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31.
M. D'Apuzzo A. Aronne S. Esposito P. Pernice 《Journal of Sol-Gel Science and Technology》2000,17(3):247-254
The sol-gel synthesis of silicophosphate gels using phosphoryl chloride and tetraethoxysilane as molecular precursors is reported and discussed. Gel-derived glasses and films having the molar compositions 10P2O5 · 90SiO2 and 30P2O5 · 70SiO2 have been obtained. The structure of the dried gels as well as the structural modifications that occurs during the transformations in gel-derived glasses are analyzed by Fourier transform infrared spectroscopy (FTIR). It has been found that the evidence of the P—O—Si linkages begins to appear only on the FTIR spectra of the bulk gels heat treated up to 400°C while they are well resolved on the FTIR spectra of the bulk gel samples heated up to 1000°C indicating that at this temperature the transformation in the corresponding gel-derived glasses occurs. The humidity sensitive properties of the gel-films have been evaluated by electrochemical impedance spectroscopy (EIS). The phosphorous content as well as the temperature of the heat treatments strongly affect the sensitivity to RH of the gel-derived films. 相似文献
32.
高介电常数陶瓷储能脉冲形成线需要用到多开关触发的层叠Blumlein线结构。从形成线波过程理论出发,分析了多开关导通时间分散性对层叠Blumlein线及其输出波形的影响。主要包括两方面影响:其一是造成输出方波脉冲的前沿和后沿均出现阶梯形畸变;其二是使得各延迟导通的平行平板Blumlein线承受过电压,容易引起陶瓷储能介质的电击穿。在不单独考虑开关电感的理想情况下,利用PSpice电路程序模拟了开关导通时间分散性对四级层叠Blumlein线的影响,模拟结果与波过程理论分析一致。为减弱这些影响,提出了可行的解决方案。 相似文献
33.
A potential calcium-phosphate fl ower-like nanocoating were coated onto the titanium surface in an easy approach. It has high surface area, low cytotoxicity as well as promising cell affi nity, which makes it a potential alternative modifi cation method for titanium surface. 相似文献
34.
综合ZnO-Al2O3-SiO2系和锗酸盐玻璃陶瓷的优点,采用熔融-晶化法首次制备了Ho3+/Yb3+共掺以ZnAl2O4为主晶相的ZnO-Al2O3-GeO2-SiO2系玻璃陶瓷。因[GeO4]四面体和[SiO4]四面体都是玻璃网络形成体,讨论了GeO2取代SiO2对玻璃陶瓷样品硬度及发光性能的影响,最终确定GeO2的取代量为10.55%(w/w)时,玻璃陶瓷综合性能最佳。在980 nm泵浦光的激发下,发现强的绿色(546 nm)和弱的红色(650 nm)上转换发光,并研究了不同Ho3+/Yb3+掺杂比对样品上转换发光的影响,最终结果表明当Ho3+/Yb3+掺杂比为1:11(n/n)时样品荧光强度最强,在绿色上转换发光材料方面具有潜在的应用。 相似文献
35.
Jutapol Jumpatam Bundit Putasaeng Narong Chanlek Prasit Thongbai 《Molecules (Basel, Switzerland)》2021,26(7)
The microstructure, dielectric response, and nonlinear current-voltage properties of Sr2+-doped CaCu3Ti4O12/CaTiO3 (CCTO/CTO) ceramic composites, which were prepared by a solid-state reaction method using a single step from the starting nominal composition of CCTO/CTO/xSrO, were investigated. The CCTO and CTO phases were detected in the X-ray diffraction patterns. The lattice parameter increased with increasing Sr2+ doping concentration. The phase compositions of CCTO and CTO were confirmed by energy-dispersive X-ray spectroscopy with elemental mapping in the sintered ceramics. It can be confirmed that most of the Sr2+ ions substituted into the CTO phase, while some minor portion substituted into the CCTO phase. Furthermore, small segregation of Cu-rich was observed along the grain boundaries. The dielectric permittivity of the CCTO/CTO composite slightly decreased by doping with Sr2+, while the loss tangent was greatly reduced. Furthermore, the dielectric properties in a high-temperature range of the Sr2+-doped CCTO/CTO ceramic composites can be improved. Interestingly, the nonlinear electrical properties of the Sr2+-doped CCTO/CTO ceramic composites were significantly enhanced. The improved dielectric and nonlinear electrical properties of the Sr2+-doped CCTO/CTO ceramic composites were explained by the enhancement of the electrical properties of the internal interfaces. 相似文献
36.
James P. Best Johannes Zechner Jeffrey M. Wheeler Rachel Schoeppner Marcus Morstein 《哲学杂志》2016,96(32-34):3552-3569
For the implementation of thin ceramic hard coatings into intensive application environments, the fracture toughness is a particularly important material design parameter. Characterisation of the fracture toughness of small-scale specimens has been a topic of great debate, due to size effects, plasticity, residual stress effects and the influence of ion penetration from the sample fabrication process. In this work, several different small-scale fracture toughness geometries (single-beam cantilever, double-beam cantilever and micro-pillar splitting) were compared, fabricated from a thin physical vapour-deposited ceramic film using a focused ion beam source, and then the effect of the gallium-milled notch on mode I toughness quantification investigated. It was found that notching using a focused gallium source influences small-scale toughness measurements and can lead to an overestimation of the fracture toughness values for chromium nitride (CrN) thin films. The effects of gallium ion irradiation were further studied by performing the first small-scale high-temperature toughness measurements within the scanning electron microscope, with the consequence that annealing at high temperatures allows for diffusion of the gallium to grain boundaries promoting embrittlement in small-scale CrN samples. This work highlights the sensitivity of some materials to gallium ion penetration effects, and the profound effect that it can have on fracture toughness evaluation. 相似文献
37.
In order to improve the performance and durability of polymer electrolyte fuel cells (PEFCs), various improvements in the microstructures of cathode catalyst layers (CLs) were initiated in the early 1990s. More recent advances in CL materials are highlighted, including carbon supports for improved accessibility of Pt nanoparticles (NPs), adsorption of ionomer on the Pt surface, high-oxygen-permeability ionomers, corrosion resistance of mesoporous and microporous carbons, and conductive ceramic supports with a fused-aggregate network structure. These approaches are summarized as stepwise improvements. The influences of the support structure on the distribution of Pt NPs and ionomer are reviewed, as well as their effects on performance and durability. These approaches for carbon supports are extended to conductive ceramic supports and the unique advantages are discussed. 相似文献
38.
采用固相反应制备了Mg1-xCux TiO3(0.00≤x≤0.20)微波介电陶瓷,研究CuO烧结助剂对MgTiO3陶瓷的微观结构和微波介电性能的影响。实验结果表明,CuO中的Cu2+离子会进入到MgTiO3晶格中并取代Mg2+,形成Mg1-xCux TiO3固溶体。由于液相效应,适量的CuO可以促进MgTiO3陶瓷的致密化烧结,降低其烧结温度。Cu2+离子的A位取代会改变样品的TiO6八面体扭曲度。随着Cu2+离子含量的增加,会使MgTiO3陶瓷的结构稳定性降低。随着CuO含量的增加,晶粒的不均匀生长和液相的出现导致样品的品质因数(Qf)下降。同时,Mg1-xCux TiO3陶瓷的相对密度、结构... 相似文献
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