球形充气液泡所带电量及系统能量变化的分析

本文分析了球形充气液泡所带的电量,推导出一个较为普遍的计算公式,并分析了整个系统的能量变化关系.     

Linear and Nonlinear Optical Absorptions of a Donor Impurity in Spherical Quantum Dots

An investigation of the optical properties of a hydrogenic donor in spherical parabolic quantum dots has been performed by using the matrix diagonalization method. The optical absorption coefficient between the ground （L = 0） and the first excited state （L = 1） have been examined based on the computed energies and wave functions. The results are presented as a function of the incident photon energy for the different values of the confinement strength. These results show the effects of the quantum size and the impurity on the optical absorption coefficient of a donor impurity quantum dot.     

球形Taylor-Couette流分叉解的数值模拟研究

用差分方法求解轴对称定常不可压N-S方程,对内球旋转、外球不动的两同心球(间隙比σ=0.18)之间的流体在Re_c_1≤1 500范围内的定常分叉流动进行了数值模拟。模拟结果表明在775≤Re≤1 220时可以存在稳定的1-涡和2-涡两种流态,而在1 220<Re≤1500时可以存在稳定的0-涡,1-涡和2-涡3种流态.同一Re数下不同流态的形成和初始条件有关,而用不同的内球角加速度可以得到不同的初始条件.     

A Geometry Model for Tortuosity of Streamtubes in Porous Media with Spherical Particles

A geometry model for tortuosity of tortuous streamtubes in porous media with spherical particles is proposed based on the assumption that some particles in a porous medium are unrestrictedly overlapped and hence of different configurations. The proposed model is a function of porosity with no empirical constant imposed on it.The model predictions are found to be in good agreement with the available experimental data.     

Linear and Nonlinear Optical Properties in Spherical Quantum Dots

We calculate the energy eigenvalues and the sate functions of one-electron Quantum Dot （QD） by using a combination of Quantum Genetic Algorithm （QGA） and Hartre-Fock-Roothaan （HFR） method. The linear and the third-order nonlinear optical absorption coefficients for the 1s-1p, 1p-1d, and 1d-1f transitions are examined as a function of the incident photon energy for three different values of the stoichiometric ratio. The results show that the stoichiometric ratio, impurity, relaxation time, and dot size have great influence on the optical absorption coefficients of QDs.     

Dielectric Response of Graded Spherical Composites

We investigate the effective dielectric responses of graded spherical composites under an external uniform electric field by taking the dielectric function of spherical inclusion, εi = cr^ke^βr, where r is the inner distance of a point inside the particle from the centre of the spherical particle in the coordination. In the dilute limit, our exact result is used to test the validity of differential effective dipole approximation （DEDA） for estimating the effective response of graded spherical composites and it is shown that the DEDA is in excellent agreement with the exact result.     

球形压痕的残余变形分析(英文)

球形压痕技术在材料力学属性,诸如硬度,弹性模量等的测量中得到了广泛的应用。应用Twyman-Green及云纹干涉法并配合相移技术,本文对IN783合金进行了一系列的球形压痕实验研究,并对残余压痕的面内(u, v)及离面( w)变形场进行了定量测量和分析。应用面内变形测量结果,进一步对试件表面的应力-应变分布进行了分析和计算,并在离面变形场的基础上,确立了压痕周围的弹塑性边界,从而进一步应用面内的分析结果,得到材料的屈服强度。应用压痕实验的接触半径和压力并配合Tabor经验公式,本文进一步得到了材料的应力应变曲线。实验结果与已知的IN783合金相吻合。对所涉及的一系列压痕实验,本文也进行了二维有限元分析并得到了比较一致的结果。     

球形纤维素吸附剂对Cu~(2+)的吸附动力学与热力学研究

以离子液体([Bmim]Cl)为反应介质,丙烯酸为单体,对纤维素进行均相接枝共聚,并采用油包水反相悬浮技术制得球形纤维素吸附剂。采用静态吸附实验方法研究了该吸附剂对水溶液中Cu2+的吸附性能,包括各种因素(溶液pH值,溶液初始浓度,吸附时间,吸附温度)对吸附效果的影响。研究结果表明,适当提高溶液pH值,增加溶液初始浓度,以及延长吸附时间都有利于改善吸附效果;球形纤维素吸附剂对Cu2+的吸附符合Langmuir吸附等温式,吸附过程是自发的放热过程;吸附剂对Cu2+的吸附符合二级吸附动力学模型,吸附过程由膜扩散和颗粒内扩散联合控制。球形纤维素吸附剂对Cu2+的具有很好的吸附性并具有良好的再生性能,可以循环使用。     

离子热合成微球方钠石

在1-甲基-3-乙基咪唑溴盐离子液体([emim]Br)中合成了球形的方钠石分子筛,分别通过X射线衍射仪(XRD)和扫描电子显微镜(SEM)等表征手段对产物进行了表征。结果表明,在反应物料配比相同的条件下,离子热合成有利于球形方钠石结构的形成。在反应物料中nNa2SiO3·9H2O/nNaAlO2为1.1(即nSiO2/nAl2O3=2.2)和5.0时(即nSiO2/nAl2O3=10)时,离子热合成得到了粒径为0.2和1.4μm的球形方钠石分子筛,而水热合成分别得到了X型分子筛和一种未知结构的产物。     

溶胶-凝胶法制备纳米氮化钒的研究

氮化钒(VN)具有十分高的热、化学稳定性和强的机械性能,广泛用于切削工具、磨具和结构材料;也是一种良好的催化剂,具有高催化活性、高选择性、良好的稳定性和抗中毒性能.细粒度的VN能有效提高催化活性,改善结构材料的韧性[1].传统上VN应用NH4VO3在NH3气氛中氨解,需要在1100℃下加热12h,冷却并研磨物料,再氨解12h,仅能获得90%的微米级VN粉体[2].