全文获取类型
收费全文 | 10789篇 |
免费 | 1237篇 |
国内免费 | 1044篇 |
专业分类
化学 | 8595篇 |
晶体学 | 47篇 |
力学 | 1059篇 |
综合类 | 159篇 |
数学 | 987篇 |
物理学 | 2223篇 |
出版年
2024年 | 28篇 |
2023年 | 142篇 |
2022年 | 348篇 |
2021年 | 387篇 |
2020年 | 486篇 |
2019年 | 400篇 |
2018年 | 402篇 |
2017年 | 411篇 |
2016年 | 550篇 |
2015年 | 477篇 |
2014年 | 557篇 |
2013年 | 1142篇 |
2012年 | 663篇 |
2011年 | 610篇 |
2010年 | 439篇 |
2009年 | 514篇 |
2008年 | 502篇 |
2007年 | 591篇 |
2006年 | 533篇 |
2005年 | 474篇 |
2004年 | 440篇 |
2003年 | 353篇 |
2002年 | 360篇 |
2001年 | 274篇 |
2000年 | 250篇 |
1999年 | 230篇 |
1998年 | 220篇 |
1997年 | 192篇 |
1996年 | 164篇 |
1995年 | 142篇 |
1994年 | 88篇 |
1993年 | 118篇 |
1992年 | 107篇 |
1991年 | 68篇 |
1990年 | 61篇 |
1989年 | 46篇 |
1988年 | 36篇 |
1987年 | 35篇 |
1986年 | 31篇 |
1985年 | 29篇 |
1984年 | 27篇 |
1983年 | 13篇 |
1982年 | 20篇 |
1981年 | 16篇 |
1980年 | 19篇 |
1979年 | 18篇 |
1978年 | 13篇 |
1977年 | 8篇 |
1976年 | 10篇 |
1973年 | 10篇 |
排序方式: 共有10000条查询结果,搜索用时 78 毫秒
991.
High-order Quadrature amplitude modulation (QAM) is a promising approach to increase the spectral efficiency of wavelength-division-multiplexing (WDM) transmission. However, the optical implementation is still challenging. A customized modulator is proposed for 64-QAM signal generation, and its performance is investigated in detail. 相似文献
992.
993.
生物可降解高吸水性非织造布的研制 总被引:5,自引:0,他引:5
用聚丙烯酸接枝淀粉浆液,在PVA非织造布上形成吸水树脂,从而得到高吸水性非织造布。对接枝单体的比例、交联条件、浸轧量及非织造布规格等因素对高吸水非织造布吸水性能的影响进行了讨论了并测定了其生物降解性能。 相似文献
994.
We have theoretically investigated the energy band structures of two typical magnetic superlattices formed by perpendicular or parallel magnetization ferromagnetic stripes periodically deposited on a two-dimensional electron gas (2DEG), where the magnetic profile in the perpendicular magnetization is of inversion anti-symmetry, but of inversion symmetry in parallel magnetization, respectively. We have shown that the energy bands of perpendicular magnetization display the spin-splitting and transverse wave-vector symmetry, while the energy bands of the parallel magnetization exhibit spin degeneration and transverse wave-vector asymmetry. These distinguishing spin-dependent and transverse wave-vector asymmetry features are essential for future spintronics devices applications. 相似文献
995.
D. K. Buslov N. A. Nikonenko N. I. Sushko R. G. Zhbankov 《Journal of Applied Spectroscopy》2002,69(6):817-824
Deconvolution of the IR absorption spectrum of -D glucose in the spectral range 1500–450 cm–1 has been carried out. The results of the deconvolution were compared with the IR and Raman spectra recorded at room and low temperatures and with the data obtained by theoretical calculations for the frequencies of the normal vibrations of the -D glucose molecule in the crystalline state. It is shown that deconvolution of the IR spectra recorded at room temperature makes it possible to separate the bands observed experimentally only at a very low temperature of the sample and a number of components that were not resolved earlier. The number of bands separated on deconvolution of the IR spectra of -D glucose in the spectral range 1500–450 cm–1 is more than twice the number of visible absorption maxima in the usual spectrum. The results of deconvolution of the IR spectrum of -D glucose are in good agreement with the data of theoretical calculations for the frequencies of the normal vibrations of the -D glucose molecule in the crystalline state. The existence of the factor-group (Davydov) splitting of a number of frequencies of the nondegenerate fundamental vibrations of molecules in a crystal cell has been revealed in the IR spectrum of -D glucose. It was concluded that the model of an isolated molecule is insufficient for detailed theoretical interpretation of the vibrational spectra of carbohydrates. 相似文献
996.
