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41.
Over 8000 line positions and intensities of phosphine (PH3) at 3 μm have been measured at 0.0115 cm−1 resolution with the McMath-Pierce Fourier Transform spectrometer at Kitt Peak. The observed line intensities ranged from 4.13 × 10−6 to 4.69 × 10−2 cm−2 atm−1 at 296 K, for line positions between 2724.477 and 3601.652 cm−1. This region spans eight interacting vibrational states: 3ν2 (2940.8 cm−1), 2ν2 + ν4 (3085.6 cm−1), ν2 + 2ν4 (3214.9 cm−1), ν1 + ν2 (3307.6 cm−1), ν2 + ν3 (3310.5 cm−1), 3ν4 (∼3345 cm−1), ν1 + ν4 (3426.9 cm−1), and ν3 + ν4 (3432.9 cm−1). Assignments have been determined for all the bands except 3ν4 (a weak band in a highly congested area) for a total of 4232 transitions. The total integrated intensity for this region is 5.70 cm−2 atm−1 near 296 K, and assigned lines account for 79% of the observed absorption. The two strongest bands in the region are ν1 + ν4 and ν3 + ν4 with band strengths at 296 K of 1.61 and 2.01 cm−2 atm−1, respectively. An empirical database of PH3 line parameters (positions, intensities, and assignments) is now available. Lower state energies (corresponding to assignments from this study) and line widths from the literature are included; default values are used for unassigned features. 相似文献
42.
宋光乐 《光谱学与光谱分析》2003,23(4):820-822
从Fourier级数出发 ,到任意闭区间上可积函数的Fourier分析 ,给出了数字信号Fourier分析的理论基础。以字符“b”为例 ,建立了严格的数学模型 ,严密推导了Fourier系数表达式。阐明了Fourier级数的“项”和“n阶Fourier级数”(前n项和 )的概念。详尽地分析了信道通频带B与Fourier阶数n(展开式“保留”项 )的关系。借助计算机计算了n≤ 10 0时各Fourier级数项和前n项和 ,并用Plot将计算结果绘成曲线 ,获得n≤10 0时各级Fourier展开曲线。与数字信号对照 ,Fourier级数的取项与波形的关系显而易见 ,特别是n取值较小时 ,Fourier级数取项少 ,波形失真严重 ;所以在B一定时传输速率不能过高 ,否则 ,由于波形失真而导致信号出错。 相似文献
43.
44.
O.N. Ulenikov G.A. Onopenko T.V. Krapivina O.V. Gromova 《Journal of Molecular Spectroscopy》2005,230(1):78-86
A high-resolution Fourier transform spectrum of the D2MSe species (M = 82, 80, 78, 77, and 76) in the region 2300-2500 cm−1 was recorded for the first time and assigned. On the basis of these experimental data, rotation-vibration energies of the (1 1 0) and (0 1 1) vibrational states were fitted, and band centers, and rotational, centrifugal distortion, and resonance interaction parameters were determined for the main D280Se species. The obtained set of 32 fitted parameters reproduces the 647 rotation-vibration energies with a rms deviation of 0.00024 cm−1. The ν1 + ν2 and ν2 + ν3 bands of the other four isotopic species are analyzed as well. 相似文献
45.
O. Dubos W. Petry J. Neuhaus B. Hennion 《The European Physical Journal B - Condensed Matter and Complex Systems》1998,3(4):447-454
We present inelastic neutron scattering measurements of the low energy and strongly damped phonons in the high temperature
bcc phase of zirconium. These phonons were investigated at different scattering vectors but equivalent phonon wave vectors in different Brillouin zones or along different but equivalent paths in the same Brillouin zone. Neither the observed differences
in intensity nor in line shapes can be explained by the coherent one-phonon scattering law . This leads to an apparent violation of the fundamental symmetry of lattice dynamics. Taking into account the strong anharmonicity
of these phonons, interferences between one- and multi-phonon scattering are held responsible for these effects. Measurements
in different scattering planes reveal that due to the symmetry of the bcc lattice, these effects can only be observed in certain
directions.
Received: 24 December 1997 / Received in final form: 9 March 1998 / Accepted: 19 March 1998 相似文献
46.
47.
The suitability of ormosils as photonic materials was investigated. Vinyl and phenyl silicates were synthesised below 100°C. A detailed assignment of mid-infrared vibrational absorption bands is given. This allowed assignment of overtone and combination bands in the near-infrared region and an assessment of residual water contamination, which is low and can be expelled by evacuation. These ormosils have low intrinsic and extrinsic optical absorption in the visible spectral region and at useful wavelengths in the near-infrared. 相似文献
48.
Critical comparison of emission spectroscopic determination of dissociation in hydrogen RF discharges 总被引:1,自引:0,他引:1
The degree of dissociation of molecular hydrogen in a RF parallel plate plasma reactor is analyzed by three dif erent emission spectroscopic methods. These schemes are based on the comparison of line intensities of atomic and molecular hydrogen and of argon which is admixed as a tracer gas (actinometry). The different schemes yield similar results in the parameter ranges where they are applicable. The basic assumptions, the available cross sections, and the conditions and limitations of applicability of the different schemes are compared and discussed. 相似文献
49.
Johnson FM 《Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy》2006,65(5):1154-1179
As a result of the search for the identity of the chromophores responsible for producing the diffuse interstellar bands, a comprehensive exposition of experimental data is presented, which implicates the following molecules: (1) The extremely stable organic molecules, magnesium tetrabenzoporphyrin (MgTBP) and H(2)TBP. (2) A paraffin matrix (referred to as "grains") containing TBPs. (3) A low concentration of pyridine (also within the grains), whose transmission window at 2175 A, accounts for the ubiquitous UV bump. The blue emission spectra associated with the central star, HD44179, of the Red Rectangle displays the fluorescence excitation spectra of bare MgTBP. This unique spectrum matches the low temperature lab data of MgTBP in the vapor phase. An effective grain temperature of 2.728 K (+/-0.008) was deduced, based on MgTBP's lowest measured vibrational state of 341 GHz. 相似文献
50.
Antunes A de Rossi W Zezell DM 《Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy》2006,64(5):1142-XXXIV
Laser irradiation on hard tissue has produced a resistant surface that is likely to prevent caries. In this study, human enamel and dentine were exposed to nanosecond pulsed Nd:YAG laser with energy densities of 20-40 J/cm(2) and pulse width of 6 ns inducing chemical changes in these tissues. Infrared analysis of human dental enamel and dentine was performed using the KBr method (2mg sample/300 mg KBr). A correlation between non-lased and lased spectra was performed that gives an indication of the changes in organic and inorganic compounds after laser-tissue interaction. Spectra of teeth simultaneously show the inorganic and organic parts of the tissue. The principal bands: amide bands A, I, II, and III from the collagen-matrix, phosphate from the mineral content, and carbonate bands were identified. The normalized area of peak versus peak position was determined. Changes of the bands attributed to the collagen matrix were verified after Nd:YAG irradiation. The present results suggest a chemical modification of organic and mineral compounds by laser. The spectral results indicated an alteration in the absorption bands relative to, essentially, organic compounds. 相似文献