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191.
We study the medium modified fragmentation function in high-energy heavy-ion collisions. We show that the ACSX and QW formalisms are equivalent to each other in the high-Q2 limit in both theoretical and numerical aspects. 相似文献
192.
Lattice QCD predicts a phase transition between hadronic matter and a system of deconfined quarks and gluons (the Quark Gluon Plasma) at high energy densities. Our current understanding of this new state of matter will be discussed with two key results from the Relativistic Heavy Ion Collider (RHIC). 相似文献
193.
目的 探讨早期干预对极低出生体重早产儿智能发育的影响,为极低出生体重早产儿的早期干预提供依据。方法 239 例极低出生体重早产儿为早产随访组,采用鲍秀兰早期教育资料制定的干预计划,进行系统干预,并与326 例失访的早产儿童以及与随访组相似的326 例正常儿童进行对照分析。采用Gesell 儿童发育量表等标准化工具进行发育评估。结果 早产随访组Gesell 儿童发育量表5 项均分、总发育商(developmental quotient,DQ)总分与早产失访组相比差异均有统计学差异(均P<0.05)。结论 早期干预能显著促进极低出生体重早产儿的智能发育,提高患儿的生活质量。 相似文献
194.
A. Carabineanu 《复变函数与椭圆型方程》2015,60(9):1190-1204
We present a new method to investigate the two-dimensional free-boundary groundwater seepage from symmetric soil channels into a homogeneous isotropic porous medium. We use Levi–Civitá’s function to construct an integral representation for the conformal mapping of the complex potential domain onto the physical flow domain. A genetic algorithm (GA) is used to calculate the coefficients of the Maclaurin series expansion of Levi–Civitá’s function. The coordinates of the points from the channel contour, calculated by means of the integral representation, must satisfy the analytic equation of the contour. We use this condition to define the objective function of the genetic algorithm. Levi–Civitá’s function is afterwards used to calculate the seepage loss, the free lines, the streamlines, the equipotential lines, the isobars and the velocity field. Some examples illustrate the method. 相似文献
195.
Franco Cataldo Giancarlo Angelini Donatella Capitani Marco Gobbino Ornella Ursini Fabrizio Forlini 《高分子科学杂志,A辑:纯化学与应用化学》2013,50(10):839-849
This paper is dedicated to the memory of our friend and colleague Annalaura Segre. The chemical structure of a series of β (-)-pinene polymers (PBP) obtained by radiation-induced polymerization, free radical initiation, cationic polymerization over a Friedel-Craft catalyst and by coordinative polymerization over a Ziegler-Natta catalyst has been fully elucidated by 1H and 13C-NMR spectroscopy. 2D NMR techniques have been applied in order to assign all the NMR resonances to the structures of the PBP investigated. The NMR spectra show that the most regular PBP structure is obtained by radiation-induced polymerization followed by the free radical initiated polymerization. The most defective structure has been observed in the case of PBP prepared by cationic mechanism over a Friedel-Crafts catalyst. The discussion accounts for different types of defects and cross-links present in the PBPs investigated whose fundamental structure is based on the p-menthene repeating unit. NMR self-diffusion measurements have been performed to evaluate the molecular weight of all the PBP investigated. The highest molecular weight (2600 Dalton) was found in the case of PBP prepared by Ziegler-Natta catalyst, while the lowest molecular weight was found in the case of PBP prepared by radiation-induced polymerization (about 1000 Dalton). 相似文献
196.
Arno M. Bieser 《Supramolecular chemistry》2013,25(4):363-367
This article highlights the aggregation behaviour of potential low molecular weight hydrogelators on attracting surfaces. Our goal was the development of a method, which enables the finding of new hydrogelators that are not easily recognizable as such because they only form instable or no hydrogels in aqueous solution. To this end, a series of negatively charges azo-dyes was synthesized and positive charged glass slides were immersed into their aqueous solutions. All dyes showed supramolecular organization and significant concentration on the attracting glass surface. Microscopic investigations mostly revealed the formation of crystals. However, one compound, (1-(2-n-octylphenylazo)-2-hydroxy-6-naphthalenesulphonate, selectively formed a hydrogel on the surface whereas it does not gel in aqueous solution. This reveals the hydrogel as the stable form of this compound under equilibrium conditions. This method of surface-induced hydrogelation might facilitate the identification of new hydrogelators. Further more, it might also allow the mimicking of surface gelation as a process of biological relevance. 相似文献
197.
