全文获取类型
收费全文 | 5171篇 |
免费 | 758篇 |
国内免费 | 3974篇 |
专业分类
化学 | 7552篇 |
晶体学 | 153篇 |
力学 | 449篇 |
综合类 | 82篇 |
数学 | 125篇 |
物理学 | 1542篇 |
出版年
2024年 | 52篇 |
2023年 | 190篇 |
2022年 | 216篇 |
2021年 | 228篇 |
2020年 | 203篇 |
2019年 | 243篇 |
2018年 | 149篇 |
2017年 | 249篇 |
2016年 | 293篇 |
2015年 | 257篇 |
2014年 | 606篇 |
2013年 | 602篇 |
2012年 | 441篇 |
2011年 | 512篇 |
2010年 | 456篇 |
2009年 | 491篇 |
2008年 | 492篇 |
2007年 | 477篇 |
2006年 | 409篇 |
2005年 | 418篇 |
2004年 | 381篇 |
2003年 | 346篇 |
2002年 | 316篇 |
2001年 | 288篇 |
2000年 | 201篇 |
1999年 | 194篇 |
1998年 | 167篇 |
1997年 | 161篇 |
1996年 | 168篇 |
1995年 | 116篇 |
1994年 | 76篇 |
1993年 | 107篇 |
1992年 | 98篇 |
1991年 | 84篇 |
1990年 | 82篇 |
1989年 | 79篇 |
1988年 | 33篇 |
1987年 | 12篇 |
1986年 | 4篇 |
1985年 | 1篇 |
1983年 | 3篇 |
1982年 | 2篇 |
排序方式: 共有9903条查询结果,搜索用时 31 毫秒
11.
A positive Mg-Al-nitrate layered double hydroxides(LDHs) has been synthesized using a non-steady coprecipitation method.The shape.size,chemical composition,electrical property and anion exchange property of the positve nanoparticle were studied by SEM,XRD,FTIR,chemical analysis,spectroanalysis and meaxsuring of electrophoretic mobilities.Preliminary results show the positive nanoparticle is a promising precursor of polymer/LDHs nanocomposite. 相似文献
12.
利用旋涂法,通过接枝共聚的方法制备了具有偶氮侧基的聚氮酯高分子聚合物薄膜。并利用二倍频YAG激光(532nm)作为激发光,白光光源作为参考光,在室温下测试了该薄膜在激发光作用前后的吸收光谱,发现该薄膜在430nm-530nm内有较强的吸收。以及随着激光能量的增大和撤去激发光后,随着无光照时间的延长,360nm与500nm波长处吸收强度的变化趋势。 相似文献
13.
Exact Solution of an Extended Hubbard Model with Electron—Lattice Interaction for an Organic Ferromagnetic Polymer
下载免费PDF全文
![点击此处可从《中国物理快报》网站下载免费的PDF全文](/ch/ext_images/free.gif)
Using an exact diagonalization method,we study an extended Hubbard model with an electron-lattice interaction for an organic ferromagnetic chain with radical coupling.The result shows that the ferromagnetic ground state originates from the antiferromagnetic correlation between adjoining sites,which is enhanced by the on-site e-e repulsion.The intersite e-e repulsion induces the inhomogeneous distribution of the charge density.The dimerization is decreased by the e-e interaction and the radical coupling.The electron-lattice interaction and the radical coupling can transfer the spin density and charge density between the main chain and the radicals. 相似文献
14.
15.
