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41.
Using the full-potential linearized augmented plane wave (FP-LAPW) method, we have studied the effect of chemistry on the average intercalation voltage (AIV) caused by the Na ions intercalating into transition metal oxides. The effect of transition metal was systematically studied by varying M=Co, Ni and Mn in NaMO2 and fixing the α-NaFeO2 layered structure. The effect of the guest atoms into the host material is discussed in terms of the structural and electronic properties. Comparatively to Li intercalation, a significant electron transfer towards transition metal was found. This observation suggests that the transition metal contribute to the AIV determination and confirms the common assumption that intercalated electron reduces M4+ to M3+. 相似文献
42.
43.
Chunlin Li Yilu Fu Guozhu Bian Tiandou Hu Yaning Xie Jing ZhanDepartment of Chemical Physics University of Science and Technology of China Hefei China Institute of High Energy Physics Chinese Academy of Sciences Beijing China 《天然气化学杂志》2003,12(3)
The Ni/CeO2-ZrO2-Al2O3 catalyst with different Al2O3 and NiO contents were prepared by hydrothermal synthesis method. The catalytic performance for CO2 reforming of CH4 reaction, the interaction among components and the relation between Ni content and catalyst surface basicity were investigated. Results show that the interaction between NiO and Al2O3 is stronger than that between NiO and CeO2-ZrO2.The addition of Al2O3 can prevent the formation of large metallic Ni ensembles, increase the dispersion of Ni, and improve catalytic activity, but excess Al2O3 causes the catalyst to deactivate easily. The interaction between NiO and CeO2 results in more facile reduction of surface CeO2. The existence of a small amount of metallic Ni can increase the number of basic sites. As metallic Ni may preferentially reside on the strong basic sites, increasing Ni content can weaken the catalyst basicity. 相似文献
44.
A hybrid technique using constraint programming and linear programming is applied to the problem of scheduling with earliness and tardiness costs. The linear model maintains a set of relaxed optimal start times which are used to guide the constraint programming search heuristic. In addition, the constraint programming problem model employs the strong constraint propagation techniques responsible for many of the advances in constraint programming for scheduling in the past few years. Empirical results validate our approach and show, in particular, that creating and solving a subproblem containing only the activities with direct impact on the cost function and then using this solution in the main search, significantly increases the number of problems that can be solved to optimality while significantly decreasing the search time. 相似文献
45.
46.
研究了Banach空间中拟-似变分包含解的存在与逼近问题.给出了一种寻求解的新的迭代算法,建立了具混合误差的Ishikawa型迭代序列强收敛到解的充要条件.所得结果推广了一些相关的结果. 相似文献
47.
Kai Kamada Shintaro Udo Shuichi Yamashita Yuko Tsutsumi Yasumichi Matsumoto 《Solid State Ionics》2003,160(3-4):389-394
Quantitative analysis of metal cation doping by solid oxide electrochemical doping (SOED) has been performed under galvanostatic doping conditions. A M–β″-Al2O3 (M=Ag, Na) microelectrode (contact radius: about 10 μm) was used as cation source to attain a homogeneous solid–solid contact between the β″-Al2O3 and doping target. In Ag doping into alkali borate glass, the measured dopant amount closely matched the theoretical value. High Faraday efficiencies of above 90% were obtained. This suggests that the dopant amount can be precisely controlled on a micromole scale by the electric charge during electrolysis. On the other hand, current efficiencies of Na doping into Bi2Sr2CaCu2Oy (BSCCO) ceramics depended on the applied constant current. Efficiencies of above 80% were achieved at a constant current of 10 μA (1.6 A cm−2). The relatively low efficiencies were explained by the saturation of BSCCO grain boundaries with Na. By contrast, excess Na was detected on the anodic surface of ceramics at a constant current of 100 μA (16 A cm−2). In the present study, we demonstrate that SOED enables micromole-scale control over dopant amount. 相似文献
48.
We consider a class of non-linear mixed integer programs with n integer variables and k continuous variables. Solving instances from this class to optimality is an NP-hard problem. We show that for the cases with
k=1 and k=2, every optimal solution is integral. In contrast to this, for every k≥3 there exist instances where every optimal solution takes non-integral values.
Received: August 2001 / Accepted: January 2002?Published online March 27, 2002 相似文献
49.
Lubomír Kubáček 《Mathematica Slovaca》2007,57(1):59-82
In some situations estimates of unknown parameters must be corrected by additional measurements. It is in principle no problem
to calculate the corrected estimates, however, it is of more interest to find formulae for correction itself. The formulae
enable us to design an additional experiment and to judge its usefulness.
The aim of the paper is to find such formulae for several situations.
Supported by the grant of the Council of Czech Government MSM 6 198 959 214. 相似文献
50.