Relativistic R-matrix studies of photoionization processes of Ar^5＋

The 3s–np photoionization processes of the ground state 2P1/2 and the metastable state 2P3/2 of Ar5＋ are investigated using our recently developed relativistic R-matrix code, where the interactions between the bound states and the continuum states are included. Both resonance positions and the oscillator strengths are in much better agreement with the absolute experimental measurements by Wang et al.[Wang J C, Lu M, Esteves D, Habibi M, Alna’washi G and Phaneuf R A 2007 Phys. Rev. A 75 062712] with a resolution of 80 meV than their theoretical results. The contributions of the two experimental unresolved transitions are distinguished in our calculations, which show that the transitions from the ground state also make significant contributions to some resonances. Our theoretical results are also in good agreement with the measurements for the first resonance with a higher resolution of 20 meV.     

丙烯腈-尿素包合物的形成过程及特征

利用差示扫描量热法(DSC)和X射线衍射(XRD)研究了在不同丙烯腈/尿素投料比情况下的丙烯腈-尿素包合物的形成过程和组成. 实验结果表明DSC是一种研究包合物的客主比及分解热的有效方法. 测定了丙烯腈-尿素包合物的客主比和分解热分别为1.17和5361.53 J/mol. 同时发现丙烯腈-尿素包合物的形成依赖于冷冻时间,在足够长的冷冻时间之后丙烯腈-尿素包合物的组成达到稳定状态. 实验结果表明,丙烯腈分子可能是采用堆叠的方式排布在尿素晶道结构中. XRD结果表明只要丙烯腈分子进入尿素晶格中,丙烯腈-尿素包合物的结构便形成了,并且这种结构与形成过程终了时的结构是一致的. 只要丙烯腈是足量的,包合物中的丙烯腈分子排列会随冷冻时间的延长而增长,直到尿素的晶道结构被丙烯腈分子填满.     

An image joint compression-encryption algorithm based on adaptive arithmetic coding

Through a series of studies on arithmetic coding and arithmetic encryption, a novel image joint compression- encryption algorithm based on adaptive arithmetic coding is proposed. The contexts produced in the process of image compression are modified by keys in order to achieve image joint compression encryption. Combined with the bit-plane coding technique, the discrete wavelet transform coefficients in different resolutions can be encrypted respectively with different keys, so that the resolution selective encryption is realized to meet different application needs. Zero-tree coding is improved, and adaptive arithmetic coding is introduced. Then, the proposed joint compression-encryption algorithm is simulated. The simulation results show that as long as the parameters are selected appropriately, the compression efficiency of proposed image joint compression-encryption algorithm is basically identical to that of the original image compression algorithm, and the security of the proposed algorithm is better than the joint encryption algorithm based on interval splitting.     

Effects of clouds, sea surface temperature, and its diurnal variation on precipitation efficiency

The effects of clouds, sea surface temperature, and its diurnal variation on precipitation efficiency are investigated using grid-scale data from nine equilibrium sensitivity cloud-resolving model experiments driven without large-scale vertical velocity. The precipitation efficiencies are respectively defined in surface rainfall, cloud, and rain microphysical budgets. We mathematically and physically demonstrate the relationship between these precipitation efficiencies. The 2℃ increases in spatiotemporal invariant sea surface temperature (SST) from 27℃ to 29℃ and from 29℃ to 31℃, and the inclusion of diurnal SST difference 1℃ and the 1℃ increase in diurnal SST difference generate opposite changes in the precipitation efficiency by changing ice cloud-radiation interactions. The radiative and microphysical processes of ice clouds have opposite effects on the precipitation efficiency because of the rainfall increase associated with the reduction in the saturation mixing ratio caused by the exclusion of radiative effects and the decrease in rainfall related to the reduction in net condensation caused by the exclusion of deposition processes. The radiative effects of water clouds on the precipitation efficiency are statistically insensitive to the radiative effects of ice clouds.     

《发光学报》征稿简则

一、《发光学报》是中国物理学会发光分会主办的,以凝聚态物质中的激发态过程研究为专业方向的综合性学术刊物。它的任务是反映各学科间该专业研究领域的科研和技术成就,及时报道国内、外的学术动态,开展学术讨论和交流,提高从事各学科间该研究领域工作的专业人员的专业知识水平,为提高我国该学科的学术水平服务。     

X-ray spectra of high temperature tungsten plasma calculated with collisional radiative model

Tungsten is regarded as an important candidate of plasma facing material in international thermonuclear experimental reactor （ITER）, so the determination and modeling of spectra of tungsten plasma, especially the spectra at high temperature were intensely focused on recently. In this work, using the atomic structure code of Cowan, a collisional radiative model （CRM） based on the spin-orbit-split-arrays is developed. Based on this model, the charge state distribution of tungsten ions is determined and the soft X-ray spectra from high charged ions of tungsten at different temperatures are calculated. The results show that both the average ionization charge and line positions are well agreed with others calculations and measurements with discrepancies of less than 0.63% and 1.26%, respectively. The spectra at higher temperatures are also reported and the relationship between ion abundance and temperature is predicted in this work.     

