全文获取类型
收费全文 | 647篇 |
免费 | 158篇 |
国内免费 | 138篇 |
专业分类
化学 | 357篇 |
晶体学 | 106篇 |
力学 | 133篇 |
综合类 | 7篇 |
数学 | 14篇 |
物理学 | 326篇 |
出版年
2024年 | 3篇 |
2023年 | 4篇 |
2022年 | 17篇 |
2021年 | 15篇 |
2020年 | 17篇 |
2019年 | 7篇 |
2018年 | 8篇 |
2017年 | 49篇 |
2016年 | 66篇 |
2015年 | 14篇 |
2014年 | 32篇 |
2013年 | 40篇 |
2012年 | 40篇 |
2011年 | 57篇 |
2010年 | 32篇 |
2009年 | 57篇 |
2008年 | 49篇 |
2007年 | 55篇 |
2006年 | 53篇 |
2005年 | 33篇 |
2004年 | 34篇 |
2003年 | 42篇 |
2002年 | 33篇 |
2001年 | 22篇 |
2000年 | 22篇 |
1999年 | 25篇 |
1998年 | 11篇 |
1997年 | 30篇 |
1996年 | 12篇 |
1995年 | 16篇 |
1994年 | 18篇 |
1993年 | 4篇 |
1992年 | 4篇 |
1991年 | 7篇 |
1990年 | 4篇 |
1989年 | 3篇 |
1988年 | 3篇 |
1987年 | 2篇 |
1985年 | 1篇 |
1982年 | 1篇 |
1971年 | 1篇 |
排序方式: 共有943条查询结果,搜索用时 31 毫秒
151.
152.
153.
Spherical magnetic Mg-Fe-O nanoparticles were successfully prepared by the crystallization of glass in the system K2O/B2O3/MgO/P2O5/Fe2O3. The magnetic glass ceramics were prepared by melting the raw materials using the conventional melt quenching technique followed by a thermal treatment at temperatures in the range 560–700 °C for a time ranging from 2 to 8 h. The studies of the X-ray diffraction, electron microscopy and FTIR spectra confirmed the precipitation of finely dispersed spherical (Mg, Fe) based spinel nanoparticles with a minor quantity of hematite (α-Fe2O3) in the glass matrix. The average size of the magnetic nano crystals increases slightly with temperature and time from 9 to 15 nm as determined by the line broadening from the XRD patterns. XRD studies show that annealing the glass samples for long periods of time at temperature ≥604 °C results in an increase of the precipitated hematite concentration, dissolution of the spinel phase and the formation of magnesium di-borate phase (Mg2B2O5). For electron microscopy, the particles were extracted by two methods; (i) replica extraction technique and (ii) dissolution of the glass matrix by diluted acetic acid. An agglomeration of the nano crystals to larger particles (25–35 nm) was observed. 相似文献
154.
Spectroscopic properties and mechanism of Tm^3+/Er^3+/Yb^3+ co-doped oxyfluorogermanate glass ceramics containing BaF2 nanocrystals
下载免费PDF全文
![点击此处可从《中国物理 B》网站下载免费的PDF全文](/ch/ext_images/free.gif)
Transparent Tm^3+/Er^3+/yb^3+ co-doped oxyfluorogermanate glass ceramics containing BaF2 nanocrystals are prepared. Under excitation of a 980-nm laser diode (LD), compared with the glass before heat treatment, the Tm^3+/Er^3+/yb^3+ co-doped oxyfluorogermanate glass ceramics can emit intense blue, green and red up-conversion luminescence and Stark- split peaks; X-ray diffraction (XRD) and transmission electron microscope (TEM) results show that BaF2 nanocrystals with an average diameter of 20 nm are precipitated from the glass matrix. Stark splitting of the up-conversion luminescence peaks in the glass ceramics indicates that Tm^3+, Er^3+ and (or) Yb^3+ ions are incorporated into the BaF2 nanocrystals. The up-conversion luminescence intensities of Tm^3+, Er^3+ and the splitting degree of luminescence peaks in the glass ceramics increase significantly with the increase of heat treat temperature and heat treat time extension. In addition, the possible energy transfer process between rare earth ions and the up-conversion luminescence mechanism are also proposed. 相似文献
155.
