CVD法制备高质量金刚石单晶研究进展

本文介绍了制备单晶金刚石的主要方法并对其进行了对比,从籽晶选择、预处理和生长工艺几个方面综述了微波等离子体化学气相沉积法制备金刚石单晶的研究进展,并简单介绍了目前国内外在单晶金刚石制备上的进展,最后对CVD金刚石单晶在电子领域的应用进行了展望.     

衍射光学元件车削补偿技术的研究

超精密单点金刚石车削加工是高精度衍射光学元件制造的重要方法,但是以往的加工方法是直接一次车削加工成型,无法实现具有加工-检测-补偿加工-检测的闭环控制特点的超精密加工,从而导致零件精度较低。针对这种加工技术的缺陷,通过研究衍射光学元件金刚石车削过程和面形状误差补偿,对表面轮廓仪实际测量的轮廓数据进行处理,计算出实际车削曲线与理想曲线之间的法向残余误差,以此获得新的金刚石车削加工轨迹,实现衍射光学元件的超精密闭环控制加工。利用单点金刚石车床对口径78的衍射光学元件进行补偿加工试验,最终使其PV值由10.4 m经过一次补偿加工后降为4.3 m。     

Approximating max-cut under graph-MSO constraints

We consider the max-cut and max-$k$-cut problems under graph-based constraints. Our approach can handle any constraint specified using monadic second-order (MSO) logic on graphs of constant treewidth. We give a $\frac{1}{2}$-approximation algorithm for this class of problems.     

可靠性试验浅述

该文基于可靠性原理,简要介绍了可靠性试验的目的和意义;可靠性试验的分类及可靠性试验的方案和设计。     

Nanostructuring of diamond films using self-assembled nanoparticles

We report the use of gold, nickel and diamond nanoparticles as a masking material for realization of diamond nano-structures by applying the dry plasma etching process. Applying low power plasma (100 W) in a gas mixture of CF₄/O₂ for 5 minutes results in a formation of three different types of diamond nanostructures, depending on the mask type material and particle size. Using of the Ni mask results in realization of diamond nano-rods, applying of the Au mask brings cauliflower-like structures, and using the diamond powder allows the production of irregular nano-structures. The main advance of the presented etching procedure is use of a self-assembly strategy where no lithographic steps are implemented.      

EACVD摆动衬底空间流场有限元模拟研究

根据EACVD系统的实际几何特点和工艺参数建立了该系统的三维流场有限元模型,研究了衬底温度及摆动周期、热丝参数、进气口参数对衬底表面流场均匀性的影响.结果表明:衬底低速摆动情况下摆动周期的变化对衬底表面流场的分布没有影响,衬底温度,热丝参数,进气口参数对衬底表面流场都有一定的影响,其中,热丝的排列方式以及进气口气体流量对衬底表面流场的影响最大.最后,采用一组优化的沉积参数进行金刚石膜衬底表面流场的仿真计算,结果表明:采用优化的沉积参数可以使衬底表面气体流速和流场的均匀性都得到很大提高,此研究结果为制备高质量金刚石膜提供理论依据.     

人造含硼金刚石单晶表面形貌与生长机制研究

本文借助Olympus光学显微镜、扫描电子显微镜(SEM)和原子力显微镜(AFM)对高温高压合成的含硼金刚石单晶表面形貌进行了分析.研究发现,含硼金刚石表面存在蚀坑、球形颗粒集团、平行台阶、花瓣状生长丘和三角形螺旋台阶等多种表面形貌.这些形貌与晶体内部的缺陷有关,硼原子的进入使金刚石晶体生长速度增加,位错增多,进而导致不同表面形貌的形成,螺旋位错生长是含硼金刚石的主要生长方式.     

Edge-swapping algorithms for the minimum fundamental cycle basis problem

We consider the problem of finding a fundamental cycle basis with minimum total cost in an undirected graph. This problem is NP-hard and has several interesting applications. Since fundamental cycle bases correspond to spanning trees, we propose a local search algorithm, a tabu search and variable neighborhood search in which edge swaps are iteratively applied to a current spanning tree. We also present a mixed integer programming formulation of the problem whose linear relaxation yields tighter lower bounds than other known formulations. Computational results obtained with our algorithms are compared with those from the best available constructive heuristic on several types of graphs. This article extends the conference paper (Amaldi et al. 2004).     

流动注射-电化学氧化法测定水体化学需氧量

采用硼掺杂金刚石(Boron-doped diamond,BDD)薄膜电极为工作电极,利用流动注射分析方法测定水体化学需氧量(COD),根据水样中有机物组分在工作电极表面氧化消耗的电量(Qoxidation)测定样品的COD值。考察了一些基本参数包括载液、工作电位、流速对检测信号的影响并选定了最佳检测条件。在最佳检测条件下,本法检测COD的线性范围为2.5~120 mg/L,检出限为1 mg/L。用该法测定化工厂和食品厂废水的COD值,相对标准偏差和回收率分别在2.4%~4.8%和96%~106%之间,且检测结果与国家标准方法(CODcr法)有良好的一致性。     

Equivalence between intersection cuts and the corner polyhedron

Intersection cuts were introduced by Balas and the corner polyhedron by Gomory. Balas showed that intersection cuts are valid for the corner polyhedron. In this paper we show that, conversely, every nontrivial facet-defining inequality for the corner polyhedron is an intersection cut.