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111.
ABSTRACTCo-crystallization frequently employs forces such as hydrogen bonds, halogen bonds, and π-π stacking to assemble molecules in a multi-component crystal. In an effort to increase the strength of the intermolecular interaction between the anti-cholesterol drug bezafibrate (BEZA), a wastewater contaminant, and hydrogen-bond-acceptor molecules, we modified the pKa values of the acceptors. Here, we describe the first series of salts incorporating BEZA and achieve a variety of supramolecular architectures including discrete assemblies, 1D chains, tapes, and 2D sheets. We discuss exceptions to the pKa rule, and demonstrate that the presence of hydrogen-bond-donor atoms on the acceptor molecule supports salt formation. 相似文献
112.
Marina S. Fonari Victor Ch. Kravtsov Yurii A. Simonov Edward V. Ganin Vladimir O. Gelmboldt Janusz Lipowski 《Journal of inclusion phenomena and macrocyclic chemistry》2001,39(1-2):85-89
The crystalline host–guest type complex [(18-crown-6NH4)2][SiF6]4H2Ohas been obtained as the result of the interaction of SiF42NH3 with 18-crown-6 (18C6) in an aqueous medium. Crystal data: monoclinic, space groupC 2 c, a=26.541(2), b=8.363(2), c=20.469(2) Å, = 122.43(1)°and Z=4. The final R-value is 0.070 for 3253 reflections with I 2(I).The crystals consist of the complex [NH418C6]+ cations, [SiF6]2-anions and water molecules. The ammonium cation is hydrogen bonded by three of its H-atoms to the crown ether oxygen atoms with N(1) O separations2.923(5)–2.940(5) Å and by the fourth H-atom to the fluorine atom of thehexafluorosilicate anion, the N(1)F(4) distance being 2.797(6) Å.The conformation of the macrocycle and the hydrogen-bond geometry in thecomplex cation closely resemble those in related adducts between 18-crown-6and ammonium salts. All crystal components are connected via a system of hydrogen bonds into a ribbon along the b axis in the unit cell. 相似文献
113.
Tingmin Wang Jerald S. Bradshaw Janet C. Curtis Peter Huszthy Reed M. Izatt 《Journal of inclusion phenomena and macrocyclic chemistry》1993,16(2):113-122
Significant - interaction is found in the complexes of (S, S)-dimethylpyridino-18-crown-6 with (R)- and (S)-[-(1-naphthyl)ethyl]ammonium perchlorate. This finding is supported by the1H NOESY NMR spectral technique, greater chemical shift changes of aromatic protons in both host and guest molecules upon complexation, and by molecular mechanics calculations. Because of the flexibility of the ligand, the tripod hydrogen bonding causes13C relaxation times of all periphery carbons to decrease without significant selectivity. Rotational energy barrier calculations of the methyl groups of the complexed ligand also show that the (S, S)-host-(R)-guest is the more stable complex. 相似文献
114.
Gupta D Roitzsch M Lippert B 《Chemistry (Weinheim an der Bergstrasse, Germany)》2005,11(22):6643-6652
Isocytosine (ICH; 1) exists in solution in an equilibrium of tautomers 1a and 1b with the N1 and N3 positions carrying the acidic proton, respectively. In the solid state, both tautomers coexist in a 1:1 ratio. As we show, the N3H tautomer 1b can selectively be crystallized in the presence of the model nucleobase 1-methylcytosine (1-MeC). The complex 1b x (1-MeC)2 x H2O (2) forms pairs through three hydrogen bonds between the components; hydrogen bonds between identical molecules are also formed, leading to an infinite tape structure. On the other hand, the N1H tautomer 1a co-crystallizes with protonated ICH to give [1a x ICH2]NO3 (3), again with three hydrogen bonds between the partners, yet the acidic proton is disordered over the two entities. With M(II)(dien) (M=Pt, Pd; dien=diethylenetriamine) preferential coordination of tautomer 1a through the N3 position is observed. DFT calculations, which were also extended to Pt(II)(tmeda) linkage isomers (tmeda=N,N,N',N'-tetramethylethylenediamine), suggest that intramolecular hydrogen bonding between the ICH tautomers and the co-ligands at M, while adding to the preference for N3 coordination, is not the major determining factor. Rather it is the inherently stronger Pt-N3 bond which favors complexation of 1a. With an excess of M(II)(dien), dinuclear species [M2(dien)2(IC-N1,N3)]3+ (M=Pd(II), 4 and Pt(II), 5) also form and were isolated as their ClO4(-) salts and structurally characterized. In strongly acidic medium 5 is converted to [Pt(dien)(ICH-N1)]2+ (6), that is, to the Pt(II) complex of tautomer 1b. 相似文献
115.
