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291.
Optical heterodyne magnetic rotation enhanced velocity modulation spectroscopy was employed to observe the visible absorption spectra of the B^2Σ^+_u-X^2Σ^+_g electronic transition of C^-_2. Four hot bands (0,1), (1,2), (2,3) and (3,4) have been observed and the band (3,4) is measured directly for the first time, so far as we know, by absorption. A rotational analysis was carried out to obtain molecular constants. With the Franck-Condon principle and the vibrational Boltzmann distribution, we have estimated the vibrational temperature of C^-_2 to be about 3000K. 相似文献
292.
293.
294.
Serge Palacin Christophe Bureau Julienne Charlier Guy Deniau Brigitte Mouanda Pascal Viel 《Chemphyschem》2004,5(10):1468-1481
Electrografting is a powerful and versatile technique for modifying and decorating conducting surfaces with organic matter. Mainly based on the electro-induced polymerization of dissolved electro-active monomers on metallic or semiconducting surfaces, it finds applications in various fields including biocompatibility, protection against corrosion, lubrication, soldering, functionalization, adhesion, and template chemistry. Starting from experimental observations, this Review highlights the mechanism of the formation of covalent metal-carbon bonds by electro-induced processes, together with major applications such as derivatization of conducting surfaces with biomolecules that can be used in biosensing, lubrication of low-level electrical contacts, reversible trapping of ionic waste on reactive electrografted surfaces as an alternative to ion-exchange resins, and localized modification of conducting surfaces, a one-step process providing submicrometer grafted areas and which is used in microelectronics. 相似文献
295.
Abakumov G. A. Druzhkov N. O. Kurskii Yu. A. Shavyrin A. S. 《Russian Chemical Bulletin》2003,52(3):712-717
Products of thermal transformation of substituted N-aryl-o-quinoneimines were studied using NMR spectroscopy. The formation of 4aH-phenoxazine, which was further dimerized by the Diels—Alder reaction, was established. 相似文献
296.
We introduce new classes of 2-weight cyclic codes which are direct sums of 1-weight irreducible cyclic codes
相似文献
297.
Reaction of arenesulfonylimines of methyl trifluoropyruvate with 1,3-C,N-and-N,N-binucleophiles led to a variety of N-sulfonylated fluorine-containing heterocycles, including the fused ones.
Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 11, pp. 2171–2175, November, 2007. 相似文献
298.
A photoemission study of molybdenum hexacarbonyl adsorption and decomposition on TiO2(1 1 0) surface
The adsorption and decomposition of molybdenum hexacarbonyl on (1 1 0) TiO2 surfaces were studied using both core levels and valence band photoemission spectroscopies. It was found that after an adsorption at 140 K, when going back to room temperature, only a small part of molybdenum compounds, previously present at low temperature, remained on the TiO2 surface. This indicates that the desorption temperature on such a surface is lower than the decomposition one. The use of photon irradiation to decompose the hexacarbonyl molecule was also studied. It was shown that during such a decomposition molecular fragments were chemisorbed on the surface allowing a higher amount of metal to remain on the surface. It was also shown that it was possible to get rid of adsorbed subcarbonyl groups and to organize the metal atoms by thermal treatments at temperatures as low as 400 K, i.e. much lower than the one needed to obtain the same structures using physical vapour deposition (PVD). Moreover, due to lower used temperatures, this chemical way of deposition allows a better control of the interface than during PVD growth. 相似文献
299.
A transverse flow, transverse discharge cw CO2 laser in which de discharge is sustained by employing high repetition rate high voltage pulses has been developed. Pulser
sustained discharge through electrodes of innovative design provided uniform excitation at electrical input power densities
more than 10 W/cc. Laser output power more than 2.5 kW was obtained in a laser gas mixture consisting of 0.5 mbar of CO2, 16 mbar of N2 and 38.5 mbar of He. Design details and operational characteristics of this laser are presented. 相似文献
300.
热等离子体裂解天然气制备C2烃 总被引:1,自引:0,他引:1
采用氮气热等离子体来裂解天然气制备乙炔乙烯,着重研究了天然气转化率和乙炔、乙烯收率随氮气流量和天然气流量的变化.结果表明,天然气流量与氮气流量之比为11时,可得到较好的结果.当等离子体功率为15kW、天然气流量为3Nm3*h-1、氮气流量为3Nm3*h-1时得到最好的结果.这时天然气转化率为57%,乙炔、乙烯的收率分别为34%和9%;乙炔在反应气中的体积浓度为7.5%,与部分氧化法相似;扣除不参加反应的氮气,乙炔在气相产品中的体积浓度为13.2%,与热力学平衡计算结果基本符合. 相似文献