This report describes development of an in silico, expert rule-based method for the classification of chemicals into irritants or non-irritants to eye, as defined by the Draize test. This method was developed to screen data-poor cosmetic ingredient chemicals for eye irritancy potential, which is based upon exclusion rules of five physicochemical properties – molecular weight (MW), hydrophobicity (log P), number of hydrogen bond donors (HBD), number of hydrogen bond acceptors (HBA) and polarizability (Pol). These rules were developed using the ADMET Predictor software and a dataset of 917 eye irritant chemicals. The dataset was divided into 826 (90%) chemicals used for training set and 91 (10%) chemicals used for external validation set (every 10th chemical sorted by molecular weight). The sensitivity of these rules for the training and validation sets was 72.3% and 71.4%, respectively. These rules were also validated for their specificity using an external validation set of 2011 non-irritant chemicals to the eye. The specificity for this validation set was revealed as 77.3%. This method facilitates rapid screening and prioritization of data poor chemicals that are unlikely to be tested for eye irritancy in the Draize test. 相似文献
198.
Prof. Katherine A. Willets 《Chemphyschem》2013,14(14):3186-3195
Surface‐enhanced Raman scattering (SERS) is quickly growing as an analytical technique, because it offers both molecular specificity and excellent sensitivity. For select substrates, SERS can even be observed from single molecules, which is the ultimate limit of detection. This review describes recent developments in the field of single‐molecule SERS (SM‐SERS) with a focus on new tools for characterizing SM‐SERS‐active substrates and how they interact with single molecules on their surface. In particular, techniques that combine optical spectroscopy and microscopy with electron microscopy are described, including correlated optical and transmission electron microscopy, correlated super‐resolution imaging and scanning electron microscopy, and correlated optical microscopy and electron energy loss spectroscopy. 相似文献
199.
A. M. Al-Sabagh M. R. Noor El-Din H. M. Mohamed 《Journal of Dispersion Science and Technology》2013,34(7):1079-1090
Six oil soluble nonionic surfactants with different HLBs have been prepared. Their HLBs situate between 3.9 and 6.7. Transesterification was carried out for glycerol and triethanol amine with oleic acid at different moles to obtain six emusilifiers. They named glycerol momooleate (I), glycerol diooleate (II), glycerol trioleate (III), triethanol amine mono-, di- and tri-oleate (IV), (V,) and (VI). The chemical structure was confirmed using; the elemental analysis, FTIR and 1HNMR. They were evaluated as a primary emulsifiers (PE) for thdrilling fluids (oil base mud) comparing with a currently used primary emulsifier (Fc). The water in oil base mud (w/o emulsions) was prepared. The concentration of emulsifiers and their HLB exhibited interesting rheology properties including shear-thinning behavior, yield value, viscoelastic effects, thixtropy, gel strength, and filtration loss. The rheology properties of such emulsions strongly depended on the average size distribution of the dispersed droplets that could be varied both with the bulk concentration and HLB value of the emulsifiers. The interfacial and surface properties of these emulsifiers suggest that the droplet size of the dispersed phase and bulk concentration are strongly related to the HLB value of emulsifiers. The w/o emulsion (mud formulation) stability is sensitive to the droplet size of the dispersed phase and HLB value of the used emulsifier. The results were discussed on the light the chemical structure of the primary emulsifiers and the emulsion ingredients. 相似文献
200.
Xiaogang Yang Bin Li Haizeng Wang Baorong Hou 《Journal of Dispersion Science and Technology》2013,34(5):672-676
The inhibition effect of cetyl trimethyl ammonium bromide (CTAB) on the corrosion of mild steel in 1.0 mol L?1 hydrochloric acid (HCl) has been studied at different temperatures (25–60°C) by weight loss and potentiodynamic polarization methods. The results reveal that CTAB behaves as an effective inhibitor in 1.0 mol L?1 HCl, and the inhibition efficiency increases with the inhibitor concentration. Polarization curves show that CTAB is a mixed-type inhibitor in hydrochloric acid. The results obtained from weight loss and polarizations are in good agreement. The effect of immersion time on corrosion inhibition has also been examined and is discussed. The adsorption of inhibitor on mild steel surface obeys the Langmuir adsorption isotherm equation. Thermodynamic parameters have been obtained by adsorption theory. The inhibition effect is satisfactorily explained by the parameters. 相似文献