Novel massive ground states of spin chains in a magnetic field

Novel massive quantum states appearing in spin chains under a strong magnetic field are discussed. These states lead to plateaus in magnetization curves. When the systems are axially symmetric and the field is applied parallel to the symmetry-axis, the phenomena are analogous to metal-insulator transitions. Striking features of the plateau phenomena - exactness and rationality - are explained as consequences the commensurability condition to the underlying lattice. The effects of the planar anisotropy are also discussed in detail. Received: 16 February 1998 / Revised: 20 April 1998 / Accepted: 30 April 1998     

Influence of partial rare-earth substitution for Sm in the giant intrinsic magnetic hardness compound SmCo2Ni3

The phenomenon of giant intrinsic magnetic hardness is investigated in compounds R_1−x Sm _x Co₂Ni₃ with R=Y, Pr, Gd, Tb, Er. Partial Er substitution for Sm actually increases magnetic hardness while all other substitutions decrease magnetic hardness. The strength of coercivity is thus dependent on both the sign and magnitude of the crystal field interaction. The temperature dependence of coercivity is complex in the case of Pr substitution as a result of competing effects from thermal activation and a decrease in anisotropy at low temperatures. This study has been supported by a grant from the National Science Foundation.     

Identification of a rotator phase of octamethyl ferrocene and correlations between its structural and dynamical properties

The low- and high-temperature phases of octamethyl ferrocene were studied in detail, using high-resolution X-ray powder diffraction, differential scanning calorimetry and nuclear resonant scattering, in particular the novel technique of synchrotron radiation perturbed angular correlations (SRPAC). Much as in the case of an analogous but more unsymmetrical molecule, octamethyl ethinyl ferrocene, the high-temperature phase possesses the space group with lattice parameters , , which in the rhombohedral setting correspond to , α=104.79^°. An increase of the volume per formula unit of about 12% across the phase transition is observed.The rotation of the electric field gradient, which can be identified with the rotation of the entire molecule within the lattice, follows Arrhenius behaviour with a high activation energy of . Whereas precursor effects and a change in activation energy were observed for octamethyl ethinyl ferrocene, no such effects are observed for octamethyl ferrocene. We relate this difference to the absence of the ethinyl substituent in octamethyl ferrocene.     

Shot Noise in Aharonov-Casher Rings

We investigate the shot noise of electron transport through an Aharonov-Casher ring subject to the Rashba spin-orbit coupling （SOC）. Analytic expressions for the coefficients of reflection and transmission are derived by using the Griffith boundary conditions. For this kind of SOC, the ballistic transport of electrons can be analyzed as two independent spin channels, and both of them have the same transmission and reflection coefficients. The dependences of shot noise and Landauer-Biittiker conductance on controllable factors, including the strength of Rashba SOC, the asymmetrical angle of lead-connection positions, the radius of the rings, and the wave vector （or energy） of the incident Fermi electrons, are explicitly described by some new combined parameters. The ways that the shot noise and conductance vary with Rashba SOC and with asymmetrical angle are demonstrated by numerical simulations, respectively. It is revealed that the shot noise reaches its maximum for the particular situation of half transmission and half reflection and zero shot noise occurs at conductance maxima.     

Cluster Observation of Eelectrostatic Solitary Waves around Magnetic Null Point in Thin Current Sheet

Electrostatic solitary waves （ESWs） are observed in the vicinity of the magnetic null of the widely studied magnetic reconnection taking place at the near-earth tail when current sheet becomes dramatic thinning during substorm time on 1 October 2001. We use the Imada method for the 2-D reconnection model and study the characteristics of ESWs near the X-line region and the magnetic null points. The result shows that the amplitude of the observed ESWs in the vicinity of X-line region ranges from 0.1mV/m to 5mV/m, and the amplitude is larger near the magnetic null points. The generation mechanism and the role of ESWs associated with magnetic reconnection are also discussed.     

