keV 质子辐照对Kapton/Al光学性能的影响

 采用空间综合辐照设备对Kapton/Al薄膜进行了质子辐照地面模拟试验,选取质子能量90 keV,辐照通量5.0×10¹¹ cm¹²·s^-1。通过辐照前后光谱反射系数的变化考察了实验样品的光学性能退化特征。借助于反射光谱和紫外-可见吸收光谱和傅里叶转换红外光谱分析技术分析了辐照后Kapton/Al光学性能的退化机理。研究结果表明：辐照过程中样品表面发生了复杂的化学反应,随着辐照剂量的增加光能隙逐渐减小,Kapton吸收曲线的末端边缘发生红移并且在可见光区吸收强度增加。     

Growth and optical characterization of organic nonlinear optical crystal: indole-3-aldehyde

The metastable zone width for the solution of organic nonlinear material: indole-3-aldehyde (IA) has been determined for the various solvents of acetone, methanol and ethyl acetate and the corresponding IA crystals have been grown by temperature lowering technique. The surface analysis on different planes of the grown crystals has been carried out. The range of transmission and powder second harmonic generation efficiency of IA have been reported.     

Resonant energy transfer from nanocrystal Si to β-FeSi2 in hybrid Si/β-FeSi2 film

The photoluminescence （PL） characteristics of hybrid β-FeSi2/Si and pure β-FeSi2 films fabricated by pulsed laser deposition at 20 K are investigated. The intensity of the 1.54-μm PL from the former is enhanced, but the enhancement vanishes when the excitation wavelength is larger than the widened band gap of Si nanocrystal. Time-resolved PL decay measurements reveal that the lifetime of the photo-excited carriers in the hybrid β-FeSi2/Si film is longer than that in the pure β-FeSi2 film, providing evidence that the PL enhancement results from the resonant charge transfer from nanocrystalline Si to β-FeSi2.     

Optical and magnetic properties of InFeP layers prepared by Fe~+ implantation

InFeP layers are prepared by ion implantation of InP with 100-keV Fe＋ ions to a dose of 5 ×10^16 cm-2 and investigated by optical, magnetic, and ion beam analysis measurements. Photoluminescence measurements show a deep-level peak at 1.035 eV due to Fe in InP and two exciton-related luminescences at 1.426 eV and 1.376 eV in the implanted samples annealed at 400℃. Conversion electron Mossbauer spectroscopy reveals a doublet corresponding to Fe3＋ ions in the indium sites. Atomic force microscopy and magnetic force microscopy show that magnetic clusters are formed in the annealing process. The magnetization-field hysteresis loops show ferromagnetic properties persisting up to room temperature with a coercive field of 100 0e （10e = 79.5775 A-m-1）, saturation magnetization of 4.35 × 10-5 emu, and remnant magnetization of 4.4× 10 6 emu.     

Thermodynamic properties of 3C-SiC

In the present paper, we report on the results of various thermodynamic properties of 3C-SiC at high pressure and temperature using first principles calculations. We use the plane-wave pseudopotential density functional theory as im- plemented in Quantum ESPRESSO code for calculating various cohesive properties in ambient condition. Further, ionic motion at a finite temperature is taken into account using the quasiharmonic Debye model. The calculated thermody- namic properties, phonon dispersion curves, and phonon densities of states at different temperatures and structural phase transitions at high pressures are found to be in good agreement with experimental and other theoretical results.     

功能层厚度对叠层有机电致发光器件出光性能影响的数值研究

功能层厚度是影响有机电致发光器件出光效率的主要因素之一,故获得不同功能层厚度对器件出光特性的影响规律是制备高性能器件的重要基础. 本文基于薄膜光学原理、电偶极子辐射理论及Fabry-Pérot微腔原理,建立了结构为glass/ITO/N,N0-bis（naphthalen-1-yl）-N,N0-bis（phenyl）-benzidine（NPB）/tris（8-hydroxyquinoline）aluminum（Alq₃）/molybdenum trioxide（MoO₃）/NPB/Alq₃/Al的叠层有机电致发光器件的光学模型,系统地研究了各个功能层厚度对叠层有机电致发光器件出光强度的影响,得到了功能层厚度对器件出光强度影响的规律. 该模型的建立与所获得的结果可对深入了解叠层有机电致发光器件的工作机理以及制备高性能的器件提供一定的帮助. 关键词： 叠层有机发光器件 出光特性 厚度 数值研究     

