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71.
Whereas glucose oxidase and related proteins are encapsulated readily in silica sol–gels, α-hydroxy enzymes such as lactate
oxidase (LOx), are reported to be damaged by electrostatic interaction with these matrices. Based on a previous report, poly(ethyleneimine),
PEI, was evaluated as a protecting compound under conditions suited to analytical measurements. With LOx and PEI co-encapsulated
in a silica sol–gel, the enzyme retained 62% of its initial activity after 20 days. In the absence of PEI, activity was lost
during the processing. Batch analytical measurements with enzyme-doped sol–gel yielded a linear response over the range 0.5–2.0 mM
lactate and a detection limit of 0.03 mM lactate. Both simple incorporation of LOx in a silica sol–gel and an alternative
protection method, blocking the ion-exchange sites on silica with La(III), failed. These negative results supported the hypothesis
that the efficacy of PEI was related to its formation of a protective sheath around the enzyme.
Author for correspondence. E-mail: coxja@muohio.edu
Received July 29, 2002; accepted December 15, 2002
Published online May 19, 2003 相似文献
72.
O. Wibbelhoff C. Meier A. Lorke P. Schafmeister A. D. Wieck 《Physica E: Low-dimensional Systems and Nanostructures》2004,21(2-4):516
We use frequency-dependent capacitance–voltage spectroscopy to study the dynamic charging of self-assembled InAs quantum dots. With increasing frequency, the AC charging becomes suppressed, beginning with the low-energy states. By applying an in-plane magnetic field, we generate an additional magnetic confinement that alters the tunneling barrier and hence the charging dynamics. In traveling through the potential barrier, the electrons acquire an additional momentum k0, proportional to the magnetic field B. As the tunneling is enhanced, when k0 matches the maximum of the electronic wave function Ψ (in momentum representation), we are able to map out the shape of Ψ by varying B. 相似文献
73.
D. Chithrani R. L. Williams J. Lefebvre P. J. Poole G. C. Aers 《Physica E: Low-dimensional Systems and Nanostructures》2004,21(2-4):290
We discuss the preparation and spectroscopic characterisation of a single InAs/InP quantum dot suitable for long-distance quantum key distribution applications around λ=1.55 μm. The dot is prepared using a site-selective growth technique which allows a single dot to be deposited in isolation at a controlled spatial location. Micro-photoluminescence measurements as a function of exciton occupation are used to determine the electronic structure of the dot. Biexciton emission, shell filling and many-body re-normalization effects are observed for the first time in single InAs/InP quantum dots. 相似文献
74.
采用ICP-AES法对钛基复合材料中的合金元素镍、钕、铁的测定进行了研究,着重进行了基体元素及待测元素镍、钕、铁之间干扰试验及各元素在测定浓度范围内的线性相关性试验,进行了酸度试验,测定了钛基复合材料中3种元素的含量,得到了较好的精密度和准确度。方法简便、可靠,获得满意的分析结果。 相似文献
75.
Toshiyuki Sugawa 《Monatshefte für Mathematik》2003,139(1):61-68
The inner radius of univalence of a domain D with Poincaré density ρ
D
is the possible largest number σ such that the condition ∥ S
f
∥
D
= sup
w∈ D
ρ
D
(w)
−2∥ S
f
(z) ∥ ≤ σ implies univalence of f for a nonconstant meromorphic function f on D, where S
f
is the Schwarzian derivative of f. In this note, we give a lower bound of the inner radius of univalence for strongly starlike domains of order α in terms
of the order α.
The author was partially supported by the Ministry of Education, Grant-in-Aid for Encouragement of Young Scientists, 11740088.
A part of this work was carried out during his visit to the University of Helsinki under the exchange programme of scientists
between the Academy of Finland and the JSPS.
Received November 26, 2001; in revised form September 24, 2002
Published online May 9, 2003 相似文献
76.
77.
A new method based on anion exchange resin separation and graphite furnace atomic absorption spectrometry (GFAAS) detection
is proposed for the determination of inorganic tin species. The result showed that Sn(IV) was quantitatively retained on the
resin when [HCl] = 9.0 mol · L−1, but Sn(II) could not be adsorbed on the resin under the same condition. Thus, a separation of Sn(II) and Sn(IV) has been
realized. When the concentration of NaOH solution was between 2.0–7.0 mol · L−1, Sn(IV) that adsorbed on the resin could be eluated from the resin completely. Meanwhile, under the atmosphere and the nitrogen
states, the translation between Sn(II) and Sn(IV) was investigated. Under the optimal conditions, the detection limit of Sn(IV)
is 0.40 μg · L−1 with RSD of 2.3% (n = 5, c = 2.0 μg · L−1). The proposed method was applied to the speciation analysis of tin in different water samples and the recovery of total
Sn was in the range of 98.7–101.7%. In order to verify the accuracy of the method, a certified reference water sample was
analyzed and the results obtained were in good agreement with the certified value. 相似文献
78.
Summary. We introduce linear semi-implicit complementary volume numerical scheme for solving level set like nonlinear degenerate diffusion
equations arising in image processing and curve evolution problems. We study discretization of image selective smoothing equation
of mean curvature flow type given by Alvarez, Lions and Morel ([3]). Solution of the level set equation of Osher and Sethian
([26], \[30]) is also included in the study. We prove and estimates for the proposed scheme and give existence of its (generalized) solution in every discrete time-scale step. Efficiency
of the scheme is given by its linearity and stability. Preconditioned iterative solvers are used for computing arising linear
systems. We present computational results related to image processing and plane curve evolution.
Received April 25, 2000 / Revised version received June 11, 2001 / Published online November 15, 2001 相似文献
79.
For a conformal manifold we introduce the notion of an ambient connection, an affine connection on an ambient manifold of
the conformal manifold, possibly with torsion, and with conditions relating it to the conformal structure. The purpose of
this construction is to realise the normal conformal Tractor holonomy as affine holonomy of such a connection. We give an
example of an ambient connection for which this is the case, and which is torsion free if we start the construction with a
C-space, and in addition Ricci-flat if we start with an Einstein manifold. Thus, for a C-space this example leads to an ambient metric in the weaker sense of Čap and Gover, and for an Einstein space to a Ricci-flat
ambient metric in the sense of Fefferman and Graham.
Current address for first author: Erwin Schr?dinger International Institute for Mathematical Physics (ESI), Boltzmanngasse
9, 1090 Vienna, Austria
Current address for second author: Department of Mathematics, University of Hamburg, Bundesstra?e 55, 20146 Hamburg, Germany 相似文献
80.
O. N. Karpenkov 《Monatshefte für Mathematik》2007,152(3):217-249
In this paper we develop an integer-affine classification of three-dimensional multistory, completely empty convex marked
pyramids. We apply it to obtain the complete lists of compact two-dimensional faces of multidimensional continued fractions
lying in planes at integer distances 2, 3, 4, … to the origin. The faces are considered up to the action of the group of
integer-linear transformations. 相似文献