全文获取类型
收费全文 | 806篇 |
免费 | 102篇 |
国内免费 | 172篇 |
专业分类
化学 | 681篇 |
晶体学 | 71篇 |
力学 | 6篇 |
综合类 | 4篇 |
物理学 | 318篇 |
出版年
2023年 | 6篇 |
2022年 | 17篇 |
2021年 | 12篇 |
2020年 | 18篇 |
2019年 | 19篇 |
2018年 | 28篇 |
2017年 | 26篇 |
2016年 | 29篇 |
2015年 | 23篇 |
2014年 | 39篇 |
2013年 | 105篇 |
2012年 | 51篇 |
2011年 | 60篇 |
2010年 | 43篇 |
2009年 | 65篇 |
2008年 | 54篇 |
2007年 | 50篇 |
2006年 | 55篇 |
2005年 | 46篇 |
2004年 | 50篇 |
2003年 | 30篇 |
2002年 | 40篇 |
2001年 | 20篇 |
2000年 | 35篇 |
1999年 | 26篇 |
1998年 | 27篇 |
1997年 | 22篇 |
1996年 | 14篇 |
1995年 | 15篇 |
1994年 | 18篇 |
1993年 | 12篇 |
1992年 | 2篇 |
1991年 | 6篇 |
1990年 | 1篇 |
1989年 | 5篇 |
1988年 | 4篇 |
1987年 | 1篇 |
1986年 | 1篇 |
1985年 | 1篇 |
1983年 | 1篇 |
1978年 | 1篇 |
1976年 | 1篇 |
1973年 | 1篇 |
排序方式: 共有1080条查询结果,搜索用时 15 毫秒
61.
62.
A. Hussain C.W. Ahn H.J. Lee I.W. Kim J.S. Lee S.J. Jeong S.K. Rout 《Current Applied Physics》2010,10(1):305-310
We have fabricated lead-free Bi0.5(Na0.75K0.25)0.5TiO3 (BNKT) ceramics by a conventional process (CP) and reactive templated grain growth (RTGG) methods. The effect of grain orientation on structure, dielectric, complex impedance and electrical properties was investigated. The phase formation and grain morphology of BNKT ceramics were examined by X-ray diffraction (XRD) and scanning electron microscope (SEM), respectively. High dielectric constant and low dielectric loss was observed for grain oriented (textured) BNKT ceramics. Complex impedance, temperature dependent ac and dc conductivity were performed to explore the conduction behavior of the prepared BNKT ceramics. 相似文献
63.
Spinel lithium titanate (Li4Ti5O12) as novel anode material for room-temperature sodium-ion battery 下载免费PDF全文
This is the first time that a novel anode material, spinel Li4Ti5O12 which is well known as a “zero-strain” anode material for lithium storage, has been introduced for sodium-ion battery. The Li4Ti5O12 shows an average Na storage voltage of about 1.0 V and a reversible capacity of about 145 mAh/g, thereby making it a promising anode for sodium-ion battery. Ex-situ X-ray diffraction (XRD) is used to investigate the structure change in the Na insertion/deinsertion process. Based on this, a possible Na storage mechanism is proposed. 相似文献
64.
Luminescentmaterialshavinglongdecayperi0dhaveat-IIactedmuchinterestduetotheirpotentialwidespreadaPplicati0ns.Recently,alongdecayluminescentp0wderhavingthecomPositionofSrAl2O4activatedwithEu' wasreportedandregardedasthebestcandidateforpracticalaPPlicationbecauseofitsuniqueadVantages0veritsprecursors.l'2Inthispaper,wereportthesynthesisofthelongdecayluminescentpowderandtheinnuence0fthemolarratioofAlt0sr0ntheethessioncolor.Toproducethelundnescentp0wder,amixtureofSrCO3,Al2O3,Eu2O3andsomesol… 相似文献
65.
聚苯乙烯—钛酸钡复合材料介电性能的研究 总被引:4,自引:0,他引:4
以聚苯乙烯与化学沉淀法钛酸钡陶瓷为基本组成,采用溶液共混,溶液聚合,表面处理后溶液聚合三种方法进行复合,发现后两种复合的钛酸钡颗粒表面发生界面变化,形成活性界面,使得溶液聚合法和表面处理后溶液聚合所得到的材料具有较低的介电损耗,在高频下能保持较高的介电系数。 相似文献
66.
微乳液法制备超细K2Ln2Ti3O10及其光催化活性研究 总被引:1,自引:4,他引:1
以钛酸四丁酯、氢氧化钾和镧系金属氧化物为原料。采用微乳液法制备了系列超细K2Ln2Ti3O10(Ln=La.Ce,Pr.Nd,Sm,Eu,Gd)光催化剂。并考察了其光催化活性。通过X射线衍射(XRD)、透射电镜(TEM)和紫外可见吸收光谱(UV—Vis)对其进行了表征。结果表明:用微乳液法制备催化剂可以在较低的温度下(900℃),用较短的烧结时间(3h)合成结晶度高、粒径较小(200Mm)的K2Ln2Ti3O10钙钛矿型层状结构化合物。催化剂在紫外光和可见光条件下均具有光催化降解甲基橙的活性。紫外光条件下可以明显提高光催化降解活性,降解率达到60%。 相似文献
67.
