A Simple Route of Morphology Control and Structural and Optical Properties of ZnO Grown by Metal-Organic Chemical Vapour Deposition

Employing the metal-organic chemical vapour deposition （MOCVD） technique, we prepare ZnO samples with different morphologies from the film to nanorods through conveniently changing the bubbled diethylzinc flux （BDF） and the carrier gas flux of oxygen （OCGF）. The scanning electron microscope images indicate that small BDF and OCGF induce two-dimensional growth while the large ones avail quasi-one-dimensional growth. X-ray diffraction （XRD） and Raman scattering analyses show that all of the morphology-dependent ZnO samples are of high crystal quality with a c-axis orientation. From the precise shifts of the 20 locations of ZnQ （002） face in the XRD patterns and the E2 （high） locations in the Raman spectra, we deduce that the compressive stress forms in the ZnO samples and is strengthened with the increasing BDF and OCGF. Photoluminescence spectroscopy results show all the samples have a sharp ultraviolet luminescent band without any defects-related emission. Upon the experiments a possible growth mechanism is proposed.     

Magnetic,transport and microstructural properties of polycrystalline samples with nominal composition of La0.7Ca0.3Mn1−xVxO3 (0⩽x⩽0.2)

Polycrystalline samples with nominal composition of La_0.7Ca_0.3Mn_1−xV_xO₃ (0?x?0.2) sintered in air were investigated by ac susceptibility, dc magnetization, magnetoresistance (MR), X-ray diffraction (XRD), scanning electron microscopy (SEM), and differential thermal analysis (DTA) measurements. It is found that V could not substitute for Mn to form La_0.7Ca_0.3Mn_1−xV_xO₃ phase when the samples are sintered in air. The obtained samples contain several phases such as (La, Ca)Mn_1−δO₃, LaCa₃V₃O₁₂, Mn₃O₄ phases, etc. and constitute multi-phase composites. The Curie temperature T_C and spontaneous magnetization of the composites decrease, and the resistance of the composites increases as the V content increases. The addition of V may effectively improve the low-field MR response at low temperatures due to the variation in the microstructure of the composites.     

Dynamics of two interacting dipoles

We study the deterministic spin dynamic of two interacting magnetic moments with anisotropy and dipolar interaction under the presence of an applied magnetic field, by using the Landau–Lifshitz equation with and without a damping term. Due to different kinds of interactions, different time scales appear: a long time scale associated with the dipolar interaction and a short time scale associated with the Zeeman interaction. We found that the total magnetization is not conserved; furthermore, for the non-dissipative case it is a fluctuating function of time, with a strong dependence on the strength of the dipolar term. In the dissipative case there is a transient time before the total magnetization reaches its constant value. We examine this critical time as a function of the distance between the magnetic moments and the phenomenological damping coefficient, and found that it strongly depends on these control parameters.     

Structure and magnetic properties of SmCoxTi0.4-1:7 ribbons

SmCo_xTi_0.4 (x=6.6, 7.1, 7.6, 8.1) ribbons have been prepared by melt spinning at a wheel speed of 42 m/s, followed by annealing at 750 °C for 2 h. Both as-spun and as-annealed ribbons possess the disordered TbCu7-type (1:7) phase even when the Sm/(Co,Ti) atomic ratio deviates from 1/7. The c/a ratio increases with increasing Co concentration x, but the unit cell volume decreases. The Curie temperatures show above 700 °C, increasing from 707 °C for x=6.6 to 782 °C for x=8.1. The saturation magnetizations increase almost linearly with increasing Co content. The observed magnetic hardening is believed to arise from the high magnetocrystalline anisotropy of the 1:7 phase and the fine nanograin structure. The intrinsic coercivity of 9797 Oe has been obtained in the melt-spun SmCo_7.1Ti_0.4 ribbons.     

Ordered mesoporous silica materials (SBA-15) with good heat-resistant magnetism

A series of highly ordered mesoporous materials (CF-SBA-15) with heat-resistant magnetism have been successfully prepared from impregnation of cobalt salt, iron salt, and citric acid with as-synthesized SBA-15. XRD and N₂ isotherms indicate that these materials have highly ordered hexagonal mesoporous symmetry and open pore systems. The measurement of magnetic property shows that these materials are ferromagnetic even if calcined at 550 °C for 10 h in air, indicating their good heat-resistant magnetism. These results would be very important for recycle and regeneration of adsorbents and catalysts in practical applications. Moreover, this method may be useful for other mesoporous materials with thermally stable magnetism from a combination of other mesoporous materials such as MCM-41 with magnetic nanoparticles of MnFe₂O₄ and NiFe₂O₄.     

Ballistic spin interferometer based on the Rashba and Dresselhaus spin-orbit interactions

By using the Al'tshuler-Aronov-Spivak (AAS) model, we give the amplitude changing with Rashba spin-orbit interaction (SOI) and Dresselhaus SOI strength. In the first idea 1D square loop (SL), Rashba SOI acts on two sides while Dresselhaus SOI acts on the other two sides. In the second SL, we consume Rashba SOI and Dresselhaus SOI act on four sides simultaneously. This model can be replaced by another one that Rashba SOI and Dresselhaus SOI act on every side independently, and each side is twice long. We theoretically illustrate the influence of the Dresselhaus SOI on node position and number. To explain the “half oscillation” phenomenon found in experiment, we apply Dresselhaus SOI to the ideal 1D SL. The conclusion is that the Dresselhaus SOI has a strong effect on the emergence of “half oscillation”.     

Structure and magnetic order in La0.7Ca0.3Mn0.5Co0.5O3 and La0.8Sr0.2Mn0.5Co0.5O3 perovskites

In this paper we report the study of the perovskites La_0.7Ca_0.3Mn_0.5Co_0.5O₃ and La_0.8Sr_0.2Mn_0.5Co_0.5O₃ by neutron powder diffraction at various temperatures and magnetization measurements in zero applied field and at low cooling regimes. The replacement of half Mn by Co in La_0.7Ca_0.3MnO₃ and La_0.8Sr_0.2MnO₃ destroys their long-range ferromagnetism exhibiting a cluster glass ferromagnetic order similar to the one observed in many cobaltites.     

Excited state absorption,energy levels,and thermal conductivity of Er<Superscript>3+</Superscript>:YAB

Polarized excited state absorption spectra of Er, Yb:YAB are reported. The Stark levels of the ⁴I_15/2, ⁴I_13/2, and ⁴I_11/2 multiplets of Er³⁺ have been derived from the measured low-temperature absorption and fluorescence spectra. The stimulated emission spectra have been calculated using the reciprocity method, and the radiative lifetime of the erbium ⁴I_13/2 level has been determined indicating high nonradiative decay rates. The thermal conductivity of Er-Yb-codoped YAB crystals has been measured.