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141.
142.
An effective residual interaction between particles and holes for shell model calculations around 208Pb, derived from the interaction between free nucleons, is compared with the measured properties of proton-hole neutron states
in 208Tl and the interaction between proton holes is adjusted to newly measured level energies in 206Hg. These interaction elements are particularly relevant for neutron-rich nuclei. The adjustment of two mixing elements reproduces
the known γ-decay data in 208Tl.
Received: 2 April 2002 / Accepted: 2 May 2002 相似文献
143.
144.
Several α-ketoalcohols of synthetic value were resolved using lipase as a catalyst. Lipoprotein lipase (LPL) provided the best rate of hydrolysis and kinetic differentiation. One of these optically pure α-ketoalcohol was converted to (5)-ibuprofen in good optical purity. The stereospecific inversion of (R)-alcohol to (S)-alcohol is described. 相似文献
145.
A self-avoiding polygon (SAP) on a graph is an elementary cycle. Counting SAPs on the hypercubic lattice ℤ
d
withd≥2, is a well-known unsolved problem, which is studied both for its combinatorial and probabilistic interest and its connections
with statistical mechanics. Of course, polygons on ℤ
d
are defined up to a translation, and the relevant statistic is their perimeter.
A SAP on ℤ
d
is said to beconvex if its perimeter is “minimal”, that is, is exactly twice the sum of the side lengths of the smallest hyper-rectangle containing
it. In 1984, Delest and Viennot enumerated convex SAPs on the square lattice [6], but no result was available in a higher
dimension.
We present an elementar approach to enumerate convex SAPs in any dimension. We first obtain a new proof of Delest and Viennot's
result, which explains combinatorially the form of the generating function. We then compute the generating function for convex
SAPs on the cubic lattice. In a dimension larger than 3, the details of the calculations become very cumbersome. However,
our method suggests that the generating function for convex SAPs on ℤ
d
is always a quotient ofdifferentiably finite power series. 相似文献
146.
147.
148.
Sans résumé
相似文献
相似文献
149.
Summary We prove convergence and error estimates in Sobolev spaces for the collocation method with tensor product splines for strongly elliptic pseudodifferential equations on the torus. Examples of applications include elliptic partial differential equations with periodic boundary conditions but also the classical boundary integral operators of potential theory on torus-shaped domains in three or more dimensions. For odd-degree splines, we prove convergence of nodal collocation for any strongly elliptic operator. For even-degree splines and midpoint collocation, we find an additional condition for the convergence which is satisfied for the classical boundary integral operators. Our analysis is a generalization to higher dimensions of the corresponding analysis of Arnold and Wendland [4]. 相似文献
150.
Semi-empirical molecular orbital calculations were carried out for the compounds (C2H5)3As, (C2H5)3Ga and RAsH2 (R = C2H5, i-C3H7, i-C4H9, and t-C4H9) by using the CNDO/2-U program, and their capability of β-elimination reaction is compared on the basis of the torsion energy to the transition state, electrostatic interactions and orbital overlapping between the central atom and the β-hydrogen, and bond order of the metal-carbon, and carbon-hydrogen bond. In the comparison of (C2H5)3As with (C2H5)3Ga, we found that the β-elimination of (C2H5)3As could hardly be expected to take place in the thermal decomposition. The capability of β-elimination would be smaller in C2H5AsH2 than that in (C2H5)3As. Moreover when the ethyl group is replaced by a t-butyl group in RAsH2, the β-elimination reaction appears to become more difficult and a large possibility for a radical process is suggested. 相似文献