N. B. Éshkobilov 《Journal of Applied Spectroscopy》2002,69(3):477-479
The main series of a silver atom with n = 5–70 are investigated. Perturbations of the np
2
P
1/2,3/2 states with n = 10 and 17 caused by interaction with the selfionization 4d5s5p
4
P
1/2,3/2 states are detected. Energies of the selfionization states are determined. 相似文献
997.
The structure and optical properties of the films of ternary compounds AgInSe2, CuInSe2 and Cu
x
Ag1–x
InSe2 solid solutions obtained by pulsed laser evaporation are investigated. It has been established that the films like bulk crystals have the structure of chalcopyrite. By the transmission and reflection spectra near the edge of natural absorption the refractive index and coefficient of optical absorption are calculated and the energies of interband transitions and the crystalline and spinorbit splitting are determined. 相似文献
998.
Effects of Water Vapor and Ammonia on SO2 Removal from Flue Gases Using Pulsed Corona Discharge 总被引:3,自引:0,他引:3
Yimin Zhu Chae J. O. Kim K. Y. Kim K. O. Park Y. K. 《Plasma Chemistry and Plasma Processing》2002,22(1):187-195
Plasma Chemistry and Plasma Processing - In the study of SO2 removal using pulsed corona discharge, there exists a serious confusion, that is, which kind of reactions, the thermal chemical... 相似文献
999.
A comparative study on chemical conversion of cellulose between the batch-type and flow-type systems in supercritical water 总被引:1,自引:0,他引:1
Microcrystalline cellulose (avicel) was treated in supercritical waterusing batch-type and flow-type systems. The flow-type system made it possibletoshorten the heating, treating and cooling times, compared with the batch-typesystem. As a result, the flow-type system was able to liquefy avicel withoutproducing any supercritical water-insoluble residue. Although hydrolyzedproducts such as glucose and fructose, and pyrolyzed products such aslevoglucosan, 5-hydroxymethyl furfural, erythrose, methylglyoxal,glycolaldehydeand dihydroxyacetone were found in common from the water-soluble portiontreatedby both systems, the flow-type system gave a water-soluble portion with morehydrolyzed and less pyrolyzed products, together with water-solubleoligosaccharides consisting of cellobiose to cellododecaose and theirdecomposedproducts at their reducing end of glucose, such as[–glucopyranosyl]1–11 –levoglucosan,[–glucopyranosyl]1–11 –erythrose and[–glucopyranosyl]1–11 –glycolaldehyde. Inaddition, the precipitates of polysaccharides were recovered after 12h setting of the water-soluble portion. These results indicatedthat the flow-type system can hydrolyze cellulose with minimizing pyrolyzedproducts. On the other hand, the batch-type system resulted in a higher yieldof the pyrolyzed products due to the longer treatment, but a higher yield ofglucose due possibly to the higher pressure and concomitantly higher ionicproduct of water. Based on these lines of evidence, the process to increase theyield of the sugar is discussed under supercritical water treatment. 相似文献
1000.
The polarized electronic absorption spectra of a blue vanadium-doped zircon single crystal, grown by the flux method, has been studied by quantum chemical (CI) calculations in order to determine the position of the V4+ dopant in the zircon host structure. Particularly, the excitation energies and polarizations of V4+ occupying alternate positions, either the zirconium or silicon position or the interstitial site 16g, have been considered. It is concluded that the observed electronic absorption spectra and the color of zirconblue can only be explained if the V4+ chromophore is placed on the respective interstitial position. 相似文献