氧等离子体处理对纳米二氧化硅溶胶涂覆高强、高模聚乙烯纤维拉伸性能的影响

基于艾琳方程,提出用于定量分析纤维表面和纳米涂覆层间的纳米界面结构的理论模型.实验结果表明,纤维高分子链段受力塑性变形时,纳米界面结构内纳米微粒阻碍其形貌变化产生热激活体积,该热激活体积是纳米界面结构性能的重要表征;氧等离子体处理对纳米二氧化硅溶胶涂覆高强、高模聚乙烯纤维有增韧作用.由不同处理样品的扫描电子显微镜图片和傅里叶变换红外光谱曲线对比分析可知,经氧等离子体处理纳米二氧化硅溶胶涂覆高强、高模聚乙烯纤维的纳米涂覆层纳米颗粒分布均匀,纳米颗粒还填补纤维表面微观缺陷,活性官能团被引入到纤维表面. 关键词： 激活体积 氧等离子体 高强、高模聚乙烯纤维 纳米界面结构     

A Finite Volume Method Preserving Maximum Principle for the Conjugate Heat Transfer Problems with General Interface Conditions

In this paper, we present a unified finite volume method preserving discrete maximum principle (DMP) for the conjugate heat transfer problems with general interface conditions. We prove the existence of the numerical solution and the DMP-preserving property. Numerical experiments show that the nonlinear iteration numbers of the scheme in [24] increase rapidly when the interfacial coefficients decrease to zero. In contrast, the nonlinear iteration numbers of the unified scheme do not increase when the interfacial coefficients decrease to zero, which reveals that the unified scheme is more robust than the scheme in [24]. The accuracy and DMP-preserving property of the scheme are also veried in the numerical experiments.     

Absorbing Interface Conditions for the Simulation of Wave Propagation on Non-Uniform Meshes

We proposed absorbing interface conditions for the simulation of linear wave propagation on non-uniform meshes. Based on the superposition principle of second-order linear wave equations, we decompose the interface condition problem into two subproblems around the interface: for the first one the conventional artificial absorbing boundary conditions is applied, while for the second one, the local analytic solutions can be derived. The proposed interface conditions permit a two-way transmission of low-frequency waves across mesh interfaces which can be supported by both coarse and fine meshes, and perform a one-way absorption of high-frequency waves which can only be supported by fine meshes when they travel from fine mesh regions to coarse ones. Numerical examples are presented to illustrate the efficiency of the proposed absorbing interface conditions.     

一类无界且带不平坦界面的声波导传播计算

无界且带不平坦界面的声波导经局部正交变换和完美匹配层（PML）截断,波导计算问题可近似转化为有界且带有平坦界面的声波导的Helmholtz方程,由于利用PML进行截断,此方程为复偏微分方程,其特征函数系一般不具有正交性,故数值步进求解时,存在着局部基下坐标转换的困难．本文一方面运用共轭特征算子,通过其所对应的特征函数系与原特征函数系的正交性,给出了局部基下坐标转换的简便公式;另一方面,利用此简便公式,进行了声波导的步进计算,数值计算结果表明,所用方法切实可行．     

SiC/SiO_2界面粗糙散射对沟道迁移率影响的Monte Carlo研究

提出了一种SiC反型层表面粗糙散射的指数模型 ,并对 6H SiC反型层迁移率进行了单电子的MonteCarlo模拟 ,模拟中考虑了沟道区的量子化效应 .模拟结果表明 ,采用表面粗糙散射的指数模型能够使SiC反型层迁移率的模拟结果和实验值符合得更好 .模拟结果还反映出有效横向电场较高时表面粗糙散射的作用会变得更显著 ,电子的屏蔽效应降低了粗糙散射对沟道迁移率的影响 ,温度升高会引起沟道迁移率降低 .     

Simple models of proteins with repulsive non-native contacts

The Go model is extended to the case when the non-native contact energies may be either attractive or repulsive. The folding temperature is found to increase with the energy of non-native contacts. The repulsive non-native contact energies may lead to folding at T=0 for some unusual two-dimensional sequences and to reduction in complexity of disconnectivity graphs for local energy minima. Received 10 May 1999 and Received in final form 13 October 1999     