Magnetic properties of xNi0.53Cu0.12Zn0.35Fe1.88O4+(1−x)BaTiO3 nanocomposites

The nanocrystalline Ni_0.53Cu_0.12Zn_0.35Fe_1.88O₄ and BaTiO₃ powders were prepared using Microwave-Hydrothermal (M-H) method at 160 °C/45 min. The as synthesized powders were characterized using the X-ray diffraction (XRD) and Transmission Electron Microscope (TEM). The size of the powders that were synthesized using M-H system was found to be ∼30 and ∼50 nm for ferrite phase and ferroelectric phases, respectively. The powders were densified using microwave sintering method at 900 °C/30 min. The ferrite and ferroelectric phases were observed from XRD and morphology of the composites was observed with the Scanning Electron Microscope (SEM).The magnetic hysteresis loops were recorded using the Vibrating Sample Magnetometer (VSM).The frequency dependence of real (μ′) and imaginary (μ″) parts of permeability was measured in the range of 1 MHz-1.8 GHz. The permeability decreases with an increase of BaTiO₃ content at 1 MHz. The transition temperature (T_C) of ferrite was found to be 245 °C. The T_C of composite materials decreases with an increase in BaTiO₃ content.     

Argon and krypton ion-induced changes in permalloy thin films

The effects of 75-keV Ar and 100-keV Kr ion irradiations of 72-nm thin DC-sputtered permalloy (Ni₈₁Fe₁₉) films on Si(100) wafers were studied at fluences of up to 10¹⁶ ions/cm². The changes of the structural and magnetic properties were measured via X-ray diffraction, Rutherford backscattering spectroscopy, and magneto-optical Kerr effect. The irradiations increase the lattice constant and improve the crystallinity of the samples. They induce also strong changes of the magnetic polarisation and the coercive field for increasing ion fluence. The hysteresis loops suggest that, with increasing ion fluence, the reversal of the magnetisation changes gradually from rotation-dominated in the as-deposited films to domain-wall-motion dominated at the highest ion fluences. The results are compared with those obtained for Ni-, Cr-and Xe-ion irradiated permalloy films.     

Spin–orbit coupling in low‐dimensional gold

We present experimental and theoretical evidence of the role played by the spin–orbit coupling in the electronic structure of a pseudomorphic Au monolayer on Nb(001) substrate. The bands found with the help of the angle‐resolved ultraviolet photoelectron spectroscopy (ARUPS) are compared with those obtained from ab initio self‐consistent calculations by the VASP and WIEN2k codes. The slab calculations are performed including geometric relaxation and using both the generalized‐gradient (GGA) and local‐density (LDA) approximations for the exchange–correlation energy. The dispersions and energy positions of the calculated bands agree with the experimentally determined band structure only if the LDA is used and the spin–orbit coupling is included. Therefore, both the structure relaxation and spin–orbit coupling are essential in understanding the electronic structure of the Au/Nb(001) system.

     

Thermal diffusion and bending kinetics in nematic elastomer cantilever

Vertically aligned monodomain nematic liquid-crystal elastomers contract when heated. If a temperature gradient is applied across the width of such a cantilever, inhomogeneous strain distribution leads to bending motion. We modelled the kinetics of thermally induced bending in the limit of a long thin strip and the predicted time variation of curvature agreed quantitatively with experimental data from samples with a range of critical indices and nematic-isotropic transition temperatures. We also deduced a value for the thermal diffusion coefficient of the elastomer.     

KDP/PEDOT:PSS mixture as a new alternative in the fabrication of pressure sensing devices

In this work we studied the mixture of poly(3,4-ethylenedioxythiophene):poly(styrenesulfonate) (PEDOT:PSS), a commercial polymer, with monobasic potassium phosphate (KDP), a piezoelectric salt, as a possible novel material in the fabrication of a low cost, easy-to-make, flexible pressure sensing device. The mixture between KDP and PEDOT:PSS was painted in a flexible polyester substrate and dried. Afterwards, I × V curves were carried out. The samples containing KDP presented higher values of current in smaller voltages than the PEDOT:PSS without KDP. This can mean a change in the chain arrays. Other results showed that the material responds to directly applied pressure to the sample that can be useful to sensors fabrication.