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81.
82.
V. G. Balenko A. V. Kovtun A. N. Kirkin V. M. Mizin 《Journal of Applied Spectroscopy》2002,69(2):320-322
A new method is suggested for producing the solgel matrices with the molecules of laser dyes introduced into them. The curves of tuning lasing in Rhodamine 6G, Rhodamine 4S, Rhodamine 101, and phenylamine 430 in these matrices are obtained. The total range of tuning is 550–650 nm at a pumping energy of 4 mJ. The halfwidth of the generation spectrum is independent of the pumping energy to 4 mJ and comprises 0.3 ± 0.1 nm. The main factors forming the generation spectrum are noted. 相似文献
83.
掺Eu3+硅基材料的发光性质 总被引:4,自引:5,他引:4
通过溶胶-凝胶技术制备了掺Eu^3 的硅基材料并测试了其三维荧光光谱、激光谱和发射光谱,结果显示,最佳激发波波长为350nm,最强荧光波长为620nm;在350nm光激发下的发射光谱显示Eu^3 的特征发射光谱,产生4条谱带,分别是577nm(^5D0-^7F0),588nm(^5D0-^7F1),596nm(^5D0-^7F1)和610nm(^5D0-^7F2)。 相似文献
84.
用“湿法”制备了长余辉发光材料,原料通过水溶液液相分子水平上的均匀混合,利用金属硝酸盐和有机还原剂在较低的温度下发生氧化还原燃烧反应,一步快速生成产品。加热起燃温度低至500℃,反应时间短,所制得的产品成份均匀,晶粒小,外观呈蓬松状态,易研磨粉碎,粉体表观密度小。以紫外-可见分光光度计测定分析了所制备样品在蓄光前后的反射光谱特征并作了探讨。结果表明,除表观密度外,“显法”与“干法”制备的长余辉发光材料的主要性质相同,紫外-可见反射光谱可以准确描述长余辉发光材料的紫外-可见光谱性能特征。 相似文献
85.
Green light emitting Mn2+ doped Zn2SiO4 particles embedded in SiO2 host matrix were synthesized by a sol–gel method. After the incorporation of ZnO:Mn nanoparticles in a silica monolith using sol–gel method with supercritical drying of ethyl alcohol in two steps, it was heat treated in air at 1200 °C for 2 h in order to obtain the SiO2/α-Zn2SiO4:Mn nanocomposites. The microstructure of phosphor crystals was characterized by transmission electron microscopy (TEM) and X-ray diffraction (XRD). XRD results indicate that the pure phase α-Zn2SiO4 with rhombohedral structure was obtained after thermal treatment at 1200 °C. The SiO2/α-Zn2SiO4:Mn nanocomposites with a Mn doping concentration of 1.5 at% exhibit two broadband emissions in the visible range: a strong green emission at around 525 nm and a second one in the range between 560 and 608 nm. This nanocomposite with a Mn doping concentration of 0.05 shows the highest relative emission intensity. Upon 255 nm excitation, the luminescence decay time of the green emission of Zn2SiO4:Mn around 525 nm is 11 ms. The luminescence spectra at 525 nm (4T1–6A1) and lifetime of the excited state of Mn2+ ions-doped Zn2SiO4 nanocrystals are investigated. 相似文献
86.
A New Higher Order Shear Deformation Model for Static Behavior of Functionally Graded Plates 下载免费PDF全文
Tahar Hassaine Daouadji Abdelouahed Tounsi & El Abbes Adda Bedia 《advances in applied mathematics and mechanics.》2013,5(3):351-364
In this paper, a new displacement based high-order shear deformation theory is introduced
for the static response of functionally graded plate. Unlike any other theory, the number
of unknown functions involved is only four, as against five in case of other shear deformation
theories. The theory presented is variationally consistent, has strong similarity with
classical plate theory in many aspects, does not require shear correction factor, and
gives rise to transverse shear stress variation such that the transverse shear stresses
vary parabolically across the thickness satisfying shear stress free surface conditions.
The mechanical properties of the plate are assumed to vary continuously in the thickness
direction by a simple power-law distribution in terms of the volume fractions of the
constituents. Numerical illustrations concerned flexural behavior of FG plates with
Metal-Ceramic composition. Parametric studies are performed for varying ceramic volume
fraction, volume fraction profiles, aspect ratios and length to thickness ratios. The
validity of the present theory is investigated by comparing some of the present results
with those of the classical, the first-order and the other higher-order theories. It
can be concluded that the proposed theory is accurate and simple in solving the static
behavior of functionally graded plates. 相似文献
87.
激光微区发射光谱分析法结合CCD光学多道分析仪测定了SrAl2O4:Eu2 ,Dy3 长余辉材料中铕的含量,研究了该方法用于长余辉材料定量分析的准确性。实验中以Eu(Ⅱ)412.973nm为分析线,计算机拟合LogIf~Logc工作曲线,对Eu的分析结果表明:分析谱线相对强度RSD为4.3%,定量分析相对标准偏差RSD为7.4%,分析结果的平均值为2.13%;采用高温固相反应法制备SrAl2O4:Eu2 ,Dy3 长余辉材料,制备前后的Eu百分含量发生明显变化,高温合成后的长余辉材料中Eu百分含量明显增大。 相似文献
88.
89.
90.
Onno de Vegt Herman Vromans Fried Faassen Kees van der Voort Maarschalk 《Particle & Particle Systems Characterization》2005,22(4):261-267
The particle size distribution of fine chemicals in the solid state, like active pharmaceutical ingredients, is often a critical parameter. To achieve the desired particle size distribution, milling of such materials is usually the method of choice. Since these chemicals are often scarcely available, experimental optimization of milling is not possible. Therefore, a model to predict the milling conditions has been developed. The model estimates the rate of breakage function, and needs mechanical properties like hardness and yield strength as input to calculate the rate of breakage function. This paper attempts to check the validity of the model by a series of experiments. A comparison of the experimental results with the outcomes of the model using five different model compounds has been performed. It appears that the rate of breakage function can be estimated by: The model is able to rank the compounds by degree of fracture as an effect of milling. It was also possible to perform a quantitative prediction of the impact of milling pressure on the milling behavior. Finally, it appeared that the prediction of the large particles in the distribution was significantly better than small ones. Because the oversized material is usually the most critical parameter, the conclusion is that the model has acceptable practical applicability. 相似文献