钛合金（TC-6）二阶和三阶弹性常数

 用脉冲回波重叠法测量了钛合金（TC-6）的二阶、三阶弹性常数。实验中发现dμ/dp<0（p<0.17 GPa）,dμ/dp>0（p>0.17 GPa）。     

舒兰褐煤树脂组分中某些分离物的化学研究

我国褐煤资源丰富 ,分布于云南、吉林、黑龙江、山东和内蒙古等地。褐煤除作燃料和腐植肥料外 ,还应用于轻化工和机械工业 ,如从褐煤制取褐煤蜡。褐煤蜡中含有较多的树脂物质 ,影响了褐煤蜡的质量 ,因此通常褐煤蜡树脂作为废弃物脱除 ,以提高褐煤蜡的质量。褐煤蜡的化学组成为纯蜡和树脂 ,前者为高碳脂肪酸和脂肪醇的酯类、游离脂肪酸和脂肪醇 ,以及烃类物等 ;后者则以萜类为主 ,并含有甾醇、羟基酸和烃化合物[1～ 5] 。 1982年唐运千等采用红外光谱和氢核磁共振谱检定 ,褐煤树脂中含有 β 谷甾醇 ;柱层析和薄层层析检出雌二醇和雌酚酮[2 ] …     

付里叶变换红外光谱仪的操作参数对光谱的影响

本文以二苯基甲酮的ＫＢｒ压片为标样，在Ｂｒｕｋｅｒ ＩＦＳ １２０ＨＲ付里叶变换红外光谱仪上系统考察了该仪器折一些重要操作参数（光源光栏、切趾函数、扫描速度）对光谱质量（信噪比，分辨率）的影响。从而获得了测样时的优化操作条件。     

反相液体色谱中饱和醇保留行为的研究 Ⅰ.低碳醇保留行为与溶质分子结构的关系

本文从吸附-疏溶剂理论出发,根据热力学平衡观点,导出了一定固定相和流动相时,描述溶质保留行为与其分子结构关系的理论模型,并用之预测了饱和醇的保留值,获满意结果。从而表明本模型不但能用于同系物,而且亦可用于同分异构体及立体异构体保留行为的预测。     

La2Zr2O7催化剂结构相变对甲烷氧化偶联反应性能的影响

采用共沉淀法并通过改变焙烧温度制备了一系列具有不同晶相结构的La₂Zr₂O₇催化剂，在微型固定床反应器上评价其甲烷氧化偶联反应性能，并利用XRD、Raman、CO₂-TPD、XPS等表征手段，探究催化剂的物相结构、表面碱性以及表面氧物种的变化规律。结果表明，随着焙烧温度从700℃逐渐升高到1200℃，La₂Zr₂O₇催化剂结晶度不断提高，晶相发生明显变化，从无定形结构逐渐向缺陷萤石结构过渡，最终转变成烧绿石结构。焙烧温度提高促使La₂Zr₂O₇晶相转变过程中，催化剂表面的碱性强度减弱，中等碱性位数量以及具有催化活性的表面氧物种O₂^2-和O₂^-的相对含量不断减少，致使催化剂的CH₄转化率和C₂₊选择性不断降低。其中，无定形LZO-CP-700催化剂表现出最佳的甲烷氧化偶联反应性能。     

Synthesis,alkylation, and molecular and crystal structure ofN-methylmorpholinium 6-amino-3,5-dicyano-1,4-dihydropyridine-4-spirocyclohexane-2-thiolate

The reaction of cyano(cyclohexylidene)thioacetamide with cyanothioacetamide or malononitrile andN-methylmorpholine yieldsN-methylmorpholinium 6-amino-3,5-dicyano-1,4-dihydropyridine-4-spirocyclohexane-2-thiolate. Its structure was established based on the results of alkylation and X-ray structural analysis.Deceased.Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 10, pp. 2535–2540, October, 1996.     

Interconnection between the Structures and Sorption Characteristics of Mesophase Materials of MCM-41 Type Containing Alkylpyridines

Under the conditions studied for the synthesis of mesophase materials with alkylpyridinium halides an increase in the density of packing of these molecules in the encapsulated micelles was observed with an increase in the length of the alkyl radicals. The difference in the density of packing of these surface active reagents (SAR) depended to a considerable extent on the perfection of the hexagonal structure and the characteristic absorption properties of the mesophase materials of MCM-41 type.     

Synthesis and structure of novel derivatives of thieno[2,3-b]thiocine. An unusual product of intramolecular cycloaddition of 2-homomethallylthio-5-methyl-3-thiophenecarbonitrile oxide

9-Methyl-3,3a,4,5-tetrahydro-6H-thieno[2,3-b]thiocino[4,5-c]isoxazole and 9-hydroxyimino-2-methyl-7-methylene-6, 7,8,9-tetrahydro-5H-thieno[2,3-b]thiocine have been prepared for the first time by the oxidation of 2--alkenylthio-3-thiophenecarbaldoximes with NaOCl. X-ray structural investigations of thieno[2,3-b]thiocine and 2-homomethallylthio-5-methyl-3-thiophenecarbaldoxime have been carried out.Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 7, pp. 1262–1266, July, 1993.     

N-Amino Derivatives of Condensed Imidazole Systems

The previously unknown 1-amino- and 3-aminonaphtho[1,2-d]imidazoles, 1-aminonaphtho[2,3-d]imidazole, 1-aminophenanthro[9,10-d]imidazole and the N-amino-N'-methylimidazolium picrates corresponding to them have been obtained by direct amination of a series of condensed imidazoles with O-picrylhydroxylamine. An X-ray structural investigation of 1-amino-3-methylnaphtho[1,2-d]imidazolium picrate showed that, in difference to 1-aminobenzimidazolium salts, a conformation exists in it in which the hydrogen atoms of the N-NH₂ group are directed to the side of the meso carbon atom.     

On Aging of Acid-Catalyzed Silica Sols—A Dynamic Light Scattering Study

Dynamic light scattering experiments in acid-catalyzed silica sols are discussed. It is shown that in spite of limited parameter accuracy and limited absolute knowledge of the particle sizes, the scattering data from various experiments are comparable with one another and give information about structural differences. Measurements at various angles indicate changes between non-spherical and nearly spherical particles and allow the estimation of gelling times before gelation.