新型噻吩基取代卟啉的合成及其荧光光谱研究

合成了两种新型噻吩基卟啉－5，15－二（2－噻吩基）－2，8，12，18－四乙基－3，7，13，17－四甲基卟啉7a（45．1％）和5，15－二（2－联噻吩基）－2，8，12，18－四乙基－3，7，13，17－四甲基卟啉7b(61.2%),并研究了它们的光谱性质，其中荧光光谱的最大发射峰蜂都在631nm处，量子产率分别为4．1％（7a)和1．4％（7b)。     

Effect of the Electron-LO-Phonon Coupling on an Exciton Quantum Dot

The influence of the electron-LO-phonon coupling on energy spectrum of the low-lying states ofan exciton inparabolic quantum dots is investigated as a function of dot size. Calculations are made by using the method of few-bodyphysics within the effective-mass approximation. A considerable decrease of the energy in the stronger confinement rangeis found for the low-lying states of an exciton in quantum dots, which results from the confinement of electron-phononcoupling.     

Tunneling and EPR linewidths due to dislocations in Mn acetate

We compute the width and shape of the EPR and tunneling resonances due to dislocations in Mn₁₂ acetate crystals. Uncorrelated dislocations produce the Gaussian shape of resonances while dislocations bound in pairs produce the Lorentzian shape. We stress that the uniaxial spin Hamiltonian together with crystal defects can explain the totality of experimental data on Mn₁₂. Received 2 August 2001 / Received in final form 15 March 2002 Published online 17 September 2002     

Renormalization of the two-photon vacuum polarization and the self energy vacuum polarization for a tightly bound electron

The renormalization method of Bogoljubov-Parasiuk-Hepp-Zimmermann (BPHZ) is used in order to derive the renormalized energy shift due to the gauge invariant K?llén-Sabry diagram of the two-photon vacuum polarization (VPVP) as well as the self energy vacuum polarization S(VP)E beyond the Uehling approximation. It is outlined, that no outer renormalization is required for the two-photon vacuum polarization and that only the inner renormalization has to be accomplished. It is shown that the so-called nongauge invariant spurious term is absent for a wide class of vacuum polarization (VP) diagrams if one applies the widely used spherical expansion of bound and free-electron propagator. This simplifies significantly calculations in bound state quantum electrodynamics. As one result of our paper the use of the BPHZ-approach in bound state QED is established. Received 28 September 2001     

清华物理系量子信息研究的新进展

在清华大学物理系成立60周年之际,我们对近年来清华大学物理系量子信息研究的主要进展情况作一介绍,包括量子搜索算法研究,核磁共振量子计算的实验研究,量子通讯的理论与实验研究.在量子搜索算法研究方面,我们提出了量子搜索算法的相位匹配,纠正了当时的一种错误观点,并且提出了一种成功率为100%的量子搜索算法,改进了Grover算法;在核磁共振量子计算实验方面,我们实现了2到7个量子比特的多种量子算法的实验演示;在量子通讯方面,我们提出了分布式传输的量子通讯的思想,应用于量子密钥分配、量子秘密共享、量子直接安全通讯等方面,构造了多个量子通讯的理论方案.在实验室,我们实现了2米距离的空间量子密码通讯的演示实验.     

Group-valued measures on coarse-grained quantum logics

In [3] it was shown that a (real) signed measure on a cyclic coarse-grained quantum logic can be extended, as a signed measure, over the entire power algebra. Later ([9]) this result was re-proved (and further improved on) and, moreover, the non-negative measures were shown to allow for extensions as non-negative measures. In both cases the proof technique used was the technique of linear algebra. In this paper we further generalize the results cited by extending group-valued measures on cyclic coarse-grained quantum logics (or non-negative group-valued measures for lattice-ordered groups). Obviously, the proof technique is entirely different from that of the preceding papers. In addition, we provide a new combinatorial argument for describing all atoms of cyclic coarse-grained quantum logics.     

Interferences in Photodetachment of a Negative Molecular Ion

The photodetachment of a negative molecular ion is studied theoretically using a two-center model. The detached electron wave function is obtained as a superposition of two coherent waves originating from each center. The photo-detached electron flux is evaluated on a screen placed at a large distance from the negative molecular ion. The electron flux on the screen displays strong interferences, the peak positions are related to the distance between the two centers in the negative molecular ion. We a/so obtained a simple analytical formula for the total photodetachment cross section. It approaches one and two times of the cross section for the one-center system in the high and lowphoton energy limits respectively.     

q变形对相干态的相位概率分布特性

通过推广Pegg和Barnett的相位算符和相位态到q变形的双模情况, 应用数值计算 研究了q变形对相干态的相位概率分布特性. 结果表明, q变形对相干态的相位概率分布受到相位参数、q参数和参数│ξ│的调节, 从而反映出不同的量子相干特性.     

The role of emitter quasi-bound state and scattering on intrinsic bistability in resonant tunneling diodes

Usually, numerical self-consistent calculations predict a much larger intrinsic bistability region than actually is measured in resonant tunneling diodes (RTDs). In addition, numerical calculations have shown that scattering in the well reduces bistability. We used a unified treatment of current flowing from continuum states and emitter quasi-bound states to show numerically and analytically that not only the scattering in the quantum well but also the scattering in the emitter reduces bistability. Moreover, within the Hartree approximation, bistability occurs by tunneling resonantly between emitter quasi-bound state and well quasi-bound state as a pitchfork bifurcation.     

Interpreting Observables in a Quantum World from the Categorial Standpoint

We develop a relativistic perspective on structures of quantum observables, in terms of localization systems of Boolean coordinatizing charts. This perspective implies that the quantum world is comprehended via Boolean reference frames for measurement of observables, pasted together along their overlaps. The scheme is formalized categorically, as an instance of the adjunction concept. The latter is used as a framework for the specification of a categorical equivalence signifying an invariance in the translational code of communication between Boolean localizing contexts and quantum systems. Aspects of the scheme semantics are discussed in relation to logic. The interpretation of coordinatizing localization systems, as structure sheaves, provides the basis for the development of an algebraic differential geometric machinery suited to the quantum regime.