Wannarat Chueangchayaphan Piyawadee Luangchuang Narong Chueangchayaphan Muhammad Azwadi Sulaiman Yeampon Nakaramontri 《高分子科学》2021,39(6):725-735
Acrylonitrile rubber(NBR) composites filled with barium titanate(BT) were prepared using an internal mixer and a two-roll mill. Also, a secondary filler, namely carbon nanotubes(CNT), was added in order to find a potential synergistic blend ratio of BT and CNT. The cure characteristics, tensile and dielectric properties(dielectric constant and dielectric loss) of the composites were determined. It was found that NBR/BT composites with CNT secondary filler, at a proper BT:CNT ratio, exhibited shorter scorch time(t_(s1)) and cure time(t_(c90)) together with superior tensile properties and reinforcement efficiency, relative to the one with only the primary filler. In addition, the NBR/BT-CNT composite with 80 phr BT and 1-2 phr CNT had dielectric constant of 100-500, dielectric loss of 12-100 and electrical conductivity below 10~(-4) S/m together with high thermal stability. Thus, with a proper BT:CNT mix and filler loading, we can produce mechanically superior rubber composites that are easy to process and low-cost, for flexible dielectric materials application. 相似文献
68.
D. Husain J. Lei F. Castao M. N. Snchez Rayo 《Journal of photochemistry and photobiology. A, Chemistry》1999,120(3):151-159
The collisional behaviour of Ba[6s5d(3DJ)], 1.151 eV above the 6s2(1S0) electronic ground state, in the presence of atomic strontium, has been investigated in the ‘long-time domain' (ca. 100 μs–1 ms) following the pulsed dye-laser excitation of barium vapour at elevated temperature at λ = 553.5 nm (Ba[6s6p(1P1)] ← Ba[6s2(1S0)]. Ba(3DJ) is subsequently produced from the short-lived 1P1 state (τe = 8.37 ± 0.38 ns) by a number of radiative and collisional processes. It may then be monitored in the ‘long-time domain' by atomic spectroscopic marker methods involving either collisional activation of Ba(3DJ) by Ba(1S0) and He buffer gas to yield Ba[6s6p(3PJ)] with subsequent emission from the 3P1 state (τe = 1.2 ± 0.1 μs): Ba[6s6p(3P1)] → Ba[6s2(1S0)] + hv (λ = 791.1 nm). Alternatively, emission from Ba(1P1) may be monitored at long times following the generation of this short-lived state by energy pooling following self-annihilation of Ba(3DJ) + Ba(3DJ) from Ba[6s6p(1P1)] → Ba[6s2(1S0)] + hv (λ = 553.5 nm). The generation of Ba(3DJ) in the presence of atomic strontium yields emission in the long-time domain from Sr[5s5p(3P1)] (τe = 19.6 μs): Sr[5s5p(3P1)] → Sr[5s2(1S0)] + hv (λ = 689.3 nm). Whilst the decay profiles at short times are complex in form, at long times all these atomic profiles show first-order kinetic removal with the decay coefficients for λ = 791.1 nm, 689.3 nm and 553.5 nm emissions in the ratio 1 : 2 : 2, consistent with overall third-order activation of the form: Ba(3DJ) + Ba(3DJ) + Sr(1S0) → Sr(3PJ) + 2Ba(1S0). The mechanism is modelled in detail, including measurement of integrated emission intensities, yielding kinetic data for fundamental collisional processes. The overall rate constant for the third-order collisional activation of Sr[5s5p(3PJ])from 2Ba[6s5d(3DJ)] + Sr[5s2(1S0)] takes the upper limit of 5.8 × 10−27 cm6 atom−2 s−1 (T = 900 K). The rate constant for the two body collisional quenching of Ba[6s5d(3DJ)] by ground state atomic strontium, Sr[5s2(1S0)], is found to be (2.0 ± 0.1) × 10−12 cm3 atom−1 s−1 (T = 900 K). 相似文献
69.
70.
Synthesis,Structure, and Properties of SrC(NH)3, a Nitrogen‐Based Carbonate Analogue with the Trinacria Motif 下载免费PDF全文
M. Sc. Ronja Missong M. Sc. Janine George Dr. Andreas Houben Dr. Markus Hoelzel Prof. Dr. Richard Dronskowski 《Angewandte Chemie (International ed. in English)》2015,54(41):12171-12175
Strontium guanidinate, SrC(NH)3, the first compound with a doubly deprotonated guanidine unit, was synthesized from strontium and guanidine in liquid ammonia and characterized by X‐ray and neutron diffraction, IR spectroscopy, and density‐functional theory including harmonic phonon calculations. The compound crystallizes in the hexagonal space group P63/m, constitutes the nitrogen analogue of strontium carbonate, SrCO3, and its structure follows a layered motif between Sr2+ ions and complex anions of the type C(NH)32?; the anions adopt the peculiar trinacria shape. A comparison of theoretical phonons with experimental IR bands as well as quantum‐chemical bonding analyses yield a first insight into bonding and packing of the formerly unknown anion in the crystal. 相似文献