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41.
使用分子图形软件设计出多种CnP-4(n =1~ 7)的结构模型 ,并进行B3LYP密度泛函几何构型优化和振动频率计算 .最稳定的CP-4和C2 P-3 都是平面环状结构 .最稳定的CnP-4(n =3 ,5 ,7)结构在直碳链的一端连接 1个磷原子且另一端是P3 C的四元环的平面结构 .最稳定的CnP-4(n =4,6)结构在直碳链的一端连接 1个磷原子且另一端是P3 的三元环的锄状结构 .直碳链可与平面环的磷原子生成大π键 .大多数构型是由C2 ,C3 ,C4子结构以环状或链状方式组成的 .碳原子与磷原子以交替方式排列的结构数量少、能量高 . 相似文献
42.
A stable model category is a setting for homotopy theory where the suspension functor is invertible. The prototypical examples are the category of spectra in the sense of stable homotopy theory and the category of unbounded chain complexes of modules over a ring. In this paper we develop methods for deciding when two stable model categories represent ‘the same homotopy theory’. We show that stable model categories with a single compact generator are equivalent to modules over a ring spectrum. More generally stable model categories with a set of generators are characterized as modules over a ‘ring spectrum with several objects’, i.e., as spectrum valued diagram categories. We also prove a Morita theorem which shows how equivalences between module categories over ring spectra can be realized by smashing with a pair of bimodules. Finally, we characterize stable model categories which represent the derived category of a ring. This is a slight generalization of Rickard's work on derived equivalent rings. We also include a proof of the model category equivalence of modules over the Eilenberg-Mac Lane spectrum HR and (unbounded) chain complexes of R-modules for a ring R. 相似文献
43.
We develop a new joint cure rate model for longitudinal and survival data. The model allows for multiple longitudinal markers as well as a cure structure for the survival component based on the promotion time cure rate model, as described in Ibrahim et al. (Bayesian Survival Analysis, Springer, New York, 2001). Several characteristics and properties of the new model are discussed and examined. A real dataset from a melanoma clinical trial is given to demonstrate the methodology. 相似文献
44.
Gravimetric measurements of thermodesorption of n-hexane and n-heptane were performed under quasi-equilibrium conditions. Differential thermodesorption profiles for ZSM-5 and ZSM-11 showed two peaks, but for Y zeolites, only one thermodesorption peak was observed. A model function, derived from the Langmiur adsorption model, was fitted to the experimental data, and the model parameters (the adsorption entropy and enthalpy) were estimated. The two-step desorption profiles observed for ZSM-5 and ZSM-11 were attributed to the commensurate freezing effect, i.e. a transition in the adsorbed phase resulting in ordering of the adsorbed molecules in the zeolite channels. The results observed for ZSM-11 indicate that the zigzag channels typical for ZSM-5 micropore system are not necessary for this transition to occur. 相似文献
45.
项斯端 《浙江大学学报(理学版)》2004,31(1):88-97
根据KIM和LEE(1999)将多管藻属分为两独立属新管藻及多管藻,报道了我国14种及1变种1变型多管藻,以及11种新管藻,其中19种为我国新记录,发表了新种垫状多管藻(Polysiphonia caespitosa sp.nov)及新变种岩生多管藻长节变种(P.scopulorum var.longinodium var.nov.). 相似文献
46.
The adsorption of six-membered hydrocarbon cycles and cyclopentane and the interaction of hydrogen with the adsorbed layer on polycrystalline Pt-foil have been studied. The work function change (Δφ) was followed by a Kelvin probe and the C/Pt peak ratio was determined by Auger electron spectroscopy. Combining these two techniques made it possible to distinguish between chemisorption via σ-bonds and π-complex formation. Benzene and toluene adsorbed first as π-complex while cyclohexane showed initially a partial aromatization and a π-complex-like bonding to the surface. Excess hydrocarbon or addition of hydrogen transformed the π-complex into σ-bonded species. Cyclopentane adsorbed via σ-bonds and showed no significant hydrogen effect. 相似文献
47.
Anna Valette-Stasica 《Topology and its Applications》2007,154(2):443-448
Using algebraically constructible functions we give a generically effective method to detect asymptotic values of polynomial mappings with finite fibers defined on the real plane. By asymptotic variety we mean the set of points at which the polynomial mapping fails to be proper. 相似文献
48.
Rupert L. Frank Ari Laptev Elliott H. Lieb Robert Seiringer 《Letters in Mathematical Physics》2006,77(3):309-316
Inequalities are derived for power sums of the real part and the modulus of the eigenvalues of a Schrödinger operator with a complex-valued potential. 相似文献
49.
Electrostriction refers to the strain induced in a dielectric by electric polarization, which is usually very small for practical application. In this paper, we present a micromechanical analysis on the effective electrostriction of a ferroelectric polyvinylidene fluoride trifluoroethylene [P(VDF-TrFE)] polymer-based composite, where the exact connections between the effective electrostrictive coefficients and effective elastic moduli are established, and numerical algorithm for the prediction of the effective electrostrictive coefficients of the composite in terms of its microstructural information is developed. From our calculations, enhanced electrostriction in the composite has been demonstrated, and optimal microstructure for electrostriction enhancement has been identified. Our analysis provides a mechanism for the electrostriction enhancement, where the electrostrictive strain several times higher than that of polymer matrix can be obtained, if the microstructure of the composites can be carefully tailored. 相似文献
50.