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81.
Xu Wen-Yang Guo Chang-Jie Do Tao 《Journal of inclusion phenomena and macrocyclic chemistry》1986,4(4):325-331
A member of the novel family of crystalline microporous aluminophosphates, AlPO4-12, was synthesized by hydrothermal crystallization using different aluminum-containing compounds. Three new crystalline phases were obtained by varying the composition of the reaction mixture. The effect of the synthesis conditions on the hudrothermal process and the kinetics of crystallization are discussed. The apparent activation energies obtained for AlPO4-12 are 20.9 and 14.6 kcal/mol for nucleation and crystallization, respectively. The adsorption isotherms of one AlPO4-12 product were measured. 相似文献
82.
F. Román S. Montserrat J. M. Hutchinson 《Journal of Thermal Analysis and Calorimetry》2007,87(1):113-118
The procedure for
the fabrication of epoxy-based polymer layered silicate nanocomposites is
important in respect of the nanostructure that is developed. To further our
understanding of this, the influence of an organically modified clay (montmorillonite,
MMT) on the curing kinetics of an epoxy resin has been studied by differential
scanning calorimetry. Clay loadings of 10 and 20 mass% are used, and isothermal
as well as dynamic cures have been investigated. For both cure schedules the
effect of the MMT is to advance the reaction. Kinetic analysis yields values
for the activation energy, but shows that the reaction cannot be described
simply by the usual autocatalytic equation. The glass transition of the cured
nanocomposites is lower than that for the cured neat resin, a result that
is attributed to homopolymerisation taking place in addition to the epoxy–amine
reaction. 相似文献
83.
84.
Zakharova L. Ya. Mirgorodskaya A. B. Zhil"tsova E. P. Kudryavtseva L. A. Konovalov A. I. 《Russian Chemical Bulletin》2004,53(7):1385-1401
The factors determining the catalytic effect of supramolecular systems on the nucleophilic substitution reactions are analyzed. The role of the structural and phase transitions of nanoaggregates in the catalytic mechanism are determined. The substrate specificity is shown for different structures of the supramolecular composition. 相似文献
85.
L.Late E.A.BlekkanDepartment of Chemical Engineering Norwegian University of Science Technology 《天然气化学杂志》2002,(Z1)
The reaction kinetics of the oxidative dehydrogenation of propane was studied at 475-550℃ over a VMgO catalyst. Vanadium-magnesium-oxides are among the most selective and active catalysts for the dehydrogenation of propane to propylene. Selectivity to propylene up to about 60% was obtained at 10% conversion, but the selectivity decreased with increasing conversion. No oxygenates were detected, the only by-products were CO and CO2. The reaction rate of propane was found to be first order in propane and close to zero order in oxygen, which is in agreement with a Mars van Krevelen mechanism with the activation of the hydrocarbon as the rate determining step. The activation energy of the conversion of propane was found to be 122±6 kJ/mol. 相似文献
86.
J?rg Libuda 《Chemphyschem》2004,5(5):625-631
Reaction kinetics on nanometer-scale particles are different from those on extended surfaces of bulk materials. This fact has been utilized for a long time to empirically maximize the performance of heterogeneous catalysts, but the understanding of the underlying effects is poor at the microscopic level. Modern molecular beam-based methods, however, allow us to derive very detailed kinetic information on catalytically active surfaces. In combination with structurally highly controlled model catalysts, microscopic insights into the activity and selectivity of specific reaction centers on catalyst nanoparticles can be obtained. This combined approach is illustrated through simple model reactions. 相似文献
87.
甲醇的裂解产物为H_2与CO,故甲醇被视为一种方便、安全的贮氢材料,可作为汽油的代用燃料;其裂解气作为保护气氛可广泛应用于热处理工业。甲醇裂解有两种方法,高温热裂解(约930℃)与低温催化裂解(约300℃)由于低温催化裂解有诸多优点,在工业上的应用正在发展。 相似文献
88.
The effects of temperature and duration of melting on the rate of isothermal crystallization of isotactic polypropylene were investigated by differential scanning calorimetry (DSC). Crystallization rates were found to decrease with increasing melt temperature and melting time. The results were discussed in the framework of the theoretical model of transient isothermal crystallization developed by the present authors [1]. The results suggest gradual destruction of predetermined nuclei with activation energyE
a=89±7 kJ/mole as a main mechanism of the observed effects.This work and Part I of this research [1] have been supported in part by Research Grant Number PB 1291/52/93/04 from State Committee for Scientific Research (KBN), Poland, and by 40% MURST founds, Italy. 相似文献
89.
J. A. Poulis C. H. Massen E. Robens G. Reichenauer 《Journal of Thermal Analysis and Calorimetry》2004,76(2):583-592
On the basis of a molecular model for adsorption kinetics Jäntti introduced a method to calculate equilibriums shortly after a change of the pressure of the sorptive gas. In the present paper we show that this method is useful in many more situations than those intended originally. 相似文献
90.
H. Stutz J. Mertes K. Neubecker 《Journal of polymer science. Part A, Polymer chemistry》1993,31(7):1879-1886
A theoretical approach to thermoset cure kinetics based on Arrhenius kinetics and mobility was developed by considering the activation of the reacting group and chain mobility as elementary steps for reaction. This extended kinetic equation was successfully applied to the curing of an epoxy by an amine, the trimerization of a cyanate, and to the polymerization of methyl methacrylate. Full agreement between theory and experimental data was obtained in all cases. The activation energies for chain mobility were exceptionally low (0.3–1 kJ/mol for bisphenol-A-based epoxy and cyanate) which indicates that the structural units must undergo only small-angle rotational oscillations to allow a reaction. A theoretical time–temperature–transformation (TTT) diagram is also presented. © 1993 John Wiley & Sons, Inc. 相似文献