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991.
Methanol oxidation in acidic alkaline electrolytes using PtRuIn/C electrocatalysts prepared by borohydride reduction process 《燃料化学学报》2018,46(12):1462-1471
PtRuIn/C electrocatalysts( 20% metal loading by weight) were prepared by sodium borohydride reduction process using H_2PtCl6·6H_2O,RuCl_3·xH_2O and InCl_3·xH_2O as metal sources,borohydride as reducing agent and Carbon Vulcan XC72 as support. The synthetized PtRuIn/C electrocatalysts were characterized by X-ray diffraction( XRD),energy dispersive analysis( EDX),transmission electron microscopy( TEM),cyclic voltammetry( CV),chronoamperommetry( CA) and polarization curves in alkaline and acidic electrolytes( single cell experiments). The XRD patterns showPtpeaks are attributed to the face-centered cubic( fcc) structure,and a shift of Pt( fcc) peaks indicates that Ru or In is incorporated into Ptlattice. TEMmicrographs showmetal nanoparticles with an average nanoparticle size between 2.7 and 3.5 nm. Methanol oxidation in acidic and alkaline electrolytes was investigated at room temperature,by CV and CA. PtRu/C( 50 ∶ 50) shows the highest activity among all electrocatalysts in study considering methanol oxidation for acidic and alkaline electrolyte. Polarization curves at 80 ℃ showPtRuIn/C( 50 ∶ 25 ∶ 25)with superior performance for methanol oxidation,when compared to Pt/C,PtIn/C and PtRu/C for both electrolytes. The best performance obtained by PtRuIn/C( 50 ∶ 25 ∶ 25) in real conditions could be associated with the increased kinetics reaction and/or with the occurrence simultaneously of the bifunctional mechanism and electronic effect resulting from the presence of Ptalloy. 相似文献
992.
设珮犠(狋):犚犖+ →犚犱是犖指标犱维广义Wiener过程,对任意紧集犈1,…,犈犿犚犖> ,该文研究了犿项代数和珮犠(犈1)…珮犠(犈犿)的Hausdorff维数,Packing维数和正的Lebesgue测度及内点的存在性. 其结果包含并推广了布朗单的结果. 相似文献
993.
Lu Chuanrong Zhejiang University of Finance Economics Zhejiang University Hangzhou China. 《高校应用数学学报(英文版)》2005,20(3):331-337
§1Introductionandresults A2-parameterGaussianprocess{Z(t,s);t,s≥0}iacalleda2-parameterfractional Wienerprocesswithorderα(0<α<1),ifZ(0,0)=0a.s.EZ(s,t)=0anditscovariance EZ(t1,s1)Z(t2,s2)={|t1|2α+|t2|2α-|t2-t1|2α}{|s1|2α+|s2|2α-|s2-s1|2α}/4.LetR=[x1,x2]×[y1,y2],DT={(x,y)∶0≤x,y≤bT,xy≤T}.Let0相似文献
994.
995.
Chin-Tsang Chiang Mei-Cheng Wang 《Annals of the Institute of Statistical Mathematics》2004,56(1):87-100
This paper proposes kernel estimation of the occurrence rate function for recurrent event data with informative censoring.
An informative censoring model is considered with assumptions made on the joint distribution of the recurrent event process
and the censoring time without modeling the censoring distribution. Under the validity of the informative censoring model,
we also show that an estimator based on the assumption of independent censoring becomes inappropriate and is generally asymptotically
biased. To investigate the asymptotic properties of the proposed estimator, the explicit form of its asymptotic mean squared
risk and the asymptotic normality are derived. Meanwhile, the empirical consistent smoothing estimator for the variance function
of the estimator is suggested. The performance of the estimators are also studied through Monte Carlo simulations. An epidemiological
example of intravenous drug user data is used to show the influence of informative censoring in the estimation of the occurrence
rate functions for inpatient cares over time. 相似文献
996.
