtained revealed that together with chloride ion, PAR is an effective corrosion inhibitor for steel corrosion in sulfuric acid. It was found that for steel corrosion inhibition in the presence of single PAR in sulfuric acid the Temkin adsorption isotherm may be used to explain the adsorption phenomenon. For the mixture of PAR and NaCl used as corrosion inhibitor, however, the Langmuir adsorption isotherm can be used to satisfactorily elucidate the adsorption of mixture of PAR and NaCl. Potentiodynamic polarization studies showed that single PAR mainly acts as a cathodic inhibitor for the corrosion of steel in 0.5 M sulfuric acid. The mixture of PAR and chloride ion, however, acts as a mixed type inhibitor that mainly inhibits cathodic reaction of the steel corrosion in sulfuric acid. By means of electrochemical polarization tests, a desorption potential at ca. −370 mV was observed for the adsorption of mixture of PAR and chloride ion, when potential reaches this value, adsorbed inhibitor molecule heavily departs from the steel surface. For the mixture of PAR and chloride ion, thermodynamic parameters such as adsorption heat, adsorption entropy and adsorption free energy were obtained from experimental data of the temperature studies of the inhibition process at four temperatures ranging from 30 to 45 °C, the kinetic data such as apparent activation energies and pre-exponential factors at different concentrations of the inhibitor were calculated, and the effect of the apparent activation energies and pre-exponential factors on the corrosion rates of cold rolled steel was discussed. The most suitable range of inhibitor concentration was discussed. The inhibitive action was satisfactorily explained by using both thermodynamic and kinetic models. Synergism between chloride ion and PAR was proposed. The results obtained from weight loss and potentiodynamic polarization were in good agreement. 相似文献
102.
Dehydration kinetics of salmon and trout fillets using ultrasonic vacuum drying as a novel technique
In this study, a novel ultrasonic vacuum (USV) drying technique was used to shorten the drying time of fish fillets. For this purpose, ultrasonic treatment and vacuum-drying were simultaneously performed to dehydrate salmon and trout fillets at 55 °C, 65 °C, and 75 °C. In addition, the USV technique was compared with vacuum-drying and oven-drying techniques. The dehydration kinetics of the fillets was successfully described by seven thin-layer drying models with R2 range between 0.944 and 1.000. Depending on drying temperatures and fish species, the drying times could be shortened using the USV technique between 7.4% and 27.4% compared with vacuum-drying. The highest effective moisture diffusivity was determined in the fillets dried with the USV technique and they increased with increasing drying temperatures. Ultrasonic treatment accelerated the vacuum drying process for the fillets; therefore, this technique could be used to improve the efficiency of vacuum-drying for the fillets. 相似文献
103.
104.
R. Trettin T. Grischek G. Strauch G. Malleean W. Nestler 《Isotopes in environmental and health studies》2013,49(4):331-350
Abstract Flow times and infiltration behaviour are very important for water extraction from riverbank filtration. Both the chloride content and the isotopic composition of oxygen (δ18O) were found to be suitable indicators for the conditions encountered in the middle course of the River Elbe near Torgau. The ranges for Elbe water were measured to be 20–43 mg Cl/l (1995-97) and -11 to -8.5‰ δ18O (1993-97). Both methods permitted flow-time spectra at two adjacent sampling profiles incorporating river and production wells to be obtained, indicating the preferred flow paths and the vertical extension of the riverbank filtrate plume in the aquifer. However, since the differences between the mean values for river water and regional groundwater were too small the percentage of river water abstracted from production wells could not be calculated. 相似文献
105.
四磺酸基酞菁氯化铝复合二氧化硅干凝胶的制备及光学性能研究 总被引:1,自引:1,他引:1
采用溶胶凝胶法将不同掺杂浓度的四磺酸基酞菁氯化铝(AlClPcTS)植入二氧化硅凝胶基质,制备了均匀掺杂的复合干凝胶通过对二氧化硅凝胶基质和掺杂AlClPcTS后复合干凝胶孔结构的测定和对复合体系紫外可见吸收光谱的表征,证实了AlClPcTS在基质中的成功掺杂,并发现AlClPcTS同时以单体和二聚体的形式存在于复合体系中,且AlClPcTS二聚体所占比例随着凝胶化过程的进行而增大对不同AlClPcTS掺杂浓度复合干凝胶的光限幅性能进行了测试,并讨论了掺杂浓度对复合体系光限幅性能的影响,证明复合体系的光限幅性能随掺杂浓度的提高而增强. 相似文献
106.
G. Leahu R. Li Voti C. Sibilia M. Bertolotti V. Golubev D. A. Kurdyukov 《Optical and Quantum Electronics》2007,39(4-6):305-310
In this paper the thermal and optical properties of the SiO2/GaN synthetic opals are studied by photothermal deflection technique. This technique, used in different configurations, allows
to determine the effective thermal diffusivity and the absorption spectra. 相似文献
107.
磷钼杂多酸-结晶紫分光光度法测定高纯氯化铯中微量磷 总被引:1,自引:0,他引:1
以 4 -叔丁基 - 2 (α-甲苄基 )苯酚 (t- BAMBP)萃取分离基体铯 ,磷钼杂多酸与结晶紫染料生成离子缔合物 ,在聚乙烯醇存在下 ,在水溶液中显色。在波长 5 45 nm处 ,其摩尔吸光系数可达 2 .0 1× 10 5L· mol-1·cm-1。方法的回收率为 97%— 10 1% ,相对标准偏差为 0 .8%— 2 .7%。 相似文献
108.
提出一种反射式流通池用于过程分析光度检测系统 ,可以明显地抑制折光指数效应产生的干扰。以发光二极管为光源 ,采用多股光纤分别与流通池 ,光源 ,检测器耦合 ,实现对透射后反射回的光谱检测。以Cl- Hg(SCN) 2 Fe(Ⅲ )反应显色体系为模型对系统的实验参数进行了优化。讨论了试剂注入量、进样量、载流流速、试剂注入次序等参数对检测结果的影响。方法的线性范围为 0~ 10 0mg·L-1(相关系数r =0 998) ;分析精度 (RSD ,n =11)为 1 5 % ;检出限为 1 2mg·L-1;分析速度为 30个样·h-1;对自来水和海水的回收率分别为 95 %和 10 4 %。 相似文献
109.
StudyoftheThermalDiffusivityofOpticalCoatingbyPhoto-thermalDeformationTechnique¥ZHOUDongping;FANZhengxiu(ShanghaiInstituteofO... 相似文献
110.