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31.
Monodisperse polyaniline nanoparticles (PAPSSA) were synthesized from an oxidative dispersion polymerization using poly(sodium 4-styrenesulfonate) (PSSA) as both a polymeric stabilizer and a dopant agent due to its acidity. The nanoparticles were being stabilized with two different molecular weight of PSSA. Size effect of PAPSSA particles were examined by scanning electron microscopy (SEM), transmission electron microscopy (TEM) and dynamic light scattering (DLS). The d.c. electrical conductivity of composite films on the glass substrate was measured by a four-probe method. It was found that the electrical properties of the composite films are affected by the content of nano-sized polyaniline and different molecular weights of stabilizer in the poly(vinyl alcohol) (PVA) matrix. 相似文献
32.
We propose a new approach towards proving that the fixed point property for ordered sets is preserved by products. This approach uses a characterization of fixed points in products via isotone relations. First explorations of classes of isotone relations are presented. These first explorations give us hope that this approach could lead to advances on the Product Problem. 相似文献
33.
C. Vaca‐Garcia G. Gozzelino W. G. Glasser M. E. Borredon 《Journal of Polymer Science.Polymer Physics》2003,41(3):281-288
The main transitions of cellulose fatty esters with different degrees of substitution (DSs) were investigated with dynamic mechanical thermal analysis. Two distinct main relaxations were observed in partially substituted cellulose esters (PSCEs). They were attributed to the glass‐transition temperature and to the chain local motion of the aliphatic substituents. The temperatures of both transitions decreased when DS or the number of carbon atoms (n) of the acyl substituent increased. Conversely, all the transitions of fully substituted cellulose esters occurred within a narrow temperature range, and they did not vary significantly with n. This phenomenon was explained by the formation of a crystalline phase of the fatty substituents. The presence of few residual OH groups in PSCEs was responsible for a large increase in the storage bending modulus, and it eliminated the effect of n on damping. © 2002 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 41: 281–288, 2003 相似文献
34.
K-强凸空间的一些性质 总被引:4,自引:0,他引:4
结合Banach空间的Drop性,利用K维体积给出了K—强凸空间的一个新的定义,同时也给出了K—强光滑空间定义的K维体积表示,然后利用单位圆的切片证明了K—强凸空间是自反空间,进而证明了K—强凸空间与K—强光滑空间是一对对偶空间.最后利用Drop性的切片描述证明了K—强凸空间具有Drop性. 相似文献
35.
Frequency dependence of ac conductivity from 1 to 105 Hz and time series of the conductivity at 2 kHz were measured along c-axis of thulium nitrate crystal, Tm(NO3)36H2O at temperatures from 203.15 to 293.15 K. The meta-stability was observed. The frequency spectra of the conductivity were similar to those in disorder system. Aging effect was observed. Non-periodic instability (burst) was found. Non-linear dynamical property was characterized by 1/f noise spectrum, limit cycle in return map and dependence of correlation exponent on embedding dimension. 相似文献
36.
We examine to what extent finite-dimensional spaces defined on locally compact subsets of the line and possessing various weak Chebyshev properties (involving sign changes, zeros, alternation of best approximations, and peak points) can be uniformly approximated by a sequence of spaces having related properties. 相似文献
37.
Hsien-Chung Wu 《Fuzzy Optimization and Decision Making》2003,2(1):61-73
The concept of fuzzy scalar (inner) product that will be used in the fuzzy objective and inequality constraints of the fuzzy primal and dual linear programming problems with fuzzy coefficients is proposed in this paper. We also introduce a solution concept that is essentially similar to the notion of Pareto optimal solution in the multiobjective programming problems by imposing a partial ordering on the set of all fuzzy numbers. We then prove the weak and strong duality theorems for fuzzy linear programming problems with fuzzy coefficients. 相似文献
38.
X.X. Guo 《Surface science》2004,549(3):211-216
We studied parallel conductivities of pure BaF2 films with thicknesses ranging from 35 to 300 nm, epitaxially grown on Al2O3(0 1 2) substrates by molecular beam epitaxy technique. The overall conductivities of the films are found to increase with decreasing thickness. The detailed investigation of the overall conductance as a function of the thickness permits the deconvolution of bulk and boundary effects, the latter being attributed to distinct space charge effects in the interface between BaF2 film and Al2O3 substrate. The (extrinsic) Debye length (λ) is estimated to be about 8 nm at T=593 K, which corresponds to an impurity content of 1018/cm3 (singly ionized dopant assumed). This is consistent with the fact that we observed a constant boundary contribution for all investigated films (film thickness >4λ). It is also consistent with the Debye length observed in a previous report on CaF2/BaF2 heterolayers fabricated by the same technique, in which the low temperature enhancement was also attributed to space charges in BaF2 [Nature 408 (2000) 946]. Only at low temperatures (below 370 °C), the conductance seems to be influenced by strain effect. 相似文献
39.
A. BOURHIM 《数学年刊B辑(英文版)》2004,25(3):369-382
In this note, the local spectral properties of unilateral operator weighted shifts arestudied. 相似文献
40.
The specific heat and related thermophysical properties of liquid Fe77.5Cu13Mo9.5 monotectic alloy were investigated by an electromagnetic levitation drop calorimeter over a wide temperature range from 1482 to 1818 K. A maximum undercooling of 221 K (0.13 Tm) was achieved and the specific heat was determined as 44.71 J·mol-1·K-1. The excess specific heat, enthalpy change, entropy change and Gibbs free energy difference of this alloy were calculated on the basis of experimental results. It was found that the calculated results by traditional estimating methods can only describe the solidification process under low undercooling conditions. Only the experimental results can reflect the reality under high undercooling conditions. Meanwhile, the thermal diffusivity, thermal conductivity, and sound speed were derived from the present experimental results. Furthermore, the solidified microstructural morphology was examined, which consists of (Fe) and (Cu) phases. The calculated interface energy was applied to exploring the correlation between competitive nucleation and solidification microstructure within monotectic alloy. 相似文献