Advanced control and modeling of deposition processes

During the last decade, striking improvements could be achieved for the precise control of deposition processes in optical coating technology. For example, as a consequence of enormous progresses in measure- ment and computer technology, direct optical monitoring in a broad spectral range can be considered as a common tool in many production environments nowadays. Besides the development of the corresponding hardware and measurement channels, advanced approaches for the evaluation of the acquired data and new multiple sensor monitoring strategies moved into the focus of modern research on the way towards de- terministic deposition techniques. In this context, also innovative concepts for the simulation of deposition processes to forecast the result for a specified coating design and automatic online correction algorithms gained of importance to reduce the risk of failure in coating production. The present contribution will be dedicated to selected aspects in this field, especially addressing broad band optical monitoring systems. A short review on examples for existing hardware configurations and software tools will be presented illus- trating the advantages of modern process control techniques. Novel approaches based on the modeling of thin film growth are discussed as an additional strategy to improve the predictability of coating processes.     

Cross section of the impact single ionization of B2＋ by H＋

The ionization process of B2+ by H+ impact is studied using the continuum-distorted-wave eikonal-initial-state (CDW-EIS) method and the modified free electron peak approximation (M-FEPA), respectively. Total, single-, and double- differential cross sections from 1s and 2s orbitals are presented for the energy range from 10 keV/u to 10 MeV/u. Comparison between the results from the two methods demonstrates that the total and single-differential cross sections for the high-energy incident projectile case can be well evaluated using the simple M-FEPA model. Moreover, the M-FEPA model reproduces the essential features of the binary-encounter (BE) bump in the double-differential cross sections. Thus, the BE ionization mechanism is discussed in detail by adopting the M-FEPA model. In particular, the double- and single-differential cross sections from the 2s orbital show a high-energy hip, which is different from those from the 1s orbital. Based on Ref. [1], the Compton profiles of B2+ for 1s and 2s orbitals are given, and the hips in DDCS and SDCS from the 2s orbital are explained.     

Densification and lithium ion conductivity of garnet-type Li7-xLa3Zr2-xTaxO12 （x=0.25） solid electrolytes

The garnet-type Li7La3Zr2O12 ceramic is a promising solid electrolyte for all-solid-state secondary lithium batteries. However, it faces the problem of lithium volatilization during sintering, which may cause low density and deterioration of ionic conductivity. In this work, the effects of sintering temperature and addition on the density as well as the lithium ion conductivity of Li7-xLa3Zr2-xTaxO12 (LLZTO, x=0.25) ceramics prepared by solid state reaction have been studied. It is found that optimization of the sintering temperature leads to a minor increase in the ceramic density, yielding an optimum ionic conductivity of 2.9×10-4 S·cm-1 at 25℃. Introduction of Li 3 PO 4 addition in an appropriate concentration can obviously increase the density, leading to an optimum ionic conductivity of 7.2×10-4 S·cm-1 at 25℃. This value is superior to the conductivity data in most recent reports on the LLZTO ceramics.     

稀疏降噪自编码结合高斯过程的近红外光谱药品鉴别方法

提出一种稀疏降噪自编码结合高斯过程的近红外光谱药品鉴别方法。首先对近红外光谱数据进行小波变换以消除基线漂移,然后用稀疏降噪自编码(SDAE)网络提取光谱特征并降维表示,最后采用高斯过程(GP)进行二分类,其中GP选用光谱混合(SM)核函数作为协方差函数,记此分类网络为wSDAG_SM。自编码网络具有很强的模型表示能力,高斯过程分类器在处理小样本数据时具有优势。wSDAG_SM网络通过稀疏降噪自编码学习得到维数更低但更有价值的特征来表示输入数据,同时将具有很好表达力的光谱混合核作为高斯过程的协方差函数,有利于更准确的光谱数据分类。以琥乙红霉素及其他药品的近红外光谱为实验数据,将该方法与经过墨西哥帽小波变换的BP神经网络(wBP)、支持向量机(wSVM), SDAE结合Logistic二分类(wSDAL)、SDAE结合采用平方指数(SE)协方差核的GP二分类(wSDAG_SE),以及未采用小波变换的SDAG_SM网络等方法进行对比。实验结果表明,对光谱数据进行墨西哥帽小波变换预处理能有效提升SDAG_SM网络的分类准确率和稳定性。wSDAG_SM方法无论从分类准确率还是分类结果稳定性方面,都优于其他分类器。