离焦激光直写的线宽稳定方法

为了提高激光直写加工衍射光学元件时的线条质量,提出一种离焦激光直写的线宽稳定方法.该方法通过同时调节激光功率和离焦量,使光刻胶的曝光阈值处于线宽对曝光量的变化率较小位置,从而可以弱化线宽对实际曝光量或光刻胶阈值等变化的敏感度,提高利用离焦方法进行衍射光学元件制作时的线宽稳定性.推导了稳定线宽后的光功率控制模型和线宽模型,模型中的变量仅为离焦量,降低了光功率控制的复杂性.利用632.8 nm的He-Ne激光和NA-0.1的物镜在CCD上对采用该方法后的离焦线宽模型进行验证,实验结果与理论模型吻合较好.该方法对于线宽稳定度较高的衍射光学元件制作具有重要价值.     

Minority Carrier Lifetime in As-Grown Germanium Doped Czochralski Silicon

The minority carrier lifetime of as-grown germanium-doped Czochralski （GCZ） silicon wafers doped with germanium concentrations [Ge]=10^16-10^18 cm^-3 is investigated in comparison with conventional CZ silicon samples. It is found that the lifetime distribution along the ingot changes with the variation of[Ge]. There is a critical value of [Ge] = 10^16 cm^-3 beyond which Ge can obviously influence the lifetime of as-grown ingots. This phenomenon is considered to be associated with the competition or combination between the oxygen related thermal donors （TDs） and electrically active Ge-related complexes. The related formation mechanisms and distributions are also discussed.     

Tm-Doped Fibre Laser Pumped Cr^2＋：ZnSe Poly-Crystal Laser

Demonstrations of cw lasing in Cr^2＋：ZnSe poly-crystal are reported. The laser consists of a 1.7-mm-thick Cr^2＋ ：ZnSe poly-crystal disc pumped by a Tin-silica double-clad fibre laser at 2050nm. Using a concave high- reflection mirror with a radius of curvature of 500mm as the rear mirror, the laser delivers up to 1030mW of radiation around 2.367μm.     

Space-Selective Precipitation of Ba2TiSi2O8 Crystals in Sm3^＋-Doped BaO-TiO2-SiO2 Glass by Femtosecond Laser Irradiation

The ferroelectric crystal Ba2TiSi2O8 with high second-order optical nonlinearity is precipitated in Sm^3＋-doped BaO-TiO2-SiO2 glass by a focused 800hm, 250 kHz and 150fs femtosecond laser irradiation. No apparent blue and red emissions are observed at the beginning, while strong blue emission due to second harmonic generation and red emission due to the f-f transitions of Sm^3＋ are observed near the focal point of the laser beam after irradiation for 25s. Micro-Raman spectra confirm that Ba2 TiSi2O8 crystalline dots and lines are formed after laser irradiation. The mechanism of the phenomenon is discussed.     

Amorphization Induced High Magneto-Caloric Effect of Gd55Al20Ni25 Ternary Alloy

We report the amorphization induced high magneto-caloric effect （MCE） of recently developed Gd55Al15Ni30 bulk metallic glass （BMG）. The magnetic properties of the Gd55Al15Ni30 BMG are investigated in comparison with that of its crystalline counterpart. It is found that amorphization can increase the saturation magnetization and decrease the hysteresis of Gd55Al15Ni30 alloys, which indicate the possible enhancement of MCE. The magnetic entropy changes and the refrigerant capacity of the BMG as well as the crystalline samples is calculated directly from isothermal magnetic measurements. The results show the amorphization induced high MCE of the alloy and the excellent refrigerant efficiency of Gd55Al15Ni30 bulk metallic glass.     

Blue-to-Orange Tunable Luminescence from Europium Doped Yttrium--Silicon--Oxide--Nitride Phosphors

Europium-doped yttrium-silicon-oxide-nitride phosphors are synthesized by carbothermal reduction and nitridation method. The crystal structure of the phosphors changed gradually from oxide Y2Si2O7 to nitride YSi3N5 state with increasing dosage of Si3N4 and carbon powder. The Y2Si2O7：Eu phosphor shows a blue emission at 465 nm with 300 nm excitation and a characteristic red emission of Eu^3＋ at 612 nm with 230 nm excitation. The YSi3N5：EU phosphor shows a broad emission band centred at 595nm with some sharp peaks of Eu^3＋ with 325nm excitation. The absorption of the studied phosphors increases from 450 to 700hm with an increment in nitrogen content. Blue-to-orange tunable luminescence is observed with 390 nm excitation.     

基于量子尺寸效应的纳米内包层光纤放大性研究

本文利用改进的化学汽相沉积法制作出纳米级InP薄膜内包层光纤;根据氢原子本征能量模型计算了InP微粒产生量子尺寸效应的相对粒径aB=8.313nm,且由量子尺寸效应计算了不同尺寸粒子的带隙能量以及相对应的光吸收波长;结果表明：当内包层薄膜材料厚度达5－50nm量级时,其能级将发生红移,产生放大性能.     

（EuxRE1-x）（β-NTA）3Phen配合物的合成、表征及荧光性能研究

在无水乙醇溶液中合成了以铕及铕掺人不同比例的Y2 或Tb3 为中心,以β萘基甲酰三氟丙酮(β-NTA)和邻菲咯啉(phen)为配体的配合物;对其进行了元素分析、摩尔电导、核磁共振氢谱、差热-热重、红外光谱分析及荧光性能的研究.其化学组成式为(EuxY1-x)(β-NTA)3 PJlen及(EuxTb1-x)(p-NTA)3Phen(x=0.1;0.3;0.5;0.7;0.9);摩尔电导测试数据表明,所有配合物均为非电解质;核磁共振氢谱和红外光谱表明,配体β-NTA通过烯醇式氧负离子采用双齿配位的形式与稀土离子配位,Phen的两个氮原子也与稀土离子双齿配位;荧光光谱实验结果表明,所有激发光谱都为一宽带峰,配体能很好的吸收能量,在惰性不发光Y3 的含量工小于0.3,发光Tb3 的含量小于0.5时,可以使Eu3 的特征荧光发射得到一定程度增强,这表明两种不同的离子都可以敏化Eu3 .     

稀土离子增敏的恩诺沙星荧光体系及其分析应用

研究了稀土Y3 离子与恩诺沙星配合物体系的荧光特性,Y3 离子可使体系的荧光强度明显增强,由此建立了灵敏测定恩诺沙星药物的分析方法。用1 cm石英比色池在激发和发射波长分别为274和424 nm处测定其荧光强度;恩诺沙星在1.0×10-9~5.0×10-6mol.L-1浓度范围内与体系的荧光强度呈良好的线性关系,相关系数为0.998 1,检测限为2.3×10-10mol.L-1(S/N=3);同时试验了常见金属离子与配伍药对其测定的干扰,进行了在配伍药中的回收试验,回收率在98.0%~107.0%之间,RSD在0.9%~4.5%之间以及对动物专用的恩诺沙星注射液的含量进行了测定,并与用铽离子荧光探针法测得的结果进行了比较,结果令人满意。此外,对该荧光体系的发光机理也进行了讨论。     

掺杂对二硼化镁超导体上临界磁场的影响

采用二带Ginzburg-Landau(GL)理论模型,考虑到能带有效质量的各向异性,讨论了MgB2超导体的上临界磁场对角度、温度和相干长度的依赖关系.结果表明,替代杂质越多,上临界磁场越强,这与实验结果符合.