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101.
Light-Driven Crawling of Molecular Crystals by Phase-Dependent Transient Elastic Lattice Deformation
Yanjun Gong Yongxian Guo Fayuan Ge Wei Xiong Jie Su Yang Sun Chuang Zhang An-Min Cao Yifan Zhang Jincai Zhao Yanke Che 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2020,132(26):10423-10428
The light-driven crawling of a molecular crystal that can form three phases, (α, β, and γ) is presented. Laser irradiation of the molecular crystal can generate phase-dependent transient elastic lattice deformation. The resulting elastic lattice deformation that follows scanning irradiation of a laser can actuate the different phases of molecular crystal to move with different velocity and direction. Because the γ phase has a large Young's modulus (ca. 26 GPa), a force of 0.1 μN can be generated under one laser spot. The generated force is sufficient to actuate the γ-formed molecular crystals in a wide dimensional range to move longitudinally at a velocity of about 60 μm min−1, which is two orders of magnitude faster than the α and β phases. 相似文献
102.
This paper is concerned with the experimental testing and the constitutive modelling of a thermoplastic microcellular polyethylene-terephthalate (MC-PET) foam on the temperature range of 21–210 °C in order to investigate the temperature-dependent performance of the applied parallel viscoelastic-viscoplastic material model. By means of carefully designed uniaxial mechanical tests in temperature chamber, the viscous, elastic and yielding behaviours of the investigated material are identified, which are then applied for selecting suitable viscoelastic-viscoplastic constitutive models. The material characterization process is conducted using finite-element-based fitting method, including also the analysis of the applied numerical optimization algorithm. The fitting results are used to analyse the parameter sensitivity and to propose closed-form analytical relations for the temperature dependency of the material parameters. Finally, the utilisation of the analytical temperature functions for speeding up the parameter-fitting process is also demonstrated. 相似文献
103.
Gerda Rogl Viktor Soprunyuk Wilfried Schranz Michael J. Zehetbauer Jiri Bursik Herbert Müller Ernst Bauer Peter F. Rogl 《无机化学与普通化学杂志》2020,646(14):1267-1272
Thermoelectric materials with a high figure of merit, ZT, are the essential basis to build thermoelectric generators, which can directly convert heat into electricity. Severe plastic deformation (SPD) via high-pressure torsion (HPT) was successfully applied to enhance ZT of ball-milled and hot-pressed skutterudites as well as to produce bulk nanostructured skutterudites directly from powders. SPD introduces many defects into the sample and in parallel the crystallite size is significantly reduced. During measurement-induced heating these defects anneal partially out, and the grains grow. In this work for the first time systematically the changes of the temperature-dependent electrical resistivity and of thermal expansion were compared. It could be shown that for p- and n-type skutterudites, being hot-pressed and HPT-processed as well as directly HPT-processed from compacted powder, these changes occur more or less simultaneously within the same temperature ranges. This evaluation gives a much deeper insight into the thermoelectric behavior of HPT samples under the influence of changing temperature. 相似文献
104.
Tom Scherzer 《Journal of Polymer Science.Polymer Physics》1996,34(3):459-470
Rheo-optical FTIR spectroscopy was used for the first time to monitor molecular orientation phenomena in highly crosslinked epoxies. After studying the orientation behavior of epoxy/amine networks during uniaxial deformation above their glass transition temperature in a preceding article, this article deals with the rheo-optical characterization of the deformation process of those epoxy systems below Tg. The orientation behavior is influenced by the different molecular structure of the constituents and the free volume entrapped in the resins. Yield strain and tensile modulus are correlated with the slope of the orientation function. The orientation function was found to show an abrupt change of its slope in the yield point region. This phenomenon is discussed with respect to the mechanism of plastic deformation. © 1996 John Wiley & Sons, Inc. 相似文献
105.
基于热弹塑性有限元法,采用ANSYS软件建立了网格疏密过渡的单箱五室钢箱梁壳单元模型;结合高效的分段移动热源,实现了对大型复杂长焊缝结构焊接全过程的数值模拟,并定性对比了宽幅钢箱梁在不同的环焊缝焊接顺序下顶板和底板的变形情况.分析结果表明:腹板焊缝的焊接顺序对竖向最大变形值(绝对值)的影响不大,其值主要取决于顶板和底板... 相似文献
106.
高功率半导体激光端面泵浦方形掺Nd3+离子激光晶体热形变研究 总被引:5,自引:4,他引:1
为了解决高功率半导体激光器端面泵浦激光晶体引起的热效应问题,激光晶体泵浦端面的热形变必须进行准确的计算.通过对于全固态激光器中激光晶体的工作特点分析,建立了矩形截面激光晶体热分析模型.基于热传导方程,提出了泊松方程的一种新解,并获得了矩形截面激光晶体端面热形变分布的一般解析表达式.同时讨论了半导体激光器偏心泵浦激光晶体给端面热形变带来的影响.与有限元分析方法以及其他数值分析方法相比,解析分析方法不会给计算引入任何的误差.热形变的解析分析为解决激光晶体的热效应问题以及提高激光器的性能提供了理论的依据. 相似文献
107.
108.
We propose a conjecture on the relative twist formula of l-adic sheaves, which can be viewed as a generalization of Kato—Saito's conjecture. We verify this conjecture under some transversal assumptions. We also define a relative cohomological characteristic class and prove that its formation is compatible with proper push-forward. A conjectural relation is also given between the relative twist formula and the relative cohomological characteristic class. 相似文献
109.
针对塑性变形量评定的局限问题,基于铁磁材料塑性变形致位错在不同方向分布不同的现象,研究了磁测法在定量评定低碳钢塑性变形量方面的应用前景。实验以工程中常用的低碳钢Q195钢板为测试材料,制作了形状尺寸一致的一批试件,并对其进行了不同程度的塑性变形量加载。通过搭建的磁化检测系统,采用相同强度及频率的正弦波激励,对所有样品进行了不同方向的磁化;同时经线圈及隧道磁敏电阻(TMR)采集了每次磁化的磁化曲线,提取了磁化曲线特征参数,对比了其与塑性变形量的定量关系。结果表明:随着塑性变形量的增加,铁磁钢材在同一磁场强度下产生的磁感应强度也会变大;沿主塑性变形方向磁化时,磁滞消耗能量最少,沿主塑性变形垂直方向磁化时,磁滞消耗的能量最多;磁路内磁场在主塑性变形方向上对塑变量的变化最敏感,而磁路外磁场在主塑变垂直方向上对塑变量的变化最敏感。实现了铁磁材料磁特征参数与塑性变形量的定量关联。本研究为开发简捷的铁磁材料塑性变形量无损评定磁方法奠定了基础。 相似文献
110.
基于一阶非线性梁理论和物理中面概念,导出了纵横向载荷作用下功能梯度材料(FGM)梁非线性弯曲和过屈曲问题的控制方程,并获得了该问题的精确解;据此解研究了梯度材料性质、外载荷、横向剪切变形以及边界条件等因素对功能梯度材料梁非线性力学行为的影响,分析中假设功能梯度材料性质只沿梁厚度方向,并按成分含量的幂指数函数形式变化。结果表明:纵横载荷共同作用下,功能梯度梁的弯曲构形将有无限多个;随着梯度指数的增大,梁的变形减小,临界载荷升高;随着长高比的增大,横向剪切变形的影响减小。 相似文献