Ab initio calculations of accurate dissociation energy and analytic potential energy function for the second excited state B1∏ of 7LiH

The reasonable dissociation limit of the second excited singlet state B¹∏ of ⁷LiH molecule is obtained. The accurate dissociation energy and equilibrium geometry of the B¹\Pi state are calculated using a symmetry-adapted-cluster configuration--interaction method in full active space. The whole potential energy curve for the B¹∏ state is obtained over the internuclear distance ranging from about 0.10nm to 0.54nm, and has a least-square fit to the analytic Murrell--Sorbie function form. The vertical excitation energy is calculated from the ground state to the B¹∏ state and compared with previous theoretical results. The equilibrium internuclear distance obtained by geometry optimization is found to be quite different from that obtained by single-point energy scanning under the same calculation condition. Based on the analytic potential energy function, the harmonic frequency value of the B¹∏ state is estimated. A comparison of the theoretical calculations of dissociation energies, equilibrium interatomic distances and the analytic potential energy function with those obtained by previous theoretical results clearly shows that the present work is more comprehensive and in better agreement with experiments than previous theories, thus it is an improvement on previous theories.     

A Unified Model of Magnetic Extraction of Spin Energy from a Black Hole

A unified model of magnetic extraction of spin energy from a black hole in discussed based on the theory of black hole magnetosphere.The magnetic extracting power is expressed by a unified formula,which is applicable to bloth the Blandford-Znajek (BZ) process and the magnetic coupling (MC) process.The strength and characteristics of the BZ power and the MC power are compared in detail.In addition,the impedance matching condition for the BZ power is extended to the more general case.     

A MEMS-Based Piezoelectric Power Generator for Low Frequency Vibration Energy Harvesting

A novel power generator has been achieved to convert vibration to electrical energy via the piezoelectric effect. The generator obtained by micro fabrication process mainly consists of silicon based frame and composite cantilever. The prototype tested at resonant vibration generates 1.15μW of effective power to a 20.4-kΩ resistance load. The potential of this work is to offer miniaturization solutions for power generators, and with the proposed method the ambient ubiquitous vibration can be harvested effectively as endless energy source to form an integrated self-powering system.     

仲态电子偶素湮没辐射能量的改进测量

用充氧气的气凝硅胶作仲态电子偶素源,用¹⁹²Ir精密γ能量作标准,以时间选择能谱仪和滑动比较法改进测量仲态电子偶素2γ湮没能量,得到hv=510995.34±0.69eV.经电子偶素结合能修正,得正、负电子对静止质量,与电子质量比较,表明正、负电子质量在1.4ppm内一致.     

纳米晶Y_2SiO_5∶Eu的浓度猝灭研究

报道了分别用溶胶－凝胶法合成的Ｙ２ＳｉＯ５∶Ｅｕ纳米晶和用高温固相法合成常规尺度的Ｙ２ＳｉＯ５∶Ｅｕ材料的光致发光光谱和猝灭浓度的实验研究．结果表明：纳米Ｙ２－ｘＥｕｘＳｉＯ５比常规尺度的Ｙ２－ｘＥｕｘＳｉＯ５有更高的猝灭浓度和更高的发光亮度．理论分析认为这是由于在纳米材料中能量共振传递被阻断和猝灭中心在各个纳米晶内分布的涨落造成的．这个结果为高亮度的Ｙ２ＳｉＯ５∶Ｅｕ纳米材料的实际开发应用展示了广阔前景．     

排列组合解题二三法

排列组合解题二三法陈宗洵（福建师范大学数学系３５０００７）排列组合的题目疑多乖戾，似无常法，暑假“陪读”偶有所得，整理成文敬飨读者，谨供参考．ＩＮ度法排列组合问题可视为按某种规则抽取元素的试验，确定试验所有不同结果的数目，我们可以把这种试验的若干结果...     

斜拉输水结构分析的能量方法

本文用迭代法对由拉索支承的梁(槽身)的位能进行迭代.通过算例证明,只需取 Fourier 级数前几项就足够,迭代是收敛的.能量法分析斜拉输水结构速度快,方法简单,为该种结构的分析和结构优化提供了近似结构重分析的新方法.     

DV4型光谱仪两种故障的处理

美国ＢＡＩＲＤ公司生产的ＤＶ4光谱仪 ,在ＣＭＵ 2 0元素板上有 8个通道 ,元素板的总数由仪器中的光电倍增管总数决定 ,最多可分析 32个元素。我公司自 1986年以来 ,先后购进两台美国ＢＡＩＲＤ公司生产的ＤＶ4光谱仪。该仪器具有自动化程度高、选择性好、操作简单 ,分析速度快 ,可同时进行多元素定量分析 ;校准曲线线性范围宽 ,精度高 ,检出限低。我公司该仪器主要用于转炉、电炉钢包钢样的化学成分 (碳、硅、锰、磷、硫、镍、铬、铜、锡、钼、钒 )分析。在使用过程中出现过一些故障 ,均妥善地进行了处理并解决了存在的问题。以下为典型故…     

Studies on fluorenscence resonance energy transfer between CdS nanoparticles and DOCAI dyes

The water-soluble CdS nanoparticles were synthesized in aqueous solution. A novel fluorescence resonance energy transfer (FRET) system with CdS nanoparticles as energy donors and 3,30-diethyl-oxadicarbocyanine iodide (DOCAI) dyes as energy accepter has been developed.     

MOLECULAR ENGINEERING STUDIES ON NONTHROMBOGENIC BIOMATERIALS——A NOVEL CLASS OF NONTHROMBOGENIC BIOMATERIALS WITH ZWITTERIONIC STRUCTURE OF CARBOXYBETAINES

N,N-dimethyl-N-methacryloyloxyethyl-N-carboxyethyl ammonium (DMMCA) was graft-copolymerized onto the surface of segmented poly(ether urethane) (SPEU) and PE film. The carboxybetaine structure on SPEU and PE film surfaces was confirmed by ATR-FTIR, XPS and water contact angle measurements. Through the experiments with platelet adhesion and protein adhesion assay in vitro, the two materials studied, including poly-DMMCA gel, all show excellent nonthrombogenicity. This confirms once again that the zwitterionic molecular structure on the surfaces of materials is essential for improving their nonthrombogenicity and biocompatibility.