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981.
Terblanche CJ Reynhardt EC Rakitianski SA Van Wyk JA 《Solid state nuclear magnetic resonance》2001,19(3-4):107-129
13C Spin–lattice relaxation (SLR) times in the laboratory frame have been measured at room temperature as a function of field in the range of 500 to 5000 G on two natural type Ib and Ia diamonds after dynamic nuclear polarization. Each of the diamonds contains two types of fixed paramagnetic centers with overlapping inhomogeneous electron paramagnetic resonance (EPR) lines. EPR techniques have been employed to identify these defects and to determine their concentrations and relaxation times at X-band. Three different nuclear SLR paths, namely that due to electron SLR and two types of three spin processes, are discussed. The one three-spin process (TSP) (type 1) involves a simultaneous transition of two electron spins belonging to the same hyperfine EPR line and a 13C spin while the other process (type 2) involves two electron spins belonging to different hyperfine EPR lines and a 13C spin. It is shown that the thermal contact between the 13C nuclear Zeeman and electron dipole–dipole interaction reservoirs decreases with an increase in field intensity, thus forming a bottleneck in the 13C relaxation path due to the type 1 TSP. The contribution of TSP of type 1 dominates that due to electron SLR and the type 2 TSP in relaxing the 13C nuclei in type Ib diamond from about 1200 to 5000 G, while for type Ia diamond it dominates from 500 up to about 2200 G. In type Ia diamond over the range 2200 to 5000 G it seems that the type 2 TSP, which involves electrons of neighboring P2 hyperfine lines, dominates that of electron spin–lattice and the type 1 TSP. Over the range 500 to about 1200 G, a field-dependent electron SLR mechanism associated with N3 centers appears to dominate the 13C SLR. 相似文献
982.
H. P. Benson 《Journal of Optimization Theory and Applications》1999,102(2):289-298
The concept of a -valid cutting plane has been used in many types of algorithms for solving concave minimization problems. Unfortunately, the procedures proposed to date for constructing these cuts are valid only under certain assumptions that often may not hold in practice. Chief among these is the requirement that the feasible region of the concave minimization problem in question have full dimension, and that the objective function of this problem be concave rather than quasiconcave. In this article, we propose, validate, and show how to implement a more general -valid cutting plane procedure which eliminates these restrictions. 相似文献
983.
984.
G. A. Gusakov N. M. Lapchuk A. V. Mudryi G. G. Fedoruk 《Journal of Applied Spectroscopy》2003,70(3):440-444
Optical and paramagnetic properties of synthetic diamond single crystals grown by the temperature gradient method in the Fe-Co-C and Fe-Co-Al-C systems using split-sphere high-pressure apparatus have been investigated. For crystals with a high (>5·1017 cm–3) nitrogen concentration a good agreement of the concentrations of single substitution nitrogen atoms obtained from EPR, IR, and UV measurements was observed. For crystals with a low ((0.5–5.0)·1017 cm–3) nitrogen concentration, there was no correlation between the results of substituting nitrogen concentrations obtained by the methods mentioned. It is shown that this behavior is attributable to the transition of the substituting nitrogen atoms from the paramagnetic neutral to nonparamagnetic positive charge state due to compensation by the boron impurity. 相似文献
985.
On the basis of the results from the FT-IR, XRD and catalytic studies, a suggestion about the mechanism of surface transformations of Ni-supported detonation-synthesized ultradispersed diamond and the influence of these transformations on the state of the loaded metal have been made. It was proposed that in dependence on the inert or oxidative atmosphere applied for the elimination of the Ni salt precursor, different interactions of the support with the NiO species have taken place that determined the way of their coordination and stability as well as the dispersion of the metal nickel phase formed upon their reduction. The catalytic activity of the latter has been tested in the reaction of toluene hydrogenation. 相似文献
986.
Selva Bilge Leyla Karadurmus Esen Bellur Atici Ali Sınağ Sibel A. Ozkan 《Electroanalysis》2022,34(8):1318-1328
Ruxolitinib (RUX), a compound of the pyrrolopyrimidines class with activity as a tyrosine kinase inhibitory drug, is used to treat myelofibrosis. This study is reported for the detailed electrochemical behavior of RUX. The effects of supporting electrolyte, pH, and scanning rate on the peak potentials and currents of RUX were investigated by BDDE and GCE using different voltammetric techniques. Under optimum experimental conditions, calibration curves for RUX were obtained as 4 μM–80 μM and 1 μM–80 μM with a limit of detection (LOD) of 0.517 μM and 0.192 μM by the GCE and BDDE, respectively using DPV. 相似文献
987.
In data science, data are often represented by using an undirected graph where vertices represent objects and edges describe a relationship between two objects. In many applications, there can be many relations arising from different sources and/or different types of models. Clustering of multiple undirected graphs over the same set of vertices can be studied. Existing clustering methods of multiple graphs involve costly optimization and/or tensor computation. In this paper, we study block spectral clustering methods for these multiple graphs. The main contribution of this paper is to propose and construct block Laplacian matrices for clustering of multiple graphs. We present a novel variant of the Laplacian matrix called the block intra‐normalized Laplacian and prove the conditions required for zero eigenvalues in this variant. We also show that eigenvectors of the constructed block Laplacian matrix can be shown to be solutions of the relaxation of multiple graphs cut problems, and the lower and upper bounds of the optimal solutions of multiple graphs cut problems can also be established. Experimental results are given to demonstrate that the clustering accuracy and the computational time of the proposed method are better than those of tested clustering methods for multiple graphs. 相似文献
988.
在爆轰反应区的热密产物流中进行Brown运动的最初碳原子珠通过任意碰撞在C-J面处聚结成碳液滴。这个过程可以近似用胶体理论的快速聚沉动力学来描述。假定在爆轰反应区末端爆轰产物中碳液滴数等于聚沉过程结束时的碳滴数,则在此基础上计算得到的类金刚石碳滴的生成时间在爆轰反应区的时间长度内,实验中得到的超细金刚石的大颗粒(~20nm)含有约7.3610 ̄5个原子,其对应反应区内的液态碳滴可以近似处理成严格进行两分子反应的碳的十九级滴,当碳滴所包含的碳原子数达到以上特定值时,爆轰反应过程结束,因此碳滴形成时间能被估算出来。 相似文献
989.
本文在对多输入多输入振动传递系统进行结构分析的基础上,建立了该系统的网络模型和数学规划模型,给出了一种求振动传递总能量的基本最大流算法,并通过分析一简单实例说明此算法的具体应用。 相似文献
990.
锯切花岗石过程中金刚石节块磨损特征及影响因素分析 总被引:5,自引:6,他引:5
在已有的节块磨损规律的基础上,对锯切花岗石过程中的金刚石及其固位载体-粘合剂的磨损规律进行了研究。通过实验,跟踪观察了不同金刚石节块在各种加工条件下的磨损状态。结果表明;金刚石的工作状态与节块的使用性能有良好的对应关系,金刚石的微破碎和完善晶型比例越高节块耐磨性越好;宏观破碎和脱落比例越高节块耐磨性越差。金刚石的粒度,含量,品级,粘合剂和金刚石的匹配以及锯切用量组合等均明显影响锯切效果。 相似文献