BiOx films are prepared by reactive direct current (DC) magnetron sputtering from a metallic bismuth target in Ar + O2 with different O2/Ar ratios. It is found that the optical property of BiOx films is sensitive to O2/Ar ratios and the films deposited at O2/Ar ratio of 0.5 have the best reflectivity contrast under the same conditions. The structure and optical characteristics of the films are studied by X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), and spectrophotometer. As revealed by investigations,the phase transition is mainly responsible for the change of optical properties. The static test results indicate that the BiOx films have good writing sensitivity for blue laser beams. A high reflectivity contrast of about 52% at a writing power of 11 mW and writing pulse width of 800 ns is obtained. In addition, the films demonstrate good stability after being read for 10000 times. 相似文献
Lines are induced on the surface of a photosensitive (FOTURAN) glass by focused femtosecond laser transverse writing with scanning velocity in a wide range of 40- 1800μm/s. The formed lines are analyzed using scanning electron microscope (SEM) and optical microscope (OM). It is observed that three distinct morphologies of lines are produced depending on the scanning velocity. Lines written in low velocity level (40 - 100 μm/s) and high velocity level (1000 - 1800 μm/s) are uniform and regular, while those written in moderate velocity level (150 - 600 μm/s) are rough. The influence of scanning velocity is explained based on different pulses overlapping or cumulative dose of laser exposure in irradiated area. Fabrication of shallow groove on the surface is also demonstrated. 相似文献
We report the fabrication of efficient, buried diffraction gratings and micro-craters in bulk polystyrene using femtosecond laser direct writing technique. We recorded a maximum diffraction efficiency of 10% for a buried grating fabricated at 1 μJ energy, 1 mm/s speed, and a period of 30 μm. Buried micro-craters, with typical dimensions of ∼2 μm, were achieved at low energies and high scanning speeds. From the field emission scanning electron microscope studies, the observed emission is attributed as due to the inner surface modifications and the debris settled around the voids. The fabricated gratings subjected to heat treatment were tested for the diffraction efficiency and emission at different excitation wavelengths and the observed results are presented. Raman spectra collected from the femtosecond laser modified regions revealed the disappearance of few Raman modes at high peak intensities associated with incident Gaussian laser pulse. Potential applications of these luminescent micro-craters are highlighted. 相似文献
A route has been developed to disperse metal‐containing phthalocyanine dyes in a non‐polar medium based on amphiphilic block copolymer micelles of poly[styrene‐block‐(4‐vinylpyridine)] (PS‐b‐P4VP) and poly[styrene‐block‐(acrylic acid)] (PS‐b‐PAA) copolymers. Polar P4VP and PAA efficiently encapsulate cobalt(II ), manganese(II ), and nickel(II ) phthalocyanine dyes by axial coordination of nitrogen and µ‐oxo bridged dimerization with the transition metals, respectively. Good dispersion of the dyes is confirmed by the linear enhancement of Q‐bands in UV–vis absorption spectra with dye concentration. A thin monolayered PS‐b‐P4VP micelle film that contained a nickel(II ) phthalocyanine dye which efficiently adsorbs a laser beam on a localized area to generate a local heat higher than the glass transition temperatures of both blocks. One‐dimensional laser writing on the dye‐containing film allows the fabrication of a few submicrometer wide line patterns in which the self‐assembled nanostructure of the block copolymer is modified by the directional heat arising from laser scanning.