Self-assembly behaviour of amphiphilic diblock copolymer in selective solvents studied by synchrotron small-angle x-ray scattering
下载免费PDF全文
![点击此处可从《中国物理》网站下载免费的PDF全文](/ch/ext_images/free.gif)
The aggregation behaviour of styrene-vinyl benzoic acid (PSm-b-PVBAn) amphiphilic diblock copolymers in selective solvents with different m and n was investigated by synchrotron small-angle x-ray scattering (SAXS). We have carried out a detailed analysis of scattering intensity, dimension, shape and microstructure of the diblock copolymers of narrow distribution in water, methanol, ethanol and isopropanol selective solvents, respectively. We have found that the aggregation behaviour of the copolymer depends on the nature of the solvent and the micelle forms fiat disc objects with the ratio of radius ω=0.4. The average radius gyration Rg of the copolymer decreases as solvents change from isopropanol to ethanol and to methanol, and increases with increasing pH in aqueous solution, but decreases with the addition of COCl2 in ethanol solvent. The scattering intensity of diblock copolymer micelle follows I(h) ∝ h^-α in different selective solutions, suggesting that the PSm-b-PVBAn coils have self-similar structure behaviour or a fractal structure in the selective solvents. All of these revealed that the aggregation behaviour of the diblock copolymer changes dramatically with experimental condition in the selective solvent. The increase of mass fractal dimension (Dm) from 2.12 to 2.47 indicates that the copolymer chain changes from a swollen coil to a rather compact disc in the course of changing solvents, decreasing surface fractal dimension (Ds) from 2.98 to 2.58 indicates that the copolymer micelle change from a rather rough surface to a smooth form in the course of increasing pH in aqueous solutions, and increasing Dm and Ds from 2.29 to 2.35 and 2.70 to 2.90, respectively, indicates the shrinkage of copolymer micelle to a rather compact and rough disc form by adding COCl2 in ethanol solvents. 相似文献
16.
17.
研究玉米淀粉接枝聚丙烯酸酯共聚物的各级结构,主要探讨去除均聚物和玉米淀粉侧链的方法。发现以环己烷为溶剂,用索氏萃取法除去均聚物比用苯萃取法时间短、效果好;用HCl酸解法除去淀粉侧链比用HClO4氧化法简单实用。用红外光谱进一步验证了各级结构的官能团,证实了所合成的共聚物是玉米淀粉接枝聚丙烯酸酯共聚物。 相似文献
18.
Controlling the gain shape of Er^3+—doped fluorozirconate fibre amplifier by a coherent field
下载免费PDF全文
![点击此处可从《中国物理》网站下载免费的PDF全文](/ch/ext_images/free.gif)
We proposed a four-level system to explore the quantum interference effects on optical amplification.We found that the gain of the probe.including positions and values of gain peaks,can be adjusted by changing the coherent field and the incoherent pumping.At the same time,we can also modify the absorption profile of electromagnetically induced transparency by the incoherent pump.The results provide a method to flatten the gain of Erbium-doped fibre amplifiers. 相似文献
19.
本文以交联的氯甲基化聚苯乙烯树脂为原料,合成了四种类型的含两个带α-H碳原子的季鏻盐树脂(Ⅰ)、(Ⅱ)、(Ⅲ)、(Ⅳ),它们在碱的作用下,与醛的Wittig反应表现出不同的位置选择性:季鏻盐树脂(Ⅰ)和(Ⅳ)与醛反应只生成带烯键的聚合物;季鏻盐树脂(Ⅲ)与醛反应只生成低分子烯烃产物;而季鏻盐树脂(Ⅱ)与醛反应则生成低分子烯烃产物又生成带烯键的聚合物。 相似文献
20.
RupingZou AibingYu 《中国颗粒学报》2003,1(1):27-32
The initial forming of fiber blend to high green density, i.e. the packing of fibrous particles, is important to the reinforcement of composite materials. It is very useful to develop a general predictive method for the optimum selection of particle mixtures for the property control of ceramic or composite products. This paper presents such a mathematical model developed on the basis of the similarity analysis between the spherical and non-spherical particle packings and assesses its applicability to the packing of fibrous particles with discrete and/or continuous length distributions. The results indicate that the model can predict this packing system well and hence provide an effective way to solve various packing problems in the composite materials processing. 相似文献