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11.
Dushmantha Kannangara Hailong Zhang Wei Shen 《Colloids and surfaces. A, Physicochemical and engineering aspects》2006,280(1-3):203-215
The spreading and recoiling of water drops on several flat and macroscopically smooth model surfaces and on sized paper surfaces were studied over a range of drop impaction velocities using a high-speed CCD camera. The water drop spreading and recoiling results on several model hydrophobic and hydrophilic surfaces were found to be in agreement with observations reported in the literature. The maximum drop spreading diameter for those model surfaces at impact was found to be dependent upon the initial drop kinetic energy and the degree of hydrophobicity/hydrophilicity of the surface. The extent of the maximum drop recoiling was found to be much weaker for hydrophilic substrates than for hydrophobic substrates. Sized papers, however, showed an interesting switch of behaviour in the process of water drop impaction. They behave like a hydrophobic substrate when a water drop impacts on it, but like a hydrophilic substrate when water drop recoils. Although the contact angle between water and hydrophilic or hydrophobic non-porous surfaces changes from advancing to receding as reported in literature, the change of contact angle during water impact on paper surface is unique in that the level of sizing was found to have a smaller than expected influence on the degree of recoil. Atomic force microscopy (AFM) was used to probe fibres on a sized filter paper surface under water. The AFM data showed that water interacted strongly with the fibre even though the paper was heavily sized. Implications of this phenomenon were discussed in the context of inkjet print quality and of the surface conditions of sized papers. Results of this study are very useful in the understanding of inkjet ink droplet impaction on paper surfaces which sets the initial condition for ink penetration into paper after impaction. 相似文献
12.
WEN Jian-Xun YIN Hui-Yong CHEN QiShanghai Institute of Organic Chemistry Chinese Academy of Sciences Shanghai China 《中国化学》1995,13(6):515-519
A homologous series of n-butyl-4-[4-((4-n-alkoxyl-tetrafluorophenyl)ethynyl)benzyloxy]benzoates have been synthesized.Their phase transition temperatures have also measured by polarizing textural observation and confirmed by DSC. 相似文献
13.
Solid-surface room-temperature phosphorimetry (SSRTP) is proposed as an alternative detection technique for the liquid chromatographic determination of caffeine, theophylline and theobromine. The measurements are performed in a continuous mode with a two-nebulizer automated system for SSRTP detection. The analytical figures of merit obtained with the proposed detector are compared with those obtained by UV absorption detection. The SSRTP and UV chromatograms of spiked urine samples are compared, and the possibility of keeping the SSRTP substrates as permanent records of analyzed samples is discussed. 相似文献
14.
15.
V. Nagirnyi S. Chernov L. Grigorjeva L. Jönsson M. Kirm A. Kotlov 《辐射效应与固体损伤》2013,168(6-12):1123-1126
A systematic spectroscopic study of single ZnWO 4 :Fe crystals with different iron concentrations has been performed under excitation by ultraviolet light, by synchrotron radiation or under photostimulation by near-infrared light. The luminescence of Fe 3+ -related centres has been studied. It is shown that iron centres of different types efficiently promote the formation of crystal defects at low temperatures. Electrons and holes can be trapped near Fe 2+ or Fe 3+ ions, which is further revealed in phosphorescence, thermostimulated or photostimulated luminescence. At room temperature the main effect of iron impurity is to reduce the light yield of a ZnWO 4 scintillator. 相似文献
16.
《Comptes Rendus Physique》2013,14(7):531-541
This is a review of the wetting properties of solid helium on various solid substrates. Due to its extreme purity and to its very fast growth dynamics, solid helium 4 is often considered as a model system in materials science. Several wetting phenomena have been studied with helium 4 crystals, namely contact angles on solid substrates with variable roughness, wetting on graphite where epitaxial growth takes place, the roughening transition as a function of film thickness, the wetting of grain boundaries by the liquid phase. 相似文献
17.
《Analytical letters》2012,45(6):531-538
Abstract A high-resolution anion-exchange system has been developed to analyze specifically for the nucleosides and bases present in physiologic fluids. This sytem employs a unique coupled-column operation that allows rapid column stripping and regeneration on completion of each run. Results obtained in the analysis of urine for nucleosides and bases are presented. 相似文献
18.
《Physics and Chemistry of Liquids》2012,50(3):209-219
Abstract The system of hard rods in an external, uniform gravitational field is studied and exact expressions obtained for the partition functions, and the one- and two-particle distributions. In principle all higher order distributions can be exactly expressed as finite sums and the Laplace transforms of the one-particle density and pressure for a semi-infinite system are reducible to single integrals. Limiting cases of weak field and small rod diameters are examined. In the former case, these results agree with Percus and Lebowitz's local density expansion. In the latter case, corrections to the barometric pressure and density laws are obtained. Finally some mathematical difficulties involved in the calculation of the virial expansion and distribution of roots of the grand partition function are mentioned. 相似文献
19.
《Journal of Coordination Chemistry》2012,65(5):832-841
The liquid–liquid extraction of copper(II) with Schiff bases in chloroform from sulfate media is studied for pH and concentration of the extractant. Stoichiometry coefficients of the extracted species are determined by the slope analysis method. With salicylideneaniline, the copper(II) is extracted as a mixed chelate complex, CuL2HL. In the presence of substituent, the copper is extracted as simple chelates, CuL2. The trends in the values of extraction constants were explained in terms of the nature of the substituents. 相似文献
20.
Summary The nematic planar anchoring is usually explained by using simple elastic models: the surface easy axis corresponds to the
surface direction that minimizes the excess of nematic elastic energy. When anisotropic rough substrates are used to align
nematic liquid crystals, due to the complex surface morphology, usual elastic models are not directly applicable. This paper
presents quantitative topographical data of rough substrates, obtained with oblique SiO evaporation under vacuum for nematic
planar anchoring. Experimental data are obtained by means of Atomic Force Microscopy and they are used to demonstrate the
self-affine nature of these substrates and to relate the nematic anchoring with the anisotropy of the local fractal properties
of the substrate itself.
Paper presented at the I International Conference on Scaling Concepts and Complex Fluids, Copanello, Italy, July 4–8, 1994. 相似文献