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1.
The analysis of mechanical structures using the Finite Element Method in the framework of large elastoplastic strain, needs frequent remeshing of the deformed domain during computation. Indeed, the remeshing is due to the large geometrical distortion of finite elements and the adaptation to the physical behavior of the solution. This paper gives the necessary steps to remesh a mechanical structure during large elastoplastic deformations with damage. An important part of this process is constituted by geometrical and physical error estimates. The proposed method is integrated in a computational environment using the ABAQUS/Explicit solver and the BL2D-V2 adaptive mesher. To cite this article: H. Borouchaki et al., C. R. Mecanique 330 (2002) 709–716.  相似文献   
2.
Various problems associated with optimal path planning for mobile observers such as mobile robots equipped with cameras to obtain maximum visual coverage of a surface in the three-dimensional Euclidean space are considered. The existence of solutions to these problems is discussed first. Then, optimality conditions are derived by considering local path perturbations. Numerical algorithms for solving the corresponding approximate problems are proposed. Detailed solutions to the optimal path planning problems for a few examples are given.  相似文献   
3.
In this paper, a structurally unstable man–machine system is considered and a rigorous mathematical analysis is performed to study the influence of time delays in the control force on stability of the equilibrium solution of this system. Results on stability, instability and conditions for the preservation of stability (instability), besides the existence of bifurcation are presented.  相似文献   
4.
依据柱相比的热力学定义和反相液相色谱中溶质的计量置换保留理论(the stoichiometric dispheement heory of solute for retention,SDT-R),对反相液相色谱中固定相和流动相性质、温度对柱相比的影响进行了研究。结果表明:固定相的种类和配基的疏水性对柱相比影响较大,而流动相中有机溶剂的种类,特别是脂肪酸作为置换剂时,对柱相比的影响更大,而柱相比受温度的影响较小。此外,通过用27种小分子溶质对柱相比的测定,其logI和Z良好的线性关系,进一步证明柱相比是一个与溶质性质无关的常数。  相似文献   
5.
Summary A theoretical treatment is presented which considers differences between the composition of the mobile phase and solvents that are incorporated into the bonded phase via preferential sorption. Equations are derived and used to analyze retention data for various homologs chromatographed under reversed-phase conditions using alkyl bonded phases and combinations of water-methanol, water-acetonitrile and watertetrahydrofuran as mobile phases. In the case of water-methanol the surface phase and bulk mobile phase compositions are similar. However, significant differences in composition between the two phases are observed when binary combinations of water-acetonitrile and water-tetrahydrofuran are used as the cluents.  相似文献   
6.
Qin F  Liu Y  Chen X  Kong L  Zou H 《Electrophoresis》2005,26(20):3921-3929
A chemically bonded cellulose tris(3,5-dimethylphenylcarbamate) chiral stationary phase (CSP) was prepared by a radical polymerization reaction. The prepared CSP was packed into fused-silica capillaries with inner diameter of 75 microm to perform enantiomer separations in CEC. The electrochromatographic behavior of the CSP was investigated. On the prepared CSP, high EOF could be generated under acidic mobile phases, which represented an advantage for the separation of acidic enantiomers. Several neutral, acidic, and basic enantiomers were resolved on the prepared CSP under aqueous mobile phases. The column efficiencies were between 20,000 and 100,000 plates/m, which were much higher than those of HPLC. In addition, it was observed that the separation of some enantiomers benefited from the adoption of THF as mobile phase modifier.  相似文献   
7.
In this paper the equation for thin-layer adsorption chromatography with multicomponent mobile phases, proposed by O?cik in 1965 is extended to energetically heterogeneous solid surfaces. Other forms of this equation, more convenient in practical applications, are presented. Model calculations are made for TLC with binary mobile phases according to the modified form of O?cik's equation. Finally, this equation is compared with that of Snyder.  相似文献   
8.
Summary In this work, an optimization procedure for gradient RPLC separation, using ternary mobile phases, is described. This procedure requires eight preliminary experiments in gradient elution mode to predict the retention surface for each solute over the whole triangular space. This is followed by computerized calculations to determine the best ternary gradient elution profile with respect to both selectivity and analysis time. The efficiency of this procedure from the point of view of rapidity and of accuracy, is illustrated for the specific separation of twelve phenyl urea herbicides.  相似文献   
9.
This paper describes the theory of liquid adsorption chromatography (LSC) with mixed mobile phase, involving formation of multilayer surface phases. An equation describing the dependence of the capacity ratio upon the mobile phase composition is derived and theoretical curves illustrating the same dependence are calculated accordingly by assuming different thicknesses of the surface phase.  相似文献   
10.
T. Kowalska 《Chromatographia》1991,31(3-4):119-122
Summary Intermolecular interactions between the solute and the moieties constituting the mobile phase significantly contribute to the overall retention pattern of a given solute in a given chromatographic system. In this paper retention of solute is discussed in the case of the B+AB1+AB2 type mobile phase, which, in a quasithermodynamic way, can be divided into seven individual moieties. One evaluates the influence of each moiety on solute retention, and refers these regularities to the polarity of the solutes.  相似文献   
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