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881.
比光谱导数-零交点法同时测定铜、锌、镍 总被引:2,自引:0,他引:2
在pH=8的硼砂-HCl缓冲溶液中,以乳化剂OP作增溶剂,Cu^2+,Zn62+,Ni^2+分别与5-Br-PADAP形成稳定的配合物,用比光谱导数-零交点法同时测定铜,锌,镍,合成试样6次测定的相对标准偏差小于5%,铜,锌,镍的回收率分别为97.0%-103.2%,96.35-104.8%和95.2%-101.9%。 相似文献
882.
Treatment of 5-vinylpyranosides with Et2Zn and catalytic Pd(0), in the presence of ZnCl2, results in the formation of 5-membered carbocyclic products. This carbohydrate ring-contraction features an intramolecular allylation of a ring-opened carbohydrate aldehyde by an in situ-generated nucleophilic allylzinc species. The stereoselectivity about vinyl and free hydroxyl groups at the newly created stereogenic centers varies from low to moderate while both its extent and sense are found to depend on particular structural features (e.g. the configuration of the starting carbohydrate). 相似文献
883.
1 INTRODUCTION For a long time much research interest has beenfocused on coordination polymers because they mayafford new materials with useful properties, such ascatalytic activity, microporosity, electrical conduc-tivity, non-linear optical activit… 相似文献
884.
A straightforward electrosynthetic method is described, which allows upper rim acylation of non-p-halogenated calix[4]arenes. For example, a solution of tetrapropoxycalix[4]arene 4 was electrolysed in the presence of ZnBr2 in an undivided cell fitted with a sacrificial zinc anode using pure acetonitrile as solvent, yielding an organozinc species, which was then treated with acetyl chloride in the presence of a palladium catalyst to afford 5,11-diacetyl-25,26,27,28-tetrapropoxycalix[4]arene 5 in ca. 35% yield after workup. 相似文献
885.
Homoleptic Zinc Amides: Transition to Monomeric Molecules Zinc chloride reacts with the lithium salts of the bulky secondary amines HN(i-Bu)2 and HN(t-Bu)2 to form the corresponding homoleptic zinc compounds {Zn[N(i-Bu)2]2}2 ( 1 ) and Zn[N(t-Bu)2]2 ( 2 ). The NMR spectroscopic and mass spectrometric results as well as the molecular weight determinations and X-ray diffraction data are consistent with a dimeric structure of 1 and a monomeric structure of 2 in the gas phase, in solution and in the solid state. 相似文献
886.
Sol-Gel Synthesis of Hollow Zinc Ferrite Fibers 总被引:2,自引:0,他引:2
Cairong?Gong Dairong?ChenEmail author Xiuling?Jiao 《Journal of Sol-Gel Science and Technology》2005,35(1):77-82
Hollow zinc ferrite fibers have been prepared via a facile citrate sol-gel process using Fe(OH)(HCOO)2 prepared in laboratory and Zn(CH3COO)2⋅2H2O as the original materials. The obtained hollow fibers were flexible and handlable with the outer diameter being 1–4 μm and the wall thickness less than 1 μm, and the fiber wall were made up of nanoparticles about 50 nm. Rheological behaviour of the precursor sol was tracked by Rheometer. The development of the gel fibers to zinc ferrite fibers was studied by IR, TG and XRD. Morphology observation of the fibers was given on SEM and TEM. 相似文献
887.
A novel two-step aldehyde homologation procedure for the preparation of methyl ketones has been developed, which involves the use of 1,1-dibromo-1-alkenes as precursors and zinc metal as mediator in near-critical water. 相似文献
888.
We have theoretically investigated a series of butadiyne-linked porphyrin derivatives that exhibit large two-photon absorption (TPA) cross sections in the visible-IR range. The electronic structure, one-photon absorption (OPA), and TPA properties have been studied in detail. We found that the introduction of a butadiyne linkage and the increase of the molecular dimensionality from monomer to dimer determine the OPA intensities of Q band and Soret band, respectively. A most important role for the enhancement of the TPA cross section is played by introducing a butadiyne bridge. The complementary coordination and the combination of the terminal free base and the core zinc porphyrin are also two effective factors for the enhancement of the TPA efficiency. The dimer with two porphyrins linked at meso-positions by a butadiyne linkage results in a maximum TPA cross section (79.35 x 10(-48) cm4 s per photon). Our theoretical findings are consistent with the recent experimental observations. This series of porphyrin derivatives as promising TPA materials are the subject of further investigation. 相似文献
889.
研制出复合泡沫塑料色诸柱,并且将其用于可溶性锌(镉)盐的深度纯化,除去重金属杂质离子Fe ̄(2+)、Cr ̄(3+)、Mn ̄(2+)、Pb ̄(2+)、Cu ̄(2+)、Co ̄(2+)和Ni ̄(2+),快速而效果显著。 相似文献
890.
IntroductionDesignandsynthesesofnovelsupramolecularcom plexeswithunusualandtailorablestructuresarefunda mentalstepsindiscoveryandfabricationofvarioustech nologicallyusefulfunctionalsupramoleculardevices .1 3Recently ,considerableeffortshavebeendevotedtocr… 相似文献