A.I. Baranov L. Kloo R.A. Lunin B.A. Popovkin 《Journal of solid state chemistry》2004,177(10):3616-3625
A systematic search for mixed low-valence, nickel-tin chalcogenides performed by establishing phase relations in the parts of Ni-Sn-Se and Ni-Sn-Te ternary systems resulted in the discovery of two new compounds, Ni5.62SnSe2 and Ni5.78SnTe2. Single crystals of both compounds were prepared by chemical transport with iodine and crystal structures were determined by single crystal X-ray investigation. The ED patterns for Ni5.78SnTe2 showed the presence of satellite reflections, which indicate a modulated structure with q≈0.4a*. Average crystal structures of both compounds were determined to be of tetragonal symmetry (Sp.gr. I4/mmm, Z=2) with a=3.6890(8) Å, c=18.648(3) Å, Rw=0.0716 and a=3.7680(5) Å, c=19.419(4) Å, Rw=0.0832, correspondingly, and are isostructural to known Ni5.72SbSe2 and Ni5.66SbTe2. Measurements were carried out for both compounds with respect to thermal, electrical and magnetic properties. Ab initio band structure calculations were also performed to take a first glance into the electronic structure of such type compounds. The anisotropy of their band structure was found. Physical property measurements showed both compounds to be the anisotropic metallic conductors and paramagnetics. Calculated difference charge density maps revealed pairwise covalent and multicenter metallic nature of the d-metal—chalcogen and d-metal—p-metal interactions, respectively. 相似文献
116.
Cyclical bifurcated hydrogen bonded structures are proposed for aqueous solutions of hydrofluoric acid and for the bifluoride ion which are consistent with the spectral data. The structure proposed for HF is also applicable to solutions in organic solvents. Raman spectra of tetramethylguanidinium perchlorate suggest that the corresponding Raman spectra of perchloric acid solutions may not be interpreted in terms of a completely dissociated acid. Other evidence including activity coefficient, heat capacity and partial molal volume data suggest that there is some association in relatively dilute perchloric acid solutions between the perchlorate ion and the hydrated proton. This association decreases in concentrated aqueous solutions. 相似文献
117.
A generalization of the kinetic equation for the isotope exchange at solid—liquid interface is presented. The generalized equation may be used to describe kinetics of the isotope exchange process limited by surface reactions and diffusion without assumption of spherical symmetry of solid particles.
Eine generalisierte Gleichung für die Kinetik des Isotopenaustausches an Fest-Flüssig-Phasengrenzen
Zusammenfassung Es wird eine generalisierte kinetische Gleichung angegeben, die die Kinetik des Isotopenaustausches an Fest-Flüssig-Phasengrenzen beschreibt, wobei der Austauschprozeß durch Oberflächenreaktionen und Diffusion ohne der Annahme sphärischer Symmetrie für die festen Partikel begrenzt ist.相似文献
118.
For most oxide/electrolyte systems potentiometric titration curves measured for different ionic strengths have a Common Intersection Point (CIP) which corresponds to the Point of Zero Charge (PZC). However, there are systems where a CIP exists but the surface charge at this point does not equal zero (PZC CIP). In this paper theoretical analysis of the systems in which the PZC and CIP do not coincide is presented. It is based on the well-known 2-pK surface charging approach and Triple Layer Model (TLM) as well as the Four Layer Model (FLM) of the electric double layer. The appropriate mathematical criterion for CIP existence was applied with detailed derivations, both for TLM and FLM. Having determined in this manner the parameter values, one can draw proper conclusions about the features of oxide/electrolyte adsorption systems, in which PZC and CIP do not coincide. The values of adsorption parameters are found by fitting simultaneously the obtained theoretical expressions to both of the experimental titration isotherms, and to the individual isotherms of electrolyte cation adsorption measured using radiometric methods. 相似文献
119.
Equilibrium geometries, interaction energies, and charge transfer for the intermolecular interactions between BrF and HnX (HF, H2O, and NH3) were studied at the MP2/6-311++G(3d,3p) level. The halogen-bonded geometry and hydrogen-bonded geometry are observed in these interactions. The calculated interaction energies show that the halogen-bonded structures are more stable than the corresponding hydrogen-bonded structures. To study the nature of the intermolecular interactions, symmetry-adapted perturbation theory (SAPT) calculations were carried out and the results indicate that the halogen bonding interactions are dominantly inductive energy in nature, while electrostatic energy governs the hydrogen bonding interactions. 相似文献
120.
Changes in the stability of the cadmium(ii) ethylenediamine complexes in mixed water—DMSO solvents were studied by pH-metry and calorimetry. Complex cations [Cd(en)]2+, [Cd(en)2]2+, and [Cd(en)3]2+ are formed in aqueous solutions, and the [Cd(en)4]2+ complex with a partially dentate ligand is stable in DMSO. An increase in the DMSO content in a solvent increases the stability of the complexes. The maximum increase in logK is observed for coordinatively saturated compounds. The thermodynamics of complexation is discussed from the viewpoint of solvation approach. Principal differences in the influence of aqueous-alcohol and aqueous-aprotic solvents on the stability of the metal amino complexes were revealed. Protolytic solvents exert a destabilizing effect on the multiligand complexes, because the coordination sphere is involved in H bonding. 相似文献