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Galal Elmanfe Hosna Benbouzid Nawal Derkaoui Mireille Privat 《Comptes Rendus Chimie》2006,9(11-12):1476
Despite its extremely weak adsorption at the water/silica interface, carbofuran can, however, induce the coadsorption of metallic salts, like, for example, lead nitrate, and thus enhance its adsorption. We quantitatively studied this phenomenon with a depletion method and under concentration conditions close to the environmental ones. Heavy metal salt was found to positively adsorb, whereas carbofuran relative adsorption is generally slightly negative. This study provides evidence that considering these facts is of paramount importance in environmental prospects. To cite this article: G. Elmanfe et al., C. R. Chimie 9 (2006). 相似文献
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Evgenii K. Legin Yurii I. Trifonov Mikhail L. Khokhlov Ekaterina E. Legina Dmitrii N. Suglobov Viktor N. Strukov Vladimir K. Legin Yurii V. Kuznetsov 《Comptes Rendus Chimie》2004,7(12):1173-1178
Joint leaching of iron and other macro- and microelements including radionuclides from radioactively contaminated floodplain soil of the Yenisei River is studied on miniecosystems. In developing anaerobic conditions, the redox potential Eh decreased to +140 mV, causing partial reduction of iron and solubilisation of iron hydrous oxide and organomineral films of the soil. Leaching of stable elements and radionuclides with water proceeds parallel to that of iron. To accelerate reductive mobilization of iron, 0.4% aqueous ascorbic acid was used instead of water as the leaching liquid phase. In this case, Eh approached –60 mV, and the leaching of stable and radioactive elements considerably increased, the effect being most pronounced for plutonium. To cite this article: E.K. Legin et al., C. R. Chimie 7 (2004).
Résumé
Effet du passage en milieu anaérobie sur la mobilisation des radionucléides dans les sols humides. La lixiviation simultanée du fer et d’autres éléments de sols contaminés de la vallée de la rivière Yénései a été étudiée. En imposant des conditions anaérobies, le potentiel redox chute à 140 mV, causant une réduction partielle du fer trivalent et la solubilisation de l’hydroxyde de fer et du film organominéral du sol. Les lixiviations du fer, des autres éléments et, par conséquent, des radionucléides contaminant le sol vont de pair. Pour accélérer la mobilisation réductive du fer, une solution d’acide ascorbique à 0,4% a été utilisée à la place de l’eau. Dans ces conditions, la valeur de Eh approche –60 mV et la lixiviation des éléments augmente considérablement, cet effet étant plus prononcé pour le plutonium. Pour citer cet article : E.K. Legin et al., C. R. Chimie 7 (2004). 相似文献5.
Morinao Fukuoka Yoshito Onoda Satoru Inoue Kenji Wada Akihiko Nukui Akio Makishima 《Journal of Sol-Gel Science and Technology》1993,1(1):47-56
Binary sols and gels of SiO2-Al2O3 were prepared using tetraethyl orthosilicate and each of four aluminum compounds; aluminum di (sec-butoxide) ethylacetoacetic ester chelate (AC), aluminum nitrate nonahydrate (AN), aluminum formoacetate (AF), and boehmite sol (BS) made from aluminum i-propoxide. The structure and the evolution of the Si-O-Al bonds in SiO2-Al2O3 sols and gels were investigated by 27Al nuclear magnetic resonance (NMR), Infrared absorption spectra, DTA, and X-ray diffraction. The formation of Si-O-Al bonds differs depending on the aluminum compounds used as raw materials. The ratio of Al(IV) to {Al(IV) + Al(VI)} is related to the microstructural homogeneity of the gels. When AC is used as a raw material, the Si-O-Al bonds are formed in the sol state and resultant gel shows good microstructural homogeneity. In case of AN, the Si-O-Al bonds are not formed either in the sol or the wet gel state. The bonds are formed by drying the gel before heat-treatment temperature reaches 300 400°C, resulting in good microstructural homogeneous gel. When AF is used, the Si-O-Al bonds are formed in the sol state but the ratio of Al(IV) to {Al(IV) + Al(VI)} is lower than when using AC. Microstructural homogeneity of the gel is ranked between AC or AN and BS. Using BS, the Si-O-Al bonds are not formed in the sol solution, and the change in the coordination number of the gel is similar to that of boehmite gel. The Microstructural homogeneity of the gel is the worst among the BS gels, which were prepared by using the four aluminum raw materials. 相似文献
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Chi Tran 《Comptes Rendus Mecanique》2005,333(8):605-611
In this Note, a fuzzy-integral based approach is developed for aggregating some of the available correlations that are commonly used for determining relative density , from cone penetration test (CPT) data, in which non-additive measures are used as fuzzy measures to relate the actual compressibility measured by the friction ratio of sands to the base correlations. The results of the case studied show that fuzzy measures and the fuzzy integral can be utilized for a new approach in geo-technical engineering. To cite this article: C. Tran, C. R. Mecanique 333 (2005). 相似文献
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Alain Pecker 《Comptes Rendus Mecanique》2004,332(9):725-730
The increasing need for probability seismic hazard assessment (PSHA) of critical facilities sometimes leads to unrealistic earthquake scenarios with very high induced ground motions. From a physical standpoint these high motions cannot exist because of the limiting resistance capacity of the soil strata through which the seismic waves travel. A simple analytical model is proposed to bound the maximum ground surface acceleration that any soil deposit can transfer. This model is an extension to non zero ground surface velocity of a previously presented model. To cite this article: A. Pecker, C. R. Mecanique 332 (2004). 相似文献
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Alain Pecker 《Comptes Rendus Mecanique》2003,331(10):661-666
The increasing need for probability seismic hazard assessment (PSHA) of critical facilities sometimes leads to unrealistic earthquake scenarios with very high induced ground motions. From a physical standpoint these high motions cannot exist because of the limiting resistance capacity of the soil strata through which the seismic waves travel. A simple analytical model is proposed to estimate a bound to the maximum ground surface acceleration that any soil deposit can transfer. To cite this article: A. Pecker, C. R. Mecanique 331 (2003). 相似文献
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Gioacchino Viggiani Nicolas Lenoir Pierre Bésuelle Marco Di Michiel Stefania Marello Jacques Desrues Mogens Kretzschmer 《Comptes Rendus Mecanique》2004,332(10):819-826
This Note presents a few selected results of an experimental testing program carried out at the ESRF in Grenoble, France. X-ray microtomography (with a spatial resolution of 14 μm) has been used to evaluate the onset and evolution of shear banding in a fine-grained stiff soil under deviatoric loading. It allowed detailed observations of strain localization in a specimen during the test, including the presence of more than one shear zone and a varying degree of dilatancy and/or crack opening. To cite this article: G. Viggiani et al., C. R. Mecanique 332 (2004). 相似文献
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