K-g-框架扰动的稳定性

在Hilbert空间中定义了K-g-框架,研究了Hilbert空间中K-g-框架扰动的稳定性,利用分析与框架理论上的方法和技巧,得到了K-g-框架满足扰动稳定性的一些充分条件,所得的结论推广了g-框架扰动稳定性的相关结果.     

新型样品前处理材料在环境污染物分析检测中的研究进展

针对复杂样品的分析和痕量目标物的检测,样品前处理是必不可少的,高效的样品前处理技术不仅可以去除或减小样品基质干扰而且能够实现分析物的富集,提高分析检测的准确性和灵敏度.近年来,固相萃取、磁分散固相萃取、枪头固相萃取、搅拌棒萃取、固相微萃取等高效的样品前处理技术已在环境污染物分析检测中获得广泛关注,萃取效率主要取决于萃取...     

三维无溶剂含能Ag-MOF的制备、热分解动力学及爆炸性能

Solvent molecules can significantly reduce the heat of detonation and stability of energetic metal-organic framework (EMOF) materials, and the development of solvent-free EMOFs has become an effective strategy to prepare high-energy density materials. In this study, a solvent-free EMOF, [Ag₂(DTPZ)]_n (1) (N% = 32.58%), was synthesized by reacting a high-energy ligand, 2, 3-di(1H-tetrazol-5-yl)pyrazine (H₂DTPZ), with silver ions under hydrothermal conditions, and it was structurally characterized by elemental analysis, infrared spectroscopy, X-ray diffraction, and thermal analysis. In 1, the DTPZ²⁻ ligands that adopted a highly torsional configuration bridged the Ag⁺ ions in an octadentate coordination mode to form a three-dimensional framework (ρ = 2.812 g∙cm⁻³). The large steric effect and strong coordination ability of DTPZ²⁻ effectively prevented the solvent molecules from binding with the metal centers or occupying the voids of 1. Moreover, the strong π-π stacking interactions [centroid-centroid distance = 0.34461(1) nm] between the tetrazole rings in different DTPZ²⁻ ligands provided a high thermal stability to the framework (T_e = 619.1 K, T_p = 658.7 K). Thermal analysis showed that a one-step rapid weight loss with intense heat release primarily occurred during the decomposition of 1, suggesting potential energetic characteristics. Non-isothermal thermokinetic analyses (based on the Kissinger and Ozawa-Doyle methods) were performed using differential scanning calorimetry to obtain the thermoanalysis kinetic parameters of the thermodecomposition of 1 (E_a = 272.1 kJ·mol⁻¹, E_o = 268.9 kJ·mol⁻¹; lgA =19.67 s⁻¹). The related thermodynamic parameters [enthalpy of activation (ΔH^≠ = 266.9 kJ·mol⁻¹), entropy of activation (ΔS^≠ = 125.4 J·mol⁻¹·K⁻¹), free energy of activation (ΔG^≠ = 188.3 kJ·mol⁻¹)], critical temperature of thermal explosion (T_b = 607.1 K), and self-accelerating decomposition temperature (T_SADT = 595.8 K) of the decomposition reaction were also calculated based on the decomposition peak temperature and extrapolated onset temperature when the heating rate approached zero. The results revealed that 1 featured good thermal safety, and its decomposition was a non-spontaneous entropy-driven process. The standard molar enthalpy for the formation of 1 was calculated to be (2165.99 ± 0.81) kJ·mol⁻¹ based on its constant volume combustion energy determined using a precise rotating oxygen bomb calorimeter. Detonation and safety performance tests revealed that 1 was insensitive to impact and friction, and its heat of detonation (10.15 kJ·g⁻¹) was higher than that of common ammonium nitrate explosives, such as octogen (HMX), hexogene (RDX), and 2, 4, 6-trinitrotoluene (TNT), indicating that 1 is a promising high-energy and insensitive material.     

多元小波变换及L^2（R^p）框架

提出了一般形式不可分离变量的多元小波变换,通常的小汉变换只是本的特例,进而相应地构造了多元小波框架以及多元函数小波框架展开式。     

Hilbert空间H中G-框架等式

框架已获得广泛的应用,g-框架是框架的推广.本文运用算子理论方法,根据Hilbert空间H中的g-框架和g-框架算子的性质,得到有关g-框架的几个等式,给出一些有意义的结果.     

2种参数对预应力混凝土梁性能的影响分析

分析了跨高比、加载方式对预应力混凝土梁抗弯强度和结构性能的影响．利用平面梁弯曲理论导出单元切线刚度矩阵,提出了新的分析模型可用于预测预应力混凝土梁从开始加载直至失效的非线性全过程响应,并利用建立的分析模型详细评估了跨高比及加载方式等参数对预应力混凝土梁的弯曲强度和受力性能的影响．     

Bessel框架及其摄动

本文进一步研究了Bessel框架的性质,给出其稳定性和摄动的几个有意义的结果。     

多孔晶体材料的分子工程学研究

功能无机晶体材料的定向设计与合成是化学及材料科学领域中一项重要的前沿课题。本文介绍了近十几年来我们在多孔晶体材料,主要包括分子筛和金属有机骨架晶体材料的分子工程学研究方面所取得的一些进展。其中包括提出了定向设计具有特殊孔道结构和特殊计量比分子筛多孔骨架结构的计算机方法;在国际上率先建立了分子筛多孔晶体材料合成与结构数据...     

有效预应力对大跨P.C.桥梁极限承载力的影响研究

采用三维实体退化虚拟层合单元理论探讨了有效预应力对大跨P.C.桥梁极限承载力的影响.针对不同的有效预应力水平,以一座典型的预应力混凝土连续刚构桥为例,采用三维精细化有限元模型,对其极限承载力进行了空间分析计算和讨论.分析表明,有效预应力对大跨P.C.桥梁极限承载力有较大影响,其中,纵向预应力筋有效预应力与竖向预应力筋有效预应力的比例是影响桥梁极限承载力的重要参数.大跨P.C.桥梁结构设计时应充分重视这一问题.