氩、氢混合等离子体处理对GaAs表面性质及发光特性的影响

介绍了一种氩、氢混合等离子体清洗GaAs基片的实验工艺,深入研究了氩、氢等离子体清洗GaAs表面污染物和氧化层,并活化表面性能的基本原理,同时讨论了气体流量、溅射功率和清洗时间等不同溅射参数对等离子体清洗效果的影响。结果表明,在氩气和氢气流量分别为10 cm³/min和30 cm³/min,溅射功率为20 W,清洗时间为15 min的条件下,GaAs样品的光致发光强度提高达139.12%,样品表面的As-O键和Ga-O键基本消失。     

共掺Mo6+离子的Ca4LaNbW4O20∶Eu3+荧光粉的发光特性

采用高温固相法制备了红色荧光粉Ca4LaNb(W1-x Mo x)4O20∶Eu3+并研究了样品的发光性质。Ca4LaNbW4O20∶Eu3+的激发光谱中包含一个宽的激发带,峰值位于275 nm,归属于WO2-4基团的电荷迁移跃迁。随着Mo6+离子的掺入,Ca4LaNbW4O20∶Eu3+位于275 nm处的吸收带变宽,其原因是O2--Eu3+的电荷迁移跃迁增强。在Ca4LaNb(W1-x Mo x)4O20∶Eu3+的发射光谱中,400~500 nm间较宽的发射带属于WO2-4基团的发射带,而位于591 nm和616 nm的尖锐的发射峰分别属于Eu3+的5D0→7F1磁偶极跃迁和5D0→7F2电偶极跃迁发射。随着Mo6+离子浓度的增加,WO2-4基团的发射带强度下降,从而提高了色纯度。     

空富勒烯C36和嵌入Mg原子的C36分子的电子学特性研究

采用基于密度泛涵理论的第一性原理和非平衡格林函数方法研究了富勒烯C36分子和以金原子面为电极的Au-S-C36-S-Au电子传输系统的电子结构和传输特性.然后将镁原子嵌入C36笼腔内得到了一个新的分子器件Mg@C36,接金电极后建立了它的电子传输系统Au-S-Mg@C36-S-Au,并且得出了这一系统的电子能级、分子轨道分布、传输概率、态密度、伏安特性和电导曲线.结果显示C36和Mg@C36的电子传导主要集中在分子壳上,且系统Au-S-C36-S-Au中的电子传输主要分布在分子壳的外侧,而系统Au-S-Mg@C36-S-Au中的电子传输在分子壳外侧和内侧的近似相同,二个系统都有着非线性的Ⅰ-Ⅴ特性和电导曲线.     

一类具有Markov性质的混沌系统的构造

本文构造了一类具有Markov性质的分段扩张线性映射, 计算表明其具有正的李雅普诺夫指数. 通过理论分析, 证明了其极限分布是均匀分布, 并给出了其最小周期的计算公式. 通过分析符号熵测度应用于此系统时的具体涵义, 指出该系统的复杂度与系统的最小周期之间存在着矛盾关系, 说明了此系统具有可控的复杂度并给出了其复杂度随系统参数变化时的理论极限公式. 通过统计测试和复杂度测试表明, 此系统产生的混沌序列服从均匀分布, 而通过参数的调整该系统的符号熵可以接近其理论极限, 而与Logistic映射和斜帐篷映射的基于近似熵和符号熵的对比实验可知, 本文所提系统具有更高的复杂度, 并有更长的最小周期. 这表明此系统比较适合用于构造保密通信系统. 关键词： 混沌 Markov性质 复杂度 均匀分布