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81.
LIU Chun PAN Wei YANG Yang WANG Ke-wei DONG De-wen .Chemistry Biology College Beihua University Jilin P.R.China 《高等学校化学研究》2009,25(1)
A facile and convenient one-pot synthesis method of substituted cyclopropanes in water has been developed.A series of 1,1-disubstituted cyclopropanes 3 were synthesized from the reaction of β-dicarbonyl compounds 1 with 1,2-dibromoethane 2,in very high yields catalyzed by tetrabutylammonium bromide(TBAB) at 50 oC in the presence of K2CO3 in water.The catalyst TBAB in the aqueous phase can be reused after the separation of organic products. 相似文献
82.
M. Narender 《Tetrahedron letters》2004,45(43):7995-7997
A variety of N-tosylaziridines undergo regioselective ring opening with tetrabutylammonium halides in the presence of β-cyclodextrin in water at pH 4 and room temperature to afford the corresponding haloamines in excellent yields. 相似文献
83.
This article reviews the most common, useful methods for the chiral determination of amphetamine (AM) and AM-derived designer drugs in different of matrix, including blood, hair, urine, medicaments or standard solutions, taking into consideration articles published in the past 15 years. We consider chromatographic methods (e.g., gas, liquid, high-performance liquid, and thin layer). We describe several types of chiral derivatization reagent, mobile-phase additive and chiral stationary phase commonly used in the chromatographic methods. Tables summarize basic information about conditions (e.g., type of column and mobile phase), detection mode and reference data for each procedure. 相似文献
84.
85.
Epoxidation of various alkenes in low to high yields (29-100%) and good to excellent selectivities (75-100%) was performed with tetrabutylammonium monopersulfate in the presence of meso-tetrakis(pentafluorophenyl)porphyrin as catalyst and tetrabutylammonium acetate or fluoride or imidazole as co-catalysts in CH2Cl2, in less than 10 min at room temperature (∼25 °C). 相似文献
86.
Mohammad Navid Soltani Rad Somayeh Behrouz Ali Khalafi-Nezhad 《Tetrahedron letters》2008,49(7):1115-1120
An efficient and selective method for esterification of alcohols using N-(p-toluenesulfonyl)imidazole (TsIm) is described. In this method, alcohols are refluxed with a mixture of RCO2Na (R: alkyl and aryl), TsIm, and triethylamine in the presence of catalytic amounts of tetra-n-butylammonium iodide (TBAI) in DMF to afford the corresponding esters in good yields. This methodology is highly efficient for various structurally diverse alcohols with selectivity for ROH: 1° > 2° > 3°. 相似文献
87.
Binuclear iron(III) phthalocyanine-(μ-oxodimer) complex was tested in catalytic oxygenation reactions of several hydrocarbons using tetrabutylammonium oxone as the oxidant in dichloromethane solution at room temperature. Results of the study demonstrate that this is an extremely powerful catalytic system for oxidative conversion of aromatic hydrocarbons (anthracene, 2-tert-butylanthracene, 2-methylnaphthalene, 9,10-dihydroanthracene, 1,2,3,4-tetrahydronaphthalene, indane, ethylbenzene, toluene, and benzene) to the respective p-quinones in high yields in 5-30 min. Under these conditions, adamantane is oxidized with 71% conversion after 10 min affording a mixture of 1-adamantanol, 2-adamantanone, 1-hydroxy-2-adamantanone, and 4-protoadamantanone. 相似文献
88.
Mariappan Periasamy G.P. Muthukumaragopal Nalluri Sanjeevakumar 《Tetrahedron letters》2007,48(39):6966-6969
Diborane is readily generated in situ at 25 °C in toluene using the Bu4NBH4/PhCH2Cl and Bu4NBH4/I2 reagent systems. The reagent prepared in this way is used for the reduction of carbonyl compounds and hydroboration-oxidation of olefins to obtain the corresponding alcohols in good yields. 相似文献
89.
In this paper, surface-enhanced Raman spectroscopy has been used to investigate the electrode/electrolyte interface during
Ag electrodeposition from water–acetonitrile mixed solvents. The reactivity of acetonitrile during Ag electrodeposition has
been monitored, promoted by the electrocatalytic activity of silver clusters electrodeposited onto the electrode surface.
The effect of the addition of tetrabutylammonium cations to the mixed solvents has been investigated and its adsorption and
tilting on the silver surface has been followed as a function of the cathodic overpotential. 相似文献
90.
Ratnadeep S. Joshi Priyanka G. Mandhane Sanjay K. Dabhade Charansingh H. Gill 《中国化学会会志》2010,57(6):1227-1231
One‐pot multistep reactions involving a new environmentally friendly catalytic procedure have been developed for the synthesis of benzimidazole. The reaction of the substituted aldehyde with o‐phenylenediamine in water under ultrasonic irradiation at ambient temperature for appropriate time using 5 mol% of TBAF furnish the desired product in good to excellent yield. The process is green, mild, inexpensive, excellent chemo selectivity, and excellent yields are the main advantages of this procedure. 相似文献