Hydrothermal synthesis and dielectric properties of chrysanthemum-like ZnO particles 总被引:1,自引:0,他引:1 下载免费PDF全文
By orthogonal design theory, technological parameters of
chrysanthemum-like ZnO particles prepared in a hydrothermal process
are optimized. This paper reports a set of technological
parameters for growing chrysanthemum-like ZnO particles on a large
scale. It investigates the morphologies and crystalline structures
of the as-synthesized three-dimensional ZnO particles with a scanning
electron microscope, x-ray diffractometer and transmission electron
microscope, and the possible growth mechanism on the three-dimensional ZnO
particles. The experimental results indicate that the values of
ε', ε ' and \tan δe gradually
increase in the X band with the improvement of the developmental level
of chrysanthemum-like ZnO particles, implying that the
electromagnetic wave absorbing property depends on the morphologies
of three-dimensional ZnO particles. 相似文献
997.
目前我国东部陆上油田大部分已进入特高含水采油期,绝大多数油井综合含水率已超过85%,部分油井已达到95%。油-气-水三相流型是特高含水混输技术界限确定、水力热力计算方法研究及集输系统科学运行管理的基础。为了研究大庆低渗透油田环状集输水平管道内油-气-水三相流型,研制一套流型试验装置,进行了一系列试验研究,获得了1360组油气水三相流型图及相应的流动参数。对采集到的流型及试验数据进行分析,首次总结出水平环状集输管道中油-气-水三相流的五种流型,分别为分层流、三层扰动流、波浪冲击流、气弹掺混流和完全掺混流。同时给出了每种流型对应的参数范围,并对每种流动形态及典型特征进行了解释。 相似文献
998.
The use of a permeation liquid membrane system for the preconcentration and separation of nickel in natural and sea waters and subsequent determination by atomic absorption spectroscopy is presented. 2-Hydroxybenzaldehyde N-ethylthiosemi-carbazone (2-HBET) in toluene is used as the active component of the liquid membrane. A study strategy based on a simplex design has been followed. Several chemical and physical parameters were optimized. Maximum permeation coefficient was obtained at a feed solution pH of 9.4, 0.3 mol l−1 of HNO3 in the stripping solution and 1.66 mmol l−1 of 2-HBTE in toluene as carrier. The precision of the method was 4.7% at 95% significance level and a detection limit of 0.012 μg l−1 of nickel was achieved. The preconcentration procedure showed a linear response within the studied concentration range from 3 to 500 μg l−1 of Ni in the feed solution. The method was validated with different spiked synthetic seawater and certified reference water samples: TMDA-62 and LGC 6016, without matrix interferences and showing good concordance with the certified values, being the relative errors −5.9% and −2.2%, respectively. Under optimal conditions, the average preconcentration yield for real seawater samples was 98 ± 5%, with a nickel preconcentration factor of 20.83 and metal concentrations ranging between 2.8 and 5.4 μg l−1. 相似文献
999.
稀土萃取分离过程自动控制研究现状及发展趋势 总被引:9,自引:2,他引:9
在简要描述稀土萃取分离生产过程的基础上,综述了目前国内外稀土萃取分离过程中稀土元素成分在线检测的方法、装置及其应用现状;稀土串级萃取分离生产过程的计算机流程模拟以及稀土萃取生产过程的自动控制方法、技术及其应用现状.指出了稀土元素组分含量的软测量方法,以综合生产指标为目标的稀土萃取分离生产过程优化控制方法以及由生产过程管理系统和过程控制系统两层结构组成的稀土萃取分离生产过程综合自动化系统已成为稀土萃取分离生产过程自动化未来发展的方向. 相似文献
1000.
通过熔炼/研磨/热压方法制备了n型和p型赝三元Bi2Te3基的热压合 金样品,测量了由不同工艺参数(热压温度、热压压力)制备的样品Seebeck系数和电导率.分析了热压参数对热电性能产生的影响.特别是发现了增加热压压力和热压温度会使n型和p型热压样品的Seebeck系数和电导率都有所提高,这与单晶和取向晶体材料的Seebeck系数和电导率变化趋势相反的规律显然不同,其结果对热压样品的电学性能提高有积极的影响.
关键词:
热电材料
热压
Seebeck系数
工艺参数 相似文献