横向位移双曝光散斑图维纳谱的信息分布

讨论了横向位移双曝光散斑图维纳谱的信息分布，并由此导出杨氏纹图的一般表达式。讨论了条纹可见度与应变，面内转动，照明光束直径与条纹图图空间坐标的关系，指出了在条纹可见度影响下最大可见条纹数目。还讨论了散斑衬比与衍射晕的关系。     

Structural Phase Transformations of ZnS Nanocrystalline Under High Pressure

In-situ energy dispersive x-ray diffraction on ZnS nanocrystalline was carried out under high pressure by using a diamond anvil cell. Phase transition of wurtzite of 10nm ZnS to rocksalt occurred at 16.0GPa, which was higher than that of the bulk materials. The structures of ZnS nanocrystalline at different pressures were built by using materials studio and the bulk modulus, and the pressure derivative of ZnS nanocrystalline were derived by fitting the equation of Birch-Murnaghan. The resulting modulus was higher than that of the corresponding bulk material, which indicates that the nanomaterial has higher hardness than its bulk materials.     

顶部籽晶法生长磁光晶体硼酸铁

本文首次采用顶部籽晶泡生法在敞开体系中生长了出了磁光晶体硼酸铁单晶。选用Ｂ２Ｏ３作自助溶剂，ＬｉＦ作稀释剂，确定了原料配方。对长出的晶体作了初步的物化性能测试。讨论了晶体生长的结果。     

峪耳崖金矿矿化绢云母的同步辐射X荧光分析

峪耳崖金矿是冀东地区与中生代花岗岩有关金矿订的典型代表.本文利用同步辐射微束X荧光对裕耳崖金矿化绢云母进行了组成成分分析,显示绢云母体内含有K,Ca,Rb,Cr,Mn,Fe,Co,Cu和Zn,以及成矿物质Au,Ag,Pt和As,Au既与绢云母的组成元素呈相关关系,又与绢云母组成元素不相关的Pt,As呈相关关系,显示了Au在绢云母中存在两种赋存形式及至少两种不同的成矿物质来源.金矿的成矿物质来源,通常认为与岩浆体系有关,蚀变矿物中Pt族元素的发现,反映了成矿过程中有深部幔源物质的参与.     

Crystal-Orientation Dependent Evolution of Edge Dislocations from a Void in Single Crystal Cu

The micro-void growth by dislocation emission under tensile loading is explored with focus on the influence of crystal orientations. Based on the elastic theory, a dislocation emission criterion is formulated. It is predicted that the preferential location of dislocation nucleation and its threshold stress are dependent on the crystal orientation. Large-scale molecular dynamics （MD） simulations are also performed for single crystal copper to illustrate the dislocation evolution pattern associated with a nano-void growth. The results are in line with those given by the theoretical prediction. As revealed by MD simulations, the characteristics of void growth at micro-scale depend greatly on the crystal-orientation.     

菲涅耳与波动光学

 一、科学渊源与历史背景光是什么?是波,还是粒子?这个问题的争论由来已久,并一直萦绕在许多科学家的脑海里。虽然光学的起源可以追溯到远古时代,但是光学形成为一门独立的学科体系,还是在16、17世纪实验科学发展的推动下促成的。15世纪末～16世纪初,欧洲的玻璃制造业已相当发达,到16世纪末,眼镜的使用已很普遍,眼镜制造业已成为一个十分健全的工业。而望远镜和显微镜的发明,则是17世纪初光学仪器发展的最大成就。与之相适应,在这一时期,也就出现了以胡克（R.Hooke,1635～1703）描述显微观察的专著《显微学》为代表的光学著作。     

CuX(X=Al, Ga, In)分子的势能函数与稳定性的密度泛函研究

根据原子分子反应静力学原理导出了CuX(X=Al,Ga,In) 分子基态电子状态及其离解极限,并在B3LYP/LANL2DZ水平上计算了平衡几何、振动频率和解离能.利用Murrell-Sorbie 函数拟合出了解析势能函数,并计算出光谱参数和力常数.计算结果表明该分子体系是稳定存在的,其稳定性排序为 CuAl＞CuGa＞CuIn.     

Synthesis and Properties of a Heteronuclear Ag（Ⅰ）/Ni（Ⅱ） Complex

Introduction Itiswell knownthatcyanogroupsincyanometa latessuchas[Ag(CN)2]-unitscanbeusedasbridg ingligandsandapolymericstructurecanbeformed throughsilver silver(argentophilic)interactions.This propertyhasbeenexploredintheconstructionofmany oligomericandp…     

同步辐射X射线和中子粉末衍射及Rietveld精化（1）

把Rietveld精化方法用于处理同步辐射X射线和中子粉末衍射数据，使得粉末试样的结构研究有很大发展。本文在简要介绍两种粉末衍射术和Rietveld方法之后，用实例描述它们在结构精化、解未知结构、沸石、有关微孔材料及磁结构材料测定中的应用。