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21.
采用Perkin Elmer公司的Diamond TMA热机械分析仪对KDP/DKDP晶体在25~100℃范围内的平均线性热膨胀系数进行了研究.得到KDP/DKDP晶体x切向、z切向、Ⅰ类切向和Ⅱ类切向的平均线性热膨胀系数,分别为:KDP(2.454×10-5/℃、4.168×10-5/℃、3.465×10-5/℃和2.884×10-5/℃),DKDP(2.602×10-5/℃、4.284×10-5/℃、3.568×10-5/℃和3.052×10-5/℃).另外,实验结果表明大尺寸KDP/DKDP晶体不同部位热膨胀系数存在不均匀性. 相似文献
22.
Phase Transition and Thermodynamics of Ruthenium Diboride via First-Principles Calculations
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The pressure induced phase transitions of RuB2 from the OsB2-type structure to the ReB2-type structure are investigated by first-principles calculations based on the plane-wave basis set with the generalized gradient ap- proximation for exchange and correlation. It is found that the phase transition occurs at 18.6 GPa. We predict the phase transition from the OsB2-type RuB2 to the ReB2-type RuB2 at high temperatures for the first time. The dependences of the heat capacity, thermal expansion coefficient, and the Grüneisen parameter on pressure and temperature for OsB2-type RuB2 and ReB2-type RuB2 are also investigated. 相似文献
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考虑到原子非简谐振动和电子-声子相互作用,用固体物理理论和方法研究了石墨烯格林艾森参量和低温热膨胀系数以及声子弛豫时间随温度的变化规律,探讨了原子非简谐振动项对它们的影响.结果表明:1)在低于室温的温度范围内,石墨烯的热膨胀系数为负值,随着温度的升高,其热膨胀系数的绝对值单调增加,室温热膨胀系数为-3.64×10~(-6)K~(-1);2)简谐近似下的格林艾森参量为零.考虑到非简谐项后,格林艾森参量在1.40-1.42之间并随温度升高而缓慢增大,几乎成线性关系,第二非简谐项对格林艾森参量的影响小于第一非简谐项;3)石墨烯声子弛豫时间随着温度的升高而减小,其中,温度很低(T10 K)时变化很快,此后变化很慢,当温度不太低(T300 K)时,声子弛豫时间与温度几乎成反比关系. 相似文献
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Phase transition and thermal expansion property of Cr_(2-x)Zr_(0.5x)Mg_(0.5x)Mo_3O_(12) solid solution
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Compounds with the formula Cr2-xZr0.5xMg0.5xMo3O12(x = 0.0, 0.3, 0.5, 0.9, 1.3, 1.5, 1.7, 1.9) are synthesized, and the effects of Zr4+ and Mg2+ co-incorporation on the phase transition, thermal expansion, and Raman mode are investigated. It is found that Cr2-xZr0.5xMg0.5xMo3O12 crystallize into monoclinic structures for x 〈 1.3 and orthorhombic structures for x _〉 1.5 at room temperature. The phase transition temperature from a monoclinic to an orthorhombic structure of Cr2Mo3O12 can be reduced by the partial substitution of (ZrMg)6+ for Cr3+. The overall linear thermal expansion coefficient decreases with the increase of the (ZrMg)6+ content in an orthorhombic structure sample. The co-incorporation of Zr4+ and Mg2+ in the lattice results in the occurrence of new Raman modes and the hardening of the symmetric vibrational modes, which are attributed to the MoO4 tetrahedra sharing comers with ZrO6/MgO6 octahedra and to the strengthening of Mo-O bonds due to less electronegativities of Zr4+ and Mg2+ than Cr3+, respectively. 相似文献
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The nonlinear Schrodinger equation is proved to be consistent-tanh-expansion (CTE) solvable. Some types of dark soliton solutions dressed by cnoidal periodic waves are obtained by means of the CTE method. 相似文献
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Most thin films have different thermal expansion coefficients from their substrates, thus thermal stresses will be introduced into the films when the temperature is changed during annealing and service. Calculations of these stresses for grains in various crystallographic orientations have been made for seven BCC transition metals Cr, Fe, Mo, Nb, Ta, V and W. Neglecting W, which is isotropic and the stresses are equiaxial and without grain orientation (hkl) dependence, the BCC metals may be grouped into two classes. In the first class (Cr, Mo, Nb and V), the (100)-oriented grains have the largest stresses, while the stresses σ1 and σ2 in other (hkl)-oriented grains decrease linearly with the increase of the angle between (hkl) and (100), and with σ1 〈 σ2 except in (100)- and (lll)-oriented grains. In the second class (Fe and Ta), on the contrary, the (100)-oriented grains have the lowest stresses, and the stresses σ1 and σ2 in other (hkl)-oriented grains increase linearly with the increase of the angle between (hkl) and (100), and with σ1 〉 σ2 except in (100)- and (111)-oriented grains. 相似文献
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