Dynamics of charge transfer at Au/Si metal-semiconductor nano-interface

An ab initio analysis of the periodic array of Au/Si nanostructure composed of gold clusters linked to silicon quantum dot (QD) co-doped by aluminium and phosphorus along [111] direction is presented in this paper. The density functional theory (DFT) is used to compute the electronic structure of the simulated system. Non-adiabatic coupling implemented in the form of dissipative equation of motion for reduced density matrix is used to study the phonon-induced relaxation in the simulated system. The density of states clearly shows that the formation of Au–Si bonds contributes states to the band gap of the model. Dynamics of selected photo-excitations shows that hole relaxation in energy and in space is much faster than electron relaxation, which is due to the higher density of states of the valence band.     

源气体对沉积的a-C∶F∶H薄膜结构的影响

采用微波电子回旋共振等离子体化学气相沉积(MWPECRCVD)方法,使用不同的源气体(CHF3CH4,CHF3C2H2,CHF3C6H6)体系制备了aC∶F∶H薄膜.由于CH4,C2H2,C6H6气体在等离子体中的分解反应不同导致了薄膜的沉积速率和结构上的差异.红外吸收谱的结果表明,用C6H6CHF3作为源气体沉积的薄膜中几乎不含H,而用C2H2CHF3所沉积的薄膜中的含氟量最高,其相应的CF振动峰位向高频方向偏移.薄膜的真空退火结果表明,aC∶F∶H薄膜的热稳定性除了取决于薄膜的CC键浓度外,还与CC键 关键词： 氟化非晶碳膜 电子回旋共振化学气相沉积 红外吸收光谱     

双光束组合激光辐照光导型CdS光电探测器的实验研究

为研究波段内和波段外组合激光对光导型光电探测器的辐照效应,实验采用532nm(波段内)和1319nm(波段外)双光束组合连续激光辐照光导型CdS光电探测器,分别改变两束激光的辐照功率,得到探测器的电压响应曲线。实验结果表明,光电探测器对波段内和波段外激光都有响应,但在激光开始和停止辐照瞬间探测器对两束激光的响应电压刚好相反。探测器对波段外激光的电压响应随线性工作区间内的波段内激光功率升高而增大;随着波段内激光趋于饱和,对波段外激光的响应电压近似指数级下降。分析认为,光电探测器对波段外激光的响应为光激发热载流子效应,是由自由载流子吸收激光能量产生带内跃迁引起的;波段内激光辐照影响探测器对波段外激光的吸收系数。     

高斯光束非线性“热像”效应研究

高功率激光系统中非线性“热像”强度可能达到光学元件损伤阀值，从而对系统的安全运行造成威胁.以往的非线性“热像”现象研究都是基于无限大平面光波背景，但实际系统中传输的是有限束宽光束.本文以高斯光束为例，基于无像差自聚焦理论分析了有限束宽光束的“热像”形成规律.结果表明，高斯光束“热像”的强度与位置在光束腰斑较小时与平面光波情况有明显不同，但光束腰斑较衍射物大得多时，高斯光束可以近似当作平面光波处理.     

水雾红外隐身的冷/热目标效应

人工水雾对抗红外成像制导导弹时,会因为蒸发对流强、辐射热流弱而使水雾形成冷目标;也可能因为辐射热流过强、散热弱而形成热目标。为详细揭示该现象,以Mie理论为基础,通过辐射传递方程和能量守恒方程的耦合计算,建立了水雾红外隐身产生冷目标或热目标效应的数学模型。应用蒙特卡洛法与本文算法作对比,验证了模型的正确性;将水雾视为吸收、发射、各向异性散射介质,考虑水雾自身辐射、多重散射和各种换热过程,比如辐射热流、两相流的热传导、热对流、紊流热扩散以及雾滴蒸发等,反映了水雾热遮蔽所产生的冷/热目标效应。     

基于SSCVD方法的a-b轴取向ZnO薄膜制备

以Zn₄(OH)₂(O₂CCH₃)₆·2H₂O为单一固相有机源,采用单源化学气相沉积法(Single sour cechem icalvapor deposition,SSCVD)在Si(100)衬底上制备ZnO薄膜,用X射线衍射(XRD)、原子力显微镜(AFM)分析ZnO薄膜样品的晶体结构和微观形貌,并用X射线光电子能谱(XPS)对薄膜的锌氧化学计量比进行了分析。研究结果表明:在非平衡条件下所得到的ZnO薄膜沿a-b轴取向生长,基片温度对ZnO薄膜生长过程影响较大,随着基片温度的升高,薄膜呈现c轴生长趋势;晶粒成柱状、尺寸均匀、膜层结构致密;薄膜样品中n_Zn:n_O=0.985。     

粘纤单丝数目自动检测系统的研究

针对化纤企业生产、检测的需要,研制了一种粘纤单丝数目自动检测系统。系统采用环形光源,从周围均匀照明经静电和高速风两次分离的粘纤,再由成像物镜将分离的粘纤清晰成像至高速面阵CCD传感器靶面上,基于Directshow技术自行编制出图像采集程序。利用自主研发的图像处理软件,处理粘纤图像信息,自动计算其单丝的数目,并给出判别结果。在图像处理方面采用分行消包络阈值分割法和连通域跟踪计数法,解决了粘纤计数中的胶丝重叠、分叉等关键技术难题,保证了计数准确率。该系统具有精度高、检测速度快等特点。     

Atmospheric pressure chemical vapour deposition of fluorine‐doped tin(IV) oxide from fluoroalkyltin precursors

Perfluoroalkytin compounds R_(4−n)Sn(R_f)_n (R = Me, Et, Bu, R_f = C₄F₉, n = 1; R = Bu, R_f = C₄F₉, n = 2, 3; R = Bu, R_f = C₆F₁₃, n = 1) have been synthesized, characterized by ¹H, ¹³C, ¹⁹F and ¹¹⁹Sn NMR, and evaluated as precursors for the atmospheric pressure chemical vapour deposition of fluorine‐doped SnO₂ thin films. All precursors were sufficiently volatile in the range 84–136 °C and glass substrate temperatures of ca 550 °C to yield high‐quality films with ca 0.79–2.02% fluorine incorporation, save for Bu₃SnC₆F₁₃, which incorporated <0.05% fluorine. Films were characterized by X‐ray diffraction, scanning electron microscopy, thickness, haze, emissivity, and sheet resistance. The fastest growth rates and highest quality films were obtained from Et₃SnC₄F₉. An electron diffraction study of Me₃SnC₄F₉ revealed four conformations, of which only the two of lowest abundance showed close F Sn contacts that could plausibly be associated with halogen transfer to tin, and in each case it was fluorine attached to either the γ‐ or δ‐carbon atoms of the R_f chain. Copyright © 2005 John Wiley & Sons, Ltd.     

热囚禁离子系统中的两量子比特条件相位门的简单方案

提出了一个实现两离子量子逻辑门的简单方案。本方案使用了两个囚禁于线性阱的三能级离子。本方案不使用振动模作为数据总线,仅需要激光与离子的单个相互作用,因而相互作用时间变短,这点从退相干的角度看是很重要的,而且本方案对振动模的加热不敏感。     

Röntgenographische Strukturuntersuchung geschmolzener Magnesium-Blei Legierungen

Abstract

Um Aufschluß über die Atomanordnung in geschmolzenen Magnesium-Blei Legierungen zu erhalten, wurden rontgenographische Strukturuntersuchungen durchgeführt.