指控装备通信接口可重构测试系统软件框架设计

指控装备通信接口种类繁多,每种接口的测试需求也不尽相同,传统接口测试系统大多仅针对某个厂家的具体设备和接口开发,功能单一,软硬件重用率低,更新维护成本高。针对上述问题,分析总结了指控装备通信接口的接口特性和测试需求,通过深入研究小型化SCA技术,设计了满足通信接口可重构测试需求的自定义中间件和自定义核心框架,完成了可在通用小型硬件平台上实现的指控装备通信接口可重构测试系统软件框架。由系统典型测试流程图可看出,用户仅通过更改应用组件和系统配置即可实现对多种通信接口的可重构测试,增强了测试系统的通用性和灵活性,提高了测试系统软硬件的重用率,降低了接口测试系统的开发和维护费用。     

粗糙纳通道内流体流动与传热的分子动力学模拟研究

为研究粗糙表面对纳尺度流体流动和传热及其流固界面速度滑移与温度阶跃的影响,本文建立了粗糙纳通道内流体流动和传热耦合过程的分子动力学模型,模拟研究了粗糙通道内流体的微观结构、速度和温度分布、速度滑移和温度阶跃并与光滑通道进行了比较,并分析了固液相互作用强度和壁面刚度对界面处速度滑移和温度阶跃的影响规律. 研究结果表明,在外力作用下,纳通道主流区域的速度分布呈抛物线分布,由于流体流动导致的黏性耗散使得纳通道内的温度分布呈四次方分布. 并且,在固体壁面处存在速度滑移与温度阶跃. 表面粗糙度的存在使得流体剪切流动产生了额外的黏性耗散,使得粗糙纳通道内的流体速度水平小于光滑通道,温度水平高于光滑通道,并且粗糙表面的速度滑移与温度阶跃均小于光滑通道. 另外,固液相互作用强度的增大和壁面刚度的减小均可导致界面处速度滑移和温度阶跃程度降低. 关键词： 速度滑移 温度阶跃 流固界面 粗糙度     

The Construction of Sandbag Microstructure in Polyamide 6/Ethylene-Propylene-Diene Terpolymer/Nanometer Calcium Carbonate Ternary Composite

A sandbag microstructure was constructed in Polyamide 6(PA6)/ethylene-propylene-diene terpolymer (EPDM)/nanometer calcium carbonate (nano-CaCO₃) ternary composites by the addition of maleinated EPDM (EPDM-g-MA) to reduce the interfacial tension between EPDM and PA6 and EPDM and nano-CaCO₃. Scanning electron microscopy (SEM) observation and differential scanning calorimetry (DSC) analysis revealed that the microstructure of the ternary composites evolved from the initial separated EPDM and nano-CaCO₃ dispersion structure to the sandbag structure and finally to the separated dispersion structure again with the increase of EPDM-g-MA content in the elastomer phase. The mechanical results showed the composites with the sandbag microstructure exhibited excellent toughness and stiffness.     

Effect of Surface Structure of Nano-CaCO3 Particles on Mechanical and Rheological Properties of PVC Composites

To study the effect of different surface structures on resultant mechanical and rheological properties, nano-CaCO₃ particles were treated with isopropyl tri-stearyl titanate (H928), isopropyl tri-(dodecylbenz-enesulfonyl) titanate (JN198), and isopropyl tri-(dioctylpyrophosphato) titanate (JN114). Scanning electron microscopy (SEM) and dynamic mechanic analysis (DMA), carried out to characterize the effective interfacial interaction between the nano-CaCO₃ particles and a poly(vinyl chloride) (PVC) matrix, indicated that JN114 treated nano-CaCO₃ particles had the strongest interfacial interaction with a PVC matrix, while H928 treated nano-CaCO₃ had the weakest. The rheological and mechanical properties of PVC/nano-CaCO₃ composites were investigated as a function of surface structure and filler volume fraction. The tensile yield stress and elongation at break decreased with the increasing of calcium carbonate content while tensile modulus increased. PVC filled with JN114 treated nano-CaCO₃ had the highest tensile modulus and tensile yield stress, while those filled with H928 treated nano-CaCO₃ had the highest elongation at break at the same filler content. The impact strength of PVC/nano-CaCO₃ composites increased with the increasing of CaCO₃ content, and PVC composites filled with JN198 treated nano-CaCO₃ particle had a higher impact strength than those with JN114 or H928 treated, with the value reaching 23.9 ± 0.7 kJ/m² at 11 vol% CaCO₃, four times as high as that of pure PVC. Rheological properties indicated that a suitable interfacial interaction and a good dispersion of inorganic filler in a PVC matrix could reduce the viscosity of PVC/nano-CaCO₃ composites. The interfacial interaction was quantitatively characterized by semiempirical parameters calculated from the tensile strength of PVC/nano-CaCO₃ composites to confirm the results from the SEM and DMA experiments.