T2铜的低温比热

在1.4—27K的温区内测量了纯度为99.9％的国产T_2铜的比热,得出了T_2铜的电子比热系数γ为0.68mJ·mol_(-1)·K_(-2),德拜温度θ_D为339.7K。与国外的比热数据比较,显然在纯度相同的条件下,比热数据是一致的,且可以互换。     

铁电单晶Pb(Mg1/3Nb2/3)O3-PbTiO3的高场致应变及其在层叠式驱动器中的应用

通过研究(1-x)Pb(Mg1/3Nb2/3)O3-xPbTiO3 (PMNT)单晶在不同方向、不同组分下高场致应变的特性,确定了〈001〉取向PMNT单晶(29%≤x≤31%)为制作层叠式驱动器的最佳组分范围,这组分的单晶具有高场致应变、低滞后而且性能较稳定的特点.研究结果表明,在保证应变曲线的线性和低滞后的前提下,将近-2kV/cm的负电场能够运用于〈001〉方向的PMNT晶体上. 40层(每片晶片尺寸为7mm×7mm×0.7mm)PMNT层叠式驱动器在电场 -1.5-10kV/cm的驱动下,可以获得38.1μm的纵向位移,负载40N的重量后,位移量减为34μm.     

新型二硫纶·菲咯啉-5，6-二酮合铜(Ⅱ)配合物的磁性研究

报道了新合成的二氰基二硫纶·菲咯啉-5，6-二酮合铜(Ⅱ)配合物CuLL′(L=mnt^2-, 1,2-dicyano-1,2-ethylenedithiolate; L′=phen-5，6-dione, 1,10-phenanthroline-5,6-dione)的变温磁化率和电子顺磁共振波谱表征结果. 发现微晶粉体型的标题配合物CuLL′具有一定的顺磁性，形成四配位的近似于方形的结构. 探讨了这种配合物磁学特性与结构的关系.     

Crystal Structures of Two Potential Tumor Imaging Agents and Therapeutic Agents Copper（Ⅱ） Ternary Complexes with Salicylidene-tyrosinato Schiff Base and Nitrogen-donor Chelating Lewis Base

The crystal structures of two potential tumor imaging agents and therapeutic agents -copper(Ⅱ) complexes with salicylidene-tyrosinato Schiff base and nitrogen-donor chelating Lewis base, [Cu(sal-tyr)(bipy)] 1 and [Cu(sal-tyr)(phen)]2CH3OH 2 are presented. Our work is helpful to get deep understanding of novel 64Cu tumor imaging agents and therapeutic agents.     

支气管灌洗液中铜锌含量及铜／锌比值的观察

用原子吸收光谱法检测了肺癌患者灌洗液中铜、锌含量及铜／锌比值。结果表明：中央型肺癌组与肺部良性疾病组比较均有极显著差异；与周围型比较，铜、铜／锌具有显著性差异；而周围型肺癌组与良性组比较，除铜／锌比值有显著性差异，Ｃｕ、Ｚｎ均无统计学意义差异。     

Study on the in—plane electrical resistivity and thermoelectric power in single crystals of La2—xBaxCuO4

The in-plane electrical resistivity and thermoelectric power have been measured on single crystals of La_2-xBa_xCuO₄ at around x=0.125. The room temperature resistivity and thermopower have their maximum values at x=0.125, indicating that the carrier concentration is the minimum and the carriers are most strongly localized at x=0.125. The observed semiconductor-like behaviour can be well described by the weak-localized quasi-two-dimensional state. The steep rise in electric resistivity of the sample at x=0.125 below 70K is attributed to the formation of static stripe-order of holes and spins, which are pinned by the low-temperature tetragonal (LTT) structure, as discovered in La_1.48Nd_0.4Sr_0.12CuO₄. The temperature dependence of electric resistivity below 70K is still well described by the formula ρ∝ lnT. A definite change in the slope of thermopower is observed at the low-temperature orthorhombic-LTT structural phase transition temperature. The origin of the 1/8 anomaly is discussed in the text.     

一种锰铜压阻测量新方法

 简单分析了几种常用的恒流供电锰铜压阻测量方法，并对这些测试方法的特点和不足进行了讨论。最后介绍一种利用数字示波器进行高保真高精度测量的方法，利用此法不仅提高了压力测量的精度，并且把小阻值锰铜压力计的测量范围向低端扩展到0.17 GPa。