Specific features of photo and thermoluminescence of Tb ions in BaO-M2O3 (M=Ga, Al, In)-P2O5 glasses

BaO-P₂O₅ glasses mixed with the three metal oxides viz., Al₂O₃, Ga₂O₃ and In₂O₃ doped with Tb₂O₃ were prepared. The glasses were characterized by X-ray diffraction and differential thermal analysis. Optical absorption and photoluminescence spectra and thermoluminescence (TL) of these glasses have been studied. From the measured intensities of various absorption bands of these glasses, the Judd-Ofelt parameters Ω₂, Ω₄ and Ω₆ have been evaluated and compared with those of other reported glass systems. The Judd-Ofelt theory could successfully be applied to characterize the absorption and luminescence spectra of these glasses. From this theory various radiative properties like transition probability A, branching ratio β_r, the radiative lifetime τ_r and the emission cross-section σ^E for various emission levels of these glasses have been determined and reported. An attempt has also been made to throw some light on the relationship between the structural modifications and luminescence efficiencies of all the three glasses. The analysis of TL data indicate high non-radiative losses in In₂O₃ mixed glasses.     

+1/-1相位掩模板和532nm激光下低损耗As_2S_3硫系光纤布喇格光栅的制备

采用改进型Sagnac干涉光栅写入系统,利用532nm准带隙光曝光源和带+1/-1衍射级的相位掩模板,在两种不同直径的低损耗As_2S_3硫系玻璃光纤上刻写布喇格光栅,并研究曝光期间光栅的动态特性.实验表明,As_2S_3光纤布喇格光栅透射峰值随光纤直径的减小而增强;在曝光过程中,布喇格波长先是较快地向短波长方向移动,随着曝光时间的延长,布喇格波长缓慢地向长波长方向回复.曝光时间为800~1 000s时,在包层直径为140μm的As_2S_3光纤上获得质量良好的布喇格光栅光谱,其透射峰值可达-2.6dB,带宽为0.37nm.对As_2S_3硫系光纤纤芯的光敏性分析结果表明,折射率调制幅度和平均折射率变化随曝光时间分别可达到10-4和10-3数量级.     

Ground states versus low-temperature equilibria in random field Ising chains

Random walk arguments and exact numerical computations are used to study one-dimensional random field chains. The ground state structure is described with absorbing and non-absorbing random walk excursions. At low temperatures, the local magnetization follows the ground state except at regions where a local random field fluctuation makes thermal excitations easier. This is explained by the random walk picture, implying that the magnetization lengthscale is a product of the domain size and the thermal excitation scale. Received 16 October 2000 and Received in final form 7 June 2001     

Spectroscopic Investigation of Tungsten Ions in Lead Scandium Phosphate Glass System

Lead scandium phosphate glasses (PbO-Sc₂O₃-P₂O₅) containing different concentrations of tungsten oxide (WO₃) ranging from 0 to 5 mol% were prepared. A number of studies, viz. differential thermal analysis (DTA), infrared spectra, optical absorption, and electron spin resonance (ESR) spectra, have been carried out. The results of DTA indicated the highest glass forming ability for the glass containing 5 mol% of WO₃. The results of spectroscopic studies have been analyzed in light of different oxidation states of tungsten ions.     

Optical Analysis of Er3+:Boro-Fluoro-Phosphate Glasses

This paper deals with the preparation and optical analysis of Er³⁺ (0.2 mol%) boro-fluoro-phosphate glasses in the following glass compositions:

• Series A: 69.8 B₂O₃–10 P₂O₅–10(ZnO/CdO/TeO₂)–10 AlF₃

• Series B: 69.8 B₂O₃–10 P₂O₅–10(ZnO/CdO/TeO₂)–10 LiF

Measured Vis-NIR absorption spectra of Er³⁺:boro-fluoro-phosphate glasses have revealed nine absorption bands at 377 nm, 405 nm, 450 nm, 486 nm, 519 nm, 543 nm, 649 nm, 973 nm and 1529 nm, which correspond with the transitions of ⁴I_15/2 → ⁴G_11/2, (²G_9/2,⁴H_9/2), ⁴F_5/2, ⁴F_7/2, ²H_11/2, ⁴S_3/2, ⁴F_9/2, ⁴I_11/2, and ⁴I_13/2, respectively. With an excitation at λ _exci = 375 nm, a bright green emission (⁴S_3/2 → ⁴I_15/2) at 547 nm has been observed from these erbium glasses. Judd–Ofelt characteristic intensity Ω_λ (λ = 2, 4, 6) parameters are obtained from the absorption spectra, and these results were used to compute the radiative properties of Er³⁺:boro-fluoro-phosphate glasses. The NIR emission (⁴I_13/2 → ⁴I_15/2) at 1547 nm from these glasses was measured with an Ar⁺ laser (514.5 nm) as an excitation source.     