156.
纳米孔莫来石陶瓷材料的制备 总被引:2,自引:2,他引:0
以正硅酸乙酯(TEOS)提供硅源、纳米氧化铝(d90=50 nm)提供铝源,通过溶胶-凝胶法与超临界干燥技术,制备了分散纳米氧化铝的SiO2气凝胶块体,所得复合气凝胶块体经1200℃、1300℃热处理后,得到了纳米孔莫来石陶瓷材料。XRD测试表明:凝胶体在1 200℃热处理后发生了莫来石化,1300℃莫来石化基本完成。压汞仪与场发射扫描电镜结果显示:凝胶块体经1 200、1 300℃热处理后,形成了具有纳米多孔结构的莫来石陶瓷材料,其骨架结构包含有200~400 nm的大孔,以及大量位于其孔壁上的6~30 nm的介孔。由于莫来石化的进行,热处理后的陶瓷材料的纳米孔结构具有更高的热稳定性。 相似文献
157.
制备了Tm3+,Yb3+共掺氟氧化物微晶玻璃, 在980 nm二极管激光器泵浦下研究了其上转换发光。发现将前驱玻璃进行热处理后,源于Tm3+的1G4能级到基态3H6跃迁所产生的蓝色上转换荧光在463 nm和476 nm出现明显劈裂。在此基础上分析了该劈裂蓝色上转换荧光在303~623 K范围内的温度特性。结果表明:Tm3+,Yb3+共掺氟氧化物微晶玻璃蓝色上转换荧光可应用于光学测温,其测温最大灵敏度为4.2×10-4 K-1,相应温度为352 K。 相似文献
158.
159.
A high-power high-stability Q-switched green laser with intracavity frequency doubling using a diode-pumped composite ceramic Nd:YAG laser
下载免费PDF全文
![点击此处可从《中国物理 B》网站下载免费的PDF全文](/ch/ext_images/free.gif)
We successfully obtain a high-average-power high-stability Q-switched green laser based on diode-side-pumped composite ceramic Nd:YAG in a straight plano-concave cavity. The temperature distribution in composite ceramic Nd:YAG crystal is numerically analyzed and compared with that of conventional Nd:YAG crystal. By using a composite ceramic Nd:YAG rod and a type-II high gray track resistance KTP (HGTR-KTP) crystal, a green laser with an average output power of 165 W is obtained at a repetition rate of 25 kHz, with a diode-to-green optical conversion of 14.68%, and a pulse width of 162 ns. To the best of our knowledge, both the output power and optical-to-optical efficiency are the highest values for green laser systems with intracavity frequency doubling of this novel composite ceramic Nd:YAG laser to date. The power fluctuation at around 160 W is lower than 0.3% in 2.5 hours. 相似文献
160.
EFP模拟弹丸侵彻陶瓷复合靶的数值模拟研究 总被引:1,自引:1,他引:0
运用LS_DYNA程序中描述陶瓷本构关系的JHC模型和二维轴对称拉格朗日算法,对EFP模拟弹丸侵彻不同厚度99氧化铝陶瓷块/金属复合靶试验进行了数值模拟,获得了侵彻过程中陶瓷的损伤演化和分布以及在A3钢背板中的侵彻深度,与实验结果进行了比对,总的侵彻深度基本相符。数值模拟和试验所得残余侵彻深度与陶瓷厚度之间基本上都呈一种良好的线性关系,因此所得质量防护系数和差分防护系数都随着陶瓷厚度的增加而增加。通过分析侵彻过程中的陶瓷损伤与演化发现:陶瓷块尺寸过小时会由于稀疏波作用使陶瓷抗弹性能下降。 相似文献