Effect of TiO2 addition on the crystallization of quenched glasses in the SiO2–Al2O3–ZrO2 system

The glass formation in the SiO₂-rich region of the ternary oxide system Al₂O₃–ZrO₂–SiO₂ with MgO, CaO, and TiO₂ as melting aids was analyzed. The crystallization of glasses with different content of TiO₂ and phase evolution with the temperature was studied by X-ray diffraction, infrared, laser Raman spectroscopy and transmission electron microscopy. The use of TiO₂ favored formation and crystallization of the glasses due to the decrease of the viscosity of melts and acting as a nucleating agent. The crystalline phase of t-ZrO₂ was developed at temperatures as low as 880°C whereas in as prepared specimens without TiO₂ its presence was not detected. For the specimens with TiO₂, t-ZrO₂ and mullite were the principal phases at 1000°C. TiO₂ addition did not change the crystallization sequence but decreased the formation temperature of the crystalline phases. Most of Ti⁴⁺ ions entered into t-ZrO₂ and only a small portion in mullite, but the surplus was detected in ZrTiO₄.     

Numerical study of the directed polymer in a 1 + 3 dimensional random medium

The directed polymer in a 1+3 dimensional random medium is known to present a disorder-induced phase transition. For a polymer of length L, the high temperature phase is characterized by a diffusive behavior for the end-point displacement R² ∼L and by free-energy fluctuations of order ΔF(L) ∼O(1). The low-temperature phase is characterized by an anomalous wandering exponent R²/L ∼L^ω and by free-energy fluctuations of order ΔF(L) ∼L^ω where ω∼0.18. In this paper, we first study the scaling behavior of various properties to localize the critical temperature T_c. Our results concerning R²/L and ΔF(L) point towards 0.76 < T_c ≤T₂=0.79, so our conclusion is that T_c is equal or very close to the upper bound T₂ derived by Derrida and coworkers (T₂ corresponds to the temperature above which the ratio remains finite as L ↦ ∞). We then present histograms for the free-energy, energy and entropy over disorder samples. For T ≫T_c, the free-energy distribution is found to be Gaussian. For T ≪T_c, the free-energy distribution coincides with the ground state energy distribution, in agreement with the zero-temperature fixed point picture. Moreover the entropy fluctuations are of order ΔS ∼L^1/2 and follow a Gaussian distribution, in agreement with the droplet predictions, where the free-energy term ΔF ∼L^ω is a near cancellation of energy and entropy contributions of order L^1/2.     

The Ising spin glass in finite dimensions: A perturbative study of the free energy

Replica field theory is used to study the n  -dependent free energy of the Ising spin glass in a first order perturbative treatment. Large sample-to-sample deviations of the free energy from its quenched average prove to be Gaussian, independently of the special structure of the order parameter. The free energy difference between the replica symmetric and (infinite level) replica symmetry broken phases is studied in details: the line n(T)$n(T)$ where it is zero coincides with the Almeida–Thouless line for d>8$d>8$. The dimensional domain 6<d<8$6<d<8$ is more complicated, and several scenarios are possible.     

Superconducting property of Zr–Co and Zr–Co–Al alloys fabricated by rapid solidification

The superconducting property of Zr_(1−x)Co_x (x = 10–50 at.%) alloys and a Zr₅₅Co₃₀Al₁₅ bulk metallic glass fabricated using techniques of rapid solidification was investigated. The Zr₅₅Co₃₀Al₁₅ alloy crystallized by heat treatment in a vacuum atmosphere exhibited superconductivity of T_c,on = 2.4 K. This was attributable to the superconducting property of a crystalline Zr–Co alloy precipitated in the Zr₅₅Co₃₀Al₁₅ alloy. The T_c,on of the crystalline Zr_(1−x)Co_x alloy was sensitive to the Co content. The increase of Co content for the Zr_(1−x)Co_x alloy led to the decrease of T_c,on. The Zr_(1−x)Co_x alloy exhibited superconductivity of a maximum T_c,on = 3.9 K for the Zr₈₀Co₂₀ alloy with superconducting nanocrystal particles embedded in the amorphous matrix.     

低温下Er3+/Yb3+共掺碲酸盐玻璃的发光特性研究

研究了在8—300K温度范围中, Er³⁺/Yb³⁺共掺碲酸盐玻璃的15μm荧光光谱、上转换光谱与温度的关系. Er³⁺:⁴I_13/2→⁴I_15/2跃迁发射光谱通过高斯拟合和简单的四能级系统估计了Er³⁺离子⁴I_13/2和⁴ 关键词： 碲酸盐玻璃 上转换发